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Ultrathin positively charged electrode skin for durable anion-intercalation battery chemistries

Author

Listed:
  • Davood Sabaghi

    (Technische Universität Dresden)

  • Zhiyong Wang

    (Technische Universität Dresden
    Max Planck Institute of Microstructure Physics)

  • Preeti Bhauriyal

    (Technische Universität Dresden)

  • Qiongqiong Lu

    (Leibniz Institute for Solid State and Materials Research (IFW))

  • Ahiud Morag

    (Technische Universität Dresden)

  • Daria Mikhailovia

    (Leibniz Institute for Solid State and Materials Research (IFW))

  • Payam Hashemi

    (Technische Universität Dresden
    Max Planck Institute of Microstructure Physics)

  • Dongqi Li

    (Technische Universität Dresden)

  • Christof Neumann

    (Friedrich Schiller University Jena)

  • Zhongquan Liao

    (Fraunhofer Institute for Ceramic Technologies and Systems (IKTS))

  • Anna Maria Dominic

    (Technische Universität Dresden)

  • Ali Shaygan Nia

    (Technische Universität Dresden
    Max Planck Institute of Microstructure Physics)

  • Renhao Dong

    (Technische Universität Dresden
    Shandong University)

  • Ehrenfried Zschech

    (University of Warsaw)

  • Andrey Turchanin

    (Friedrich Schiller University Jena)

  • Thomas Heine

    (Technische Universität Dresden
    Leipzig Research Branch
    Yonsei University)

  • Minghao Yu

    (Technische Universität Dresden)

  • Xinliang Feng

    (Technische Universität Dresden
    Max Planck Institute of Microstructure Physics)

Abstract

The anion-intercalation chemistries of graphite have the potential to construct batteries with promising energy and power breakthroughs. Here, we report the use of an ultrathin, positively charged two-dimensional poly(pyridinium salt) membrane (C2DP) as the graphite electrode skin to overcome the critical durability problem. Large-area C2DP enables the conformal coating on the graphite electrode, remarkably alleviating the electrolyte. Meanwhile, the dense face-on oriented single crystals with ultrathin thickness and cationic backbones allow C2DP with high anion-transport capability and selectivity. Such desirable anion-transport properties of C2DP prevent the cation/solvent co-intercalation into the graphite electrode and suppress the consequent structure collapse. An impressive PF6−-intercalation durability is demonstrated for the C2DP-covered graphite electrode, with capacity retention of 92.8% after 1000 cycles at 1 C and Coulombic efficiencies of > 99%. The feasibility of constructing artificial ion-regulating electrode skins with precisely customized two-dimensional polymers offers viable means to promote problematic battery chemistries.

Suggested Citation

  • Davood Sabaghi & Zhiyong Wang & Preeti Bhauriyal & Qiongqiong Lu & Ahiud Morag & Daria Mikhailovia & Payam Hashemi & Dongqi Li & Christof Neumann & Zhongquan Liao & Anna Maria Dominic & Ali Shaygan Ni, 2023. "Ultrathin positively charged electrode skin for durable anion-intercalation battery chemistries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-36384-5
    DOI: 10.1038/s41467-023-36384-5
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    as
    1. Jianming Zheng & Mark H. Engelhard & Donghai Mei & Shuhong Jiao & Bryant J. Polzin & Ji-Guang Zhang & Wu Xu, 2017. "Electrolyte additive enabled fast charging and stable cycling lithium metal batteries," Nature Energy, Nature, vol. 2(3), pages 1-8, March.
    2. Daniela Molina Piper & Tyler Evans & Kevin Leung & Tylan Watkins & Jarred Olson & Seul Cham Kim & Sang Sub Han & Vinay Bhat & Kyu Hwan Oh & Daniel A. Buttry & Se-Hee Lee, 2015. "Stable silicon-ionic liquid interface for next-generation lithium-ion batteries," Nature Communications, Nature, vol. 6(1), pages 1-10, May.
    3. Bohua Wen & Zhi Deng & Ping-Chun Tsai & Zachary W. Lebens-Higgins & Louis F. J. Piper & Shyue Ping Ong & Yet-Ming Chiang, 2020. "Ultrafast ion transport at a cathode–electrolyte interface and its strong dependence on salt solvation," Nature Energy, Nature, vol. 5(8), pages 578-586, August.
    4. Chunpeng Yang & Qisheng Wu & Weiqi Xie & Xin Zhang & Alexandra Brozena & Jin Zheng & Mounesha N. Garaga & Byung Hee Ko & Yimin Mao & Shuaiming He & Yue Gao & Pengbo Wang & Madhusudan Tyagi & Feng Jiao, 2021. "Copper-coordinated cellulose ion conductors for solid-state batteries," Nature, Nature, vol. 598(7882), pages 590-596, October.
    5. Zhaodong Huang & Yue Hou & Tairan Wang & Yuwei Zhao & Guojin Liang & Xinliang Li & Ying Guo & Qi Yang & Ze Chen & Qing Li & Longtao Ma & Jun Fan & Chunyi Zhi, 2021. "Author Correction: Manipulating anion intercalation enables a high-voltage aqueous dual ion battery," Nature Communications, Nature, vol. 12(1), pages 1-1, December.
    6. Qifeng Zheng & Yuki Yamada & Rui Shang & Seongjae Ko & Yun-Yang Lee & Kijae Kim & Eiichi Nakamura & Atsuo Yamada, 2020. "A cyclic phosphate-based battery electrolyte for high voltage and safe operation," Nature Energy, Nature, vol. 5(4), pages 291-298, April.
    7. Minghao Yu & Hui Shao & Gang Wang & Fan Yang & Chaolun Liang & Patrick Rozier & Cai-Zhuang Wang & Xihong Lu & Patrice Simon & Xinliang Feng, 2020. "Interlayer gap widened α-phase molybdenum trioxide as high-rate anodes for dual-ion-intercalation energy storage devices," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    8. Chongyin Yang & Ji Chen & Xiao Ji & Travis P. Pollard & Xujie Lü & Cheng-Jun Sun & Singyuk Hou & Qi Liu & Cunming Liu & Tingting Qing & Yingqi Wang & Oleg Borodin & Yang Ren & Kang Xu & Chunsheng Wang, 2019. "Aqueous Li-ion battery enabled by halogen conversion–intercalation chemistry in graphite," Nature, Nature, vol. 569(7755), pages 245-250, May.
    9. Junru Wu & Xianshu Wang & Qi Liu & Shuwei Wang & Dong Zhou & Feiyu Kang & Devaraj Shanmukaraj & Michel Armand & Teofilo Rojo & Baohua Li & Guoxiu Wang, 2021. "A synergistic exploitation to produce high-voltage quasi-solid-state lithium metal batteries," Nature Communications, Nature, vol. 12(1), pages 1-13, December.
    10. Zhaodong Huang & Yue Hou & Tairan Wang & Yuwei Zhao & Guojin Liang & Xinliang Li & Ying Guo & Qi Yang & Ze Chen & Qing Li & Longtao Ma & Jun Fan & Chunyi Zhi, 2021. "Manipulating anion intercalation enables a high-voltage aqueous dual ion battery," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    11. Di-Yan Wang & Chuan-Yu Wei & Meng-Chang Lin & Chun-Jern Pan & Hung-Lung Chou & Hsin-An Chen & Ming Gong & Yingpeng Wu & Chunze Yuan & Michael Angell & Yu-Ju Hsieh & Yu-Hsun Chen & Cheng-Yen Wen & Chun, 2017. "Advanced rechargeable aluminium ion battery with a high-quality natural graphite cathode," Nature Communications, Nature, vol. 8(1), pages 1-7, April.
    12. Meng-Chang Lin & Ming Gong & Bingan Lu & Yingpeng Wu & Di-Yan Wang & Mingyun Guan & Michael Angell & Changxin Chen & Jiang Yang & Bing-Joe Hwang & Hongjie Dai, 2015. "An ultrafast rechargeable aluminium-ion battery," Nature, Nature, vol. 520(7547), pages 324-328, April.
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    1. Yao Wang & Shuyu Dong & Yifu Gao & Pui-Kit Lee & Yao Tian & Yuefeng Meng & Xia Hu & Xin Zhao & Baohua Li & Dong Zhou & Feiyu Kang, 2024. "Difluoroester solvent toward fast-rate anion-intercalation lithium metal batteries under extreme conditions," Nature Communications, Nature, vol. 15(1), pages 1-13, December.

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