IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-40792-y.html
   My bibliography  Save this article

Skin-like cryogel electronics from suppressed-freezing tuned polymer amorphization

Author

Listed:
  • Xiansheng Zhang

    (Qingdao University)

  • Hongwei Yan

    (Qingdao University)

  • Chongzhi Xu

    (Qingdao University)

  • Xia Dong

    (Chinese Academy of Sciences)

  • Yu Wang

    (Chinese Academy of Sciences)

  • Aiping Fu

    (Qingdao University)

  • Hao Li

    (SungKyunKwan University)

  • Jin Yong Lee

    (SungKyunKwan University)

  • Sheng Zhang

    (Zhejiang University)

  • Jiahua Ni

    (Donghua University)

  • Min Gao

    (ETH Zürich)

  • Jing Wang

    (ETH Zürich)

  • Jinpeng Yu

    (Qingdao University)

  • Shuzhi Sam Ge

    (National University of Singapore)

  • Ming Liang Jin

    (Qingdao University)

  • Lili Wang

    (Qingdao University)

  • Yanzhi Xia

    (Qingdao University)

Abstract

The sole situation of semi-crystalline structure induced single performance remarkably limits the green cryogels in the application of soft devices due to uncontrolled freezing field. Here, a facile strategy for achieving multifunctionality of cryogels is proposed using total amorphization of polymer. Through precisely lowering the freezing point of precursor solutions with an antifreezing salt, the suppressed growth of ice is achieved, creating an unusually weak and homogenous aggregation of polymer chains upon freezing, thereby realizing the tunable amorphization of polymer and the coexistence of free and hydrogen bonding hydroxyl groups. Such multi-scale microstructures trigger the integrated properties of tissue-like ultrasoftness (Young’s modulus

Suggested Citation

  • Xiansheng Zhang & Hongwei Yan & Chongzhi Xu & Xia Dong & Yu Wang & Aiping Fu & Hao Li & Jin Yong Lee & Sheng Zhang & Jiahua Ni & Min Gao & Jing Wang & Jinpeng Yu & Shuzhi Sam Ge & Ming Liang Jin & Lil, 2023. "Skin-like cryogel electronics from suppressed-freezing tuned polymer amorphization," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-40792-y
    DOI: 10.1038/s41467-023-40792-y
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-40792-y
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-023-40792-y?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Wei Zhang & Baohu Wu & Shengtong Sun & Peiyi Wu, 2021. "Skin-like mechanoresponsive self-healing ionic elastomer from supramolecular zwitterionic network," Nature Communications, Nature, vol. 12(1), pages 1-12, December.
    2. Chunpeng Yang & Qisheng Wu & Weiqi Xie & Xin Zhang & Alexandra Brozena & Jin Zheng & Mounesha N. Garaga & Byung Hee Ko & Yimin Mao & Shuaiming He & Yue Gao & Pengbo Wang & Madhusudan Tyagi & Feng Jiao, 2021. "Copper-coordinated cellulose ion conductors for solid-state batteries," Nature, Nature, vol. 598(7882), pages 590-596, October.
    3. Mutian Hua & Shuwang Wu & Yanfei Ma & Yusen Zhao & Zilin Chen & Imri Frenkel & Joseph Strzalka & Hua Zhou & Xinyuan Zhu & Ximin He, 2021. "Strong tough hydrogels via the synergy of freeze-casting and salting out," Nature, Nature, vol. 590(7847), pages 594-599, February.
    4. Hyunwoo Yuk & Claudia E. Varela & Christoph S. Nabzdyk & Xinyu Mao & Robert F. Padera & Ellen T. Roche & Xuanhe Zhao, 2019. "Dry double-sided tape for adhesion of wet tissues and devices," Nature, Nature, vol. 575(7781), pages 169-174, November.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Feipeng Chen & Xiufeng Li & Yafeng Yu & Qingchuan Li & Haisong Lin & Lizhi Xu & Ho Cheung Shum, 2023. "Phase-separation facilitated one-step fabrication of multiscale heterogeneous two-aqueous-phase gel," Nature Communications, Nature, vol. 14(1), pages 1-14, December.
    2. Wenqian He & Meilin Wang & Guangkai Mei & Shiyong Liu & Abdul Qadeer Khan & Chao Li & Danyang Feng & Zihao Su & Lili Bao & Ge Wang & Enzhao Liu & Yutian Zhu & Jie Bai & Meifang Zhu & Xiang Zhou & Zunf, 2024. "Establishing superfine nanofibrils for robust polyelectrolyte artificial spider silk and powerful artificial muscles," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    3. Jiqiang Wang & Baohu Wu & Peng Wei & Shengtong Sun & Peiyi Wu, 2022. "Fatigue-free artificial ionic skin toughened by self-healable elastic nanomesh," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    4. Guangyu Bao & Qiman Gao & Massimo Cau & Nabil Ali-Mohamad & Mitchell Strong & Shuaibing Jiang & Zhen Yang & Amin Valiei & Zhenwei Ma & Marco Amabili & Zu-Hua Gao & Luc Mongeau & Christian Kastrup & Ji, 2022. "Liquid-infused microstructured bioadhesives halt non-compressible hemorrhage," Nature Communications, Nature, vol. 13(1), pages 1-14, December.
    5. Parth Chansoria & Ameya Chaudhari & Emma L. Etter & Emily E. Bonacquisti & Mairead K. Heavey & Jiayan Le & Murali Kannan Maruthamuthu & Caden C. Kussatz & John Blackwell & Natalie E. Jasiewicz & Rani , 2024. "Instantly adhesive and ultra-elastic patches for dynamic organ and wound repair," Nature Communications, Nature, vol. 15(1), pages 1-19, December.
    6. Bin Xue & Jie Gu & Lan Li & Wenting Yu & Sheng Yin & Meng Qin & Qing Jiang & Wei Wang & Yi Cao, 2021. "Hydrogel tapes for fault-tolerant strong wet adhesion," Nature Communications, Nature, vol. 12(1), pages 1-12, December.
    7. Chenyue Guo & Huajie Tang & Pengfei Wang & Qihao Xu & Haodan Pan & Xinyu Zhao & Fan Fan & Tingxian Li & Dongliang Zhao, 2024. "Radiative cooling assisted self-sustaining and highly efficient moisture energy harvesting," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    8. Zhao Pan & Qi-Qi Fu & Mo-Han Wang & Huai-Ling Gao & Liang Dong & Pu Zhou & Dong-Dong Cheng & Ying Chen & Duo-Hong Zou & Jia-Cai He & Xue Feng & Shu-Hong Yu, 2023. "Designing nanohesives for rapid, universal, and robust hydrogel adhesion," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    9. Chao Chen & Jiaming Zhang & Benrui Hu & Qianwen Liang & Xunhui Xiong, 2023. "Dynamic gel as artificial interphase layer for ultrahigh-rate and large-capacity lithium metal anode," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    10. Ruixin Zhu & Dandan Zhu & Zhen Zheng & Xinling Wang, 2024. "Tough double network hydrogels with rapid self-reinforcement and low hysteresis based on highly entangled networks," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    11. Camilo Duque Londono & Seth F. Cones & Jue Deng & Jingjing Wu & Hyunwoo Yuk & David E. Guza & T. Aran Mooney & Xuanhe Zhao, 2024. "Bioadhesive interface for marine sensors on diverse soft fragile species," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    12. Caicong Li & Jianxiang Cheng & Yunfeng He & Xiangnan He & Ziyi Xu & Qi Ge & Canhui Yang, 2023. "Polyelectrolyte elastomer-based ionotronic sensors with multi-mode sensing capabilities via multi-material 3D printing," Nature Communications, Nature, vol. 14(1), pages 1-14, December.
    13. Jine Wu & Chenyi Liao & Tianyu Li & Jing Zhou & Linjuan Zhang & Jian-Qiang Wang & Guohui Li & Xianfeng Li, 2023. "Metal-coordinated polybenzimidazole membranes with preferential K+ transport," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    14. Quanqian Lyu & Miaomiao Li & Lianbin Zhang & Jintao Zhu, 2024. "Structurally-colored adhesives for sensitive, high-resolution, and non-invasive adhesion self-monitoring," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    15. Jun Zhang & Wenxiang Wang & Yan Zhang & Qiang Wei & Fei Han & Shengyi Dong & Dongqing Liu & Shiguo Zhang, 2022. "Small-molecule ionic liquid-based adhesive with strong room-temperature adhesion promoted by electrostatic interaction," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    16. Dan Xu & Yang Yang & Lukas Emmerich & Yong Wang & Kai Zhang, 2023. "Divergent Deborah number-dependent transition from homogeneity to heterogeneity," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    17. Won Bae Han & Gwan-Jin Ko & Kang-Gon Lee & Donghak Kim & Joong Hoon Lee & Seung Min Yang & Dong-Je Kim & Jeong-Woong Shin & Tae-Min Jang & Sungkeun Han & Honglei Zhou & Heeseok Kang & Jun Hyeon Lim & , 2023. "Ultra-stretchable and biodegradable elastomers for soft, transient electronics," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    18. Elvis K. Boahen & Baohai Pan & Hyukmin Kweon & Joo Sung Kim & Hanbin Choi & Zhengyang Kong & Dong Jun Kim & Jin Zhu & Wu Bin Ying & Kyung Jin Lee & Do Hwan Kim, 2022. "Ultrafast, autonomous self-healable iontronic skin exhibiting piezo-ionic dynamics," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    19. Yujie Hua & Kai Wang & Yingying Huo & Yaping Zhuang & Yuhui Wang & Wenzhuo Fang & Yuyan Sun & Guangdong Zhou & Qiang Fu & Wenguo Cui & Kaile Zhang, 2023. "Four-dimensional hydrogel dressing adaptable to the urethral microenvironment for scarless urethral reconstruction," Nature Communications, Nature, vol. 14(1), pages 1-16, December.
    20. Qingao Chen & Lunjun Qu & Hui Hou & Jiayue Huang & Chen Li & Ying Zhu & Yongkang Wang & Xiaohong Chen & Qian Zhou & Yan Yang & Chaolong Yang, 2024. "Long lifetimes white afterglow in slightly crosslinked polymer systems," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-40792-y. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.