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A weakly coordinating-intervention strategy for modulating Na+ solvation sheathes and constructing robust interphase in sodium-metal batteries

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  • Chutao Wang

    (Xiamen University)

  • Zongqiang Sun

    (Xiamen University)

  • Yaqing Liu

    (Xiamen University)

  • Lin Liu

    (Xiamen University)

  • Xiaoting Yin

    (Xiamen University)

  • Qing Hou

    (Xiamen University)

  • Jingmin Fan

    (Xiamen University)

  • Jiawei Yan

    (Xiamen University)

  • Ruming Yuan

    (Xiamen University)

  • Mingsen Zheng

    (Xiamen University
    Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM))

  • Quanfeng Dong

    (Xiamen University
    Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM))

Abstract

Constructing powerful anode/cathode interphases by modulate ion solvation structure is the principle of electrolyte design. However, the methodological and theoretical design principles of electrolyte/solvation structure and their effect on electrochemical performance are still vague. Here, we propose a cationic weakly coordinating-intervention strategy for modulating the Na+ solvation sheathes and constructing robust anode/cathode interphases in sodium-metal batteries. Unlike the local highly concentrated electrolytes, 1,2-difluorobenzene can weakly coordinate with Na+ thus transforming the solvation structure into Na+-anion-incorporated structures and strengthening anode/cathode interphases formation by combining with salt decomposition. Furthermore, the correlations between the electrode interface properties and solvation structure are revealed, which can be tuned by the weakly coordination. Ultimately, the modulated electrolyte achieves 97.5% Coulombic efficiency for 600 cycles in Na‖Cu cells at 1 mA cm−2 and a beneficial lifetime (2500 h) in Na‖Na cells. Meanwhile, Na‖PB cells have achieved long-term operation at 4.8 V, along with operation at wide temperatures.

Suggested Citation

  • Chutao Wang & Zongqiang Sun & Yaqing Liu & Lin Liu & Xiaoting Yin & Qing Hou & Jingmin Fan & Jiawei Yan & Ruming Yuan & Mingsen Zheng & Quanfeng Dong, 2024. "A weakly coordinating-intervention strategy for modulating Na+ solvation sheathes and constructing robust interphase in sodium-metal batteries," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-50751-w
    DOI: 10.1038/s41467-024-50751-w
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    as
    1. Jijian Xu & Jiaxun Zhang & Travis P. Pollard & Qingdong Li & Sha Tan & Singyuk Hou & Hongli Wan & Fu Chen & Huixin He & Enyuan Hu & Kang Xu & Xiao-Qing Yang & Oleg Borodin & Chunsheng Wang, 2023. "Electrolyte design for Li-ion batteries under extreme operating conditions," Nature, Nature, vol. 614(7949), pages 694-700, February.
    2. Zheng Li & Harsha Rao & Rasha Atwi & Bhuvaneswari M. Sivakumar & Bharat Gwalani & Scott Gray & Kee Sung Han & Thomas A. Everett & Tanvi A. Ajantiwalay & Vijayakumar Murugesan & Nav Nidhi Rajput & Vila, 2023. "Non-polar ether-based electrolyte solutions for stable high-voltage non-aqueous lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    3. Yan Jin & Phung M. L. Le & Peiyuan Gao & Yaobin Xu & Biwei Xiao & Mark H. Engelhard & Xia Cao & Thanh D. Vo & Jiangtao Hu & Lirong Zhong & Bethany E. Matthews & Ran Yi & Chongmin Wang & Xiaolin Li & J, 2022. "Low-solvation electrolytes for high-voltage sodium-ion batteries," Nature Energy, Nature, vol. 7(8), pages 718-725, August.
    4. Zhiao Yu & Hansen Wang & Xian Kong & William Huang & Yuchi Tsao & David G. Mackanic & Kecheng Wang & Xinchang Wang & Wenxiao Huang & Snehashis Choudhury & Yu Zheng & Chibueze V. Amanchukwu & Samantha , 2020. "Molecular design for electrolyte solvents enabling energy-dense and long-cycling lithium metal batteries," Nature Energy, Nature, vol. 5(7), pages 526-533, July.
    5. Sang Cheol Kim & Jingyang Wang & Rong Xu & Pu Zhang & Yuelang Chen & Zhuojun Huang & Yufei Yang & Zhiao Yu & Solomon T. Oyakhire & Wenbo Zhang & Louisa C. Greenburg & Mun Sek Kim & David T. Boyle & Ph, 2023. "High-entropy electrolytes for practical lithium metal batteries," Nature Energy, Nature, vol. 8(8), pages 814-826, August.
    6. Jianhui Wang & Yuki Yamada & Keitaro Sodeyama & Ching Hua Chiang & Yoshitaka Tateyama & Atsuo Yamada, 2016. "Superconcentrated electrolytes for a high-voltage lithium-ion battery," Nature Communications, Nature, vol. 7(1), pages 1-9, November.
    7. Qifeng Zheng & Yuki Yamada & Rui Shang & Seongjae Ko & Yun-Yang Lee & Kijae Kim & Eiichi Nakamura & Atsuo Yamada, 2020. "A cyclic phosphate-based battery electrolyte for high voltage and safe operation," Nature Energy, Nature, vol. 5(4), pages 291-298, April.
    8. Yuki Yamada & Jianhui Wang & Seongjae Ko & Eriko Watanabe & Atsuo Yamada, 2019. "Advances and issues in developing salt-concentrated battery electrolytes," Nature Energy, Nature, vol. 4(4), pages 269-280, April.
    9. Shuhong Jiao & Xiaodi Ren & Ruiguo Cao & Mark H. Engelhard & Yuzi Liu & Dehong Hu & Donghai Mei & Jianming Zheng & Wengao Zhao & Qiuyan Li & Ning Liu & Brian D. Adams & Cheng Ma & Jun Liu & Ji-Guang Z, 2018. "Stable cycling of high-voltage lithium metal batteries in ether electrolytes," Nature Energy, Nature, vol. 3(9), pages 739-746, September.
    10. Bing Han & Yucheng Zou & Zhen Zhang & Xuming Yang & Xiaobo Shi & Hong Meng & Hong Wang & Kang Xu & Yonghong Deng & Meng Gu, 2021. "Probing the Na metal solid electrolyte interphase via cryo-transmission electron microscopy," Nature Communications, Nature, vol. 12(1), pages 1-8, December.
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