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Electrolyte additive enabled fast charging and stable cycling lithium metal batteries

Author

Listed:
  • Jianming Zheng

    (Energy and Environment Directorate, Pacific Northwest National Laboratory)

  • Mark H. Engelhard

    (Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory)

  • Donghai Mei

    (Physical and Computational Sciences Directorate, Pacific Northwest National Laboratory)

  • Shuhong Jiao

    (Energy and Environment Directorate, Pacific Northwest National Laboratory)

  • Bryant J. Polzin

    (Argonne National Laboratory)

  • Ji-Guang Zhang

    (Energy and Environment Directorate, Pacific Northwest National Laboratory)

  • Wu Xu

    (Energy and Environment Directorate, Pacific Northwest National Laboratory)

Abstract

Batteries using lithium (Li) metal as anodes are considered promising energy storage systems because of their high energy densities. However, safety concerns associated with dendrite growth along with limited cycle life, especially at high charge current densities, hinder their practical uses. Here we report that an optimal amount (0.05 M) of LiPF6 as an additive in LiTFSI–LiBOB dual-salt/carbonate-solvent-based electrolytes significantly enhances the charging capability and cycling stability of Li metal batteries. In a Li metal battery using a 4-V Li-ion cathode at a moderately high loading of 1.75 mAh cm−2, a cyclability of 97.1% capacity retention after 500 cycles along with very limited increase in electrode overpotential is accomplished at a charge/discharge current density up to 1.75 mA cm−2. The fast charging and stable cycling performances are ascribed to the generation of a robust and conductive solid electrolyte interphase at the Li metal surface and stabilization of the Al cathode current collector.

Suggested Citation

  • Jianming Zheng & Mark H. Engelhard & Donghai Mei & Shuhong Jiao & Bryant J. Polzin & Ji-Guang Zhang & Wu Xu, 2017. "Electrolyte additive enabled fast charging and stable cycling lithium metal batteries," Nature Energy, Nature, vol. 2(3), pages 1-8, March.
    • Handle: RePEc:nat:natene:v:2:y:2017:i:3:d:10.1038_nenergy.2017.12
    DOI: 10.1038/nenergy.2017.12
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    Cited by:

    1. Shuoqing Zhang & Ruhong Li & Nan Hu & Tao Deng & Suting Weng & Zunchun Wu & Di Lu & Haikuo Zhang & Junbo Zhang & Xuefeng Wang & Lixin Chen & Liwu Fan & Xiulin Fan, 2022. "Tackling realistic Li+ flux for high-energy lithium metal batteries," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    2. Yuqiang Zeng & Buyi Zhang & Yanbao Fu & Fengyu Shen & Qiye Zheng & Divya Chalise & Ruijiao Miao & Sumanjeet Kaur & Sean D. Lubner & Michael C. Tucker & Vincent Battaglia & Chris Dames & Ravi S. Prashe, 2023. "Extreme fast charging of commercial Li-ion batteries via combined thermal switching and self-heating approaches," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    3. Jijiang Liu & Wei Hao & Mingming Fang & Xin Chen & Yongteng Dong & Yuanmao Chen & Zhiyong Wang & Xinyang Yue & Zheng Liang, 2024. "Screening of F-containing electrolyte additives and clarifying their decomposition routes for stable Li metal anodes," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    4. Muhammad Mominur Rahman & Sha Tan & Yang Yang & Hui Zhong & Sanjit Ghose & Iradwikanari Waluyo & Adrian Hunt & Lu Ma & Xiao-Qing Yang & Enyuan Hu, 2023. "An inorganic-rich but LiF-free interphase for fast charging and long cycle life lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    5. Zhi Chang & Huijun Yang & Xingyu Zhu & Ping He & Haoshen Zhou, 2022. "A stable quasi-solid electrolyte improves the safe operation of highly efficient lithium-metal pouch cells in harsh environments," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    6. Yan Zhao & Tianhong Zhou & Mounir Mensi & Jang Wook Choi & Ali Coskun, 2023. "Electrolyte engineering via ether solvent fluorination for developing stable non-aqueous lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    7. Xuekun Lu & Marco Lagnoni & Antonio Bertei & Supratim Das & Rhodri E. Owen & Qi Li & Kieran O’Regan & Aaron Wade & Donal P. Finegan & Emma Kendrick & Martin Z. Bazant & Dan J. L. Brett & Paul R. Shear, 2023. "Multiscale dynamics of charging and plating in graphite electrodes coupling operando microscopy and phase-field modelling," Nature Communications, Nature, vol. 14(1), pages 1-14, December.
    8. Zhi Chang & Huijun Yang & Anqiang Pan & Ping He & Haoshen Zhou, 2022. "An improved 9 micron thick separator for a 350 Wh/kg lithium metal rechargeable pouch cell," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    9. In-Ho Cho & Pyeong-Yeon Lee & Jong-Hoon Kim, 2019. "Analysis of the Effect of the Variable Charging Current Control Method on Cycle Life of Li-ion Batteries," Energies, MDPI, vol. 12(15), pages 1-11, August.
    10. Solomon T. Oyakhire & Wenbo Zhang & Andrew Shin & Rong Xu & David T. Boyle & Zhiao Yu & Yusheng Ye & Yufei Yang & James A. Raiford & William Huang & Joel R. Schneider & Yi Cui & Stacey F. Bent, 2022. "Electrical resistance of the current collector controls lithium morphology," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    11. Davood Sabaghi & Zhiyong Wang & Preeti Bhauriyal & Qiongqiong Lu & Ahiud Morag & Daria Mikhailovia & Payam Hashemi & Dongqi Li & Christof Neumann & Zhongquan Liao & Anna Maria Dominic & Ali Shaygan Ni, 2023. "Ultrathin positively charged electrode skin for durable anion-intercalation battery chemistries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    12. Jyotshna Pokharel & Arthur Cresce & Bharat Pant & Moon Young Yang & Ashim Gurung & Wei He & Abiral Baniya & Buddhi Sagar Lamsal & Zhongjiu Yang & Stephen Gent & Xiaojun Xian & Ye Cao & William A. Godd, 2024. "Manipulating the diffusion energy barrier at the lithium metal electrolyte interface for dendrite-free long-life batteries," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

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