IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v13y2022i1d10.1038_s41467-022-30701-0.html
   My bibliography  Save this article

The Landé factors of electrons and holes in lead halide perovskites: universal dependence on the band gap

Author

Listed:
  • E. Kirstein

    (Experimentelle Physik 2, Technische Universität Dortmund)

  • D. R. Yakovlev

    (Experimentelle Physik 2, Technische Universität Dortmund
    Ioffe Institute, Russian Academy of Sciences)

  • M. M. Glazov

    (Ioffe Institute, Russian Academy of Sciences)

  • E. A. Zhukov

    (Experimentelle Physik 2, Technische Universität Dortmund
    Ioffe Institute, Russian Academy of Sciences)

  • D. Kudlacik

    (Experimentelle Physik 2, Technische Universität Dortmund)

  • I. V. Kalitukha

    (Ioffe Institute, Russian Academy of Sciences)

  • V. F. Sapega

    (Ioffe Institute, Russian Academy of Sciences)

  • G. S. Dimitriev

    (Ioffe Institute, Russian Academy of Sciences)

  • M. A. Semina

    (Ioffe Institute, Russian Academy of Sciences)

  • M. O. Nestoklon

    (Ioffe Institute, Russian Academy of Sciences)

  • E. L. Ivchenko

    (Ioffe Institute, Russian Academy of Sciences)

  • N. E. Kopteva

    (Experimentelle Physik 2, Technische Universität Dortmund)

  • D. N. Dirin

    (ETH Zürich)

  • O. Nazarenko

    (ETH Zürich)

  • M. V. Kovalenko

    (ETH Zürich
    Department of Advanced Materials and Surfaces, Laboratory for Thin Films and Photovoltaics, Empa—Swiss Federal Laboratories for Materials Science and Technology)

  • A. Baumann

    (Experimental Physics VI, Julius-Maximilian University of Würzburg)

  • J. Höcker

    (Experimental Physics VI, Julius-Maximilian University of Würzburg)

  • V. Dyakonov

    (Experimental Physics VI, Julius-Maximilian University of Würzburg)

  • M. Bayer

    (Experimentelle Physik 2, Technische Universität Dortmund
    Ioffe Institute, Russian Academy of Sciences)

Abstract

The Landé or g-factors of charge carriers are decisive for the spin-dependent phenomena in solids and provide also information about the underlying electronic band structure. We present a comprehensive set of experimental data for values and anisotropies of the electron and hole Landé factors in hybrid organic-inorganic (MAPbI3, MAPb(Br0.5Cl0.5)3, MAPb(Br0.05Cl0.95)3, FAPbBr3, FA0.9Cs0.1PbI2.8Br0.2, MA=methylammonium and FA=formamidinium) and all-inorganic (CsPbBr3) lead halide perovskites, determined by pump-probe Kerr rotation and spin-flip Raman scattering in magnetic fields up to 10 T at cryogenic temperatures. Further, we use first-principles density functional theory (DFT) calculations in combination with tight-binding and k ⋅ p approaches to calculate microscopically the Landé factors. The results demonstrate their universal dependence on the band gap energy across the different perovskite material classes, which can be summarized in a universal semi-phenomenological expression, in good agreement with experiment.

Suggested Citation

  • E. Kirstein & D. R. Yakovlev & M. M. Glazov & E. A. Zhukov & D. Kudlacik & I. V. Kalitukha & V. F. Sapega & G. S. Dimitriev & M. A. Semina & M. O. Nestoklon & E. L. Ivchenko & N. E. Kopteva & D. N. Di, 2022. "The Landé factors of electrons and holes in lead halide perovskites: universal dependence on the band gap," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-30701-0
    DOI: 10.1038/s41467-022-30701-0
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-022-30701-0
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-022-30701-0?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Haotong Wei & Jinsong Huang, 2019. "Halide lead perovskites for ionizing radiation detection," Nature Communications, Nature, vol. 10(1), pages 1-12, December.
    2. Vasilii V. Belykh & Dmitri R. Yakovlev & Mikhail M. Glazov & Philipp S. Grigoryev & Mujtaba Hussain & Janina Rautert & Dmitry N. Dirin & Maksym V. Kovalenko & Manfred Bayer, 2019. "Coherent spin dynamics of electrons and holes in CsPbBr3 perovskite crystals," Nature Communications, Nature, vol. 10(1), pages 1-6, December.
    3. Vasilii V. Belykh & Dmitri R. Yakovlev & Mikhail M. Glazov & Philipp S. Grigoryev & Mujtaba Hussain & Janina Rautert & Dmitry N. Dirin & Maksym V. Kovalenko & Manfred Bayer, 2019. "Author Correction: Coherent spin dynamics of electrons and holes in CsPbBr3 perovskite crystals," Nature Communications, Nature, vol. 10(1), pages 1-1, December.
    4. Jingying Wang & Chuang Zhang & Haoliang Liu & Ryan McLaughlin & Yaxin Zhai & Shai R. Vardeny & Xiaojie Liu & Stephen McGill & Dmitry Semenov & Hangwen Guo & Ryuichi Tsuchikawa & Vikram V. Deshpande & , 2019. "Spin-optoelectronic devices based on hybrid organic-inorganic trihalide perovskites," Nature Communications, Nature, vol. 10(1), pages 1-6, December.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. E. Kirstein & N. E. Kopteva & D. R. Yakovlev & E. A. Zhukov & E. V. Kolobkova & M. S. Kuznetsova & V. V. Belykh & I. A. Yugova & M. M. Glazov & M. Bayer & A. Greilich, 2023. "Mode locking of hole spin coherences in CsPb(Cl, Br)3 perovskite nanocrystals," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
    2. Junqing Xu & Kejun Li & Uyen N. Huynh & Mayada Fadel & Jinsong Huang & Ravishankar Sundararaman & Valy Vardeny & Yuan Ping, 2024. "How spin relaxes and dephases in bulk halide perovskites," Nature Communications, Nature, vol. 15(1), pages 1-13, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. E. Kirstein & N. E. Kopteva & D. R. Yakovlev & E. A. Zhukov & E. V. Kolobkova & M. S. Kuznetsova & V. V. Belykh & I. A. Yugova & M. M. Glazov & M. Bayer & A. Greilich, 2023. "Mode locking of hole spin coherences in CsPb(Cl, Br)3 perovskite nanocrystals," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
    2. Rui Cai & Indrajit Wadgaonkar & Jia Wei Melvin Lim & Stefano Dal Forno & David Giovanni & Minjun Feng & Senyun Ye & Marco Battiato & Tze Chien Sum, 2023. "Zero-field quantum beats and spin decoherence mechanisms in CsPbBr3 perovskite nanocrystals," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
    3. E. Kirstein & D. S. Smirnov & E. A. Zhukov & D. R. Yakovlev & N. E. Kopteva & D. N. Dirin & O. Hordiichuk & M. V. Kovalenko & M. Bayer, 2023. "The squeezed dark nuclear spin state in lead halide perovskites," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    4. Junqing Xu & Kejun Li & Uyen N. Huynh & Mayada Fadel & Jinsong Huang & Ravishankar Sundararaman & Valy Vardeny & Yuan Ping, 2024. "How spin relaxes and dephases in bulk halide perovskites," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    5. Madeleine Laitz & Alexander E. K. Kaplan & Jude Deschamps & Ulugbek Barotov & Andrew H. Proppe & Inés García-Benito & Anna Osherov & Giulia Grancini & Dane W. deQuilettes & Keith A. Nelson & Moungi G., 2023. "Uncovering temperature-dependent exciton-polariton relaxation mechanisms in hybrid organic-inorganic perovskites," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    6. Xiaopeng Feng & Yuhong He & Wei Qu & Jinmei Song & Wanting Pan & Mingrui Tan & Bai Yang & Haotong Wei, 2022. "Spray-coated perovskite hemispherical photodetector featuring narrow-band and wide-angle imaging," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    7. Peng Jin & Yingjie Tang & Dingwei Li & Yan Wang & Peng Ran & Chuanyu Zhou & Ye Yuan & Wenjuan Zhu & Tianyu Liu & Kun Liang & Cuifang Kuang & Xu Liu & Bowen Zhu & Yang (Michael) Yang, 2023. "Realizing nearly-zero dark current and ultrahigh signal-to-noise ratio perovskite X-ray detector and image array by dark-current-shunting strategy," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    8. Xueli Yang & Ankang Guo & Jie Yang & Jinyang Chen & Ke Meng & Shunhua Hu & Ran Duan & Mingliang Zhu & Wenkang Shi & Yang Qin & Rui Zhang & Haijun Yang & Jikun Li & Lidan Guo & Xiangnan Sun & Yunqi Liu, 2024. "Halogenated-edge polymeric semiconductor for efficient spin transport," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    9. Yurou Zhang & Miaoqiang Lyu & Tengfei Qiu & Ekyu Han & Il Ku Kim & Min-Cherl Jung & Yun Hau Ng & Jung-Ho Yun & Lianzhou Wang, 2020. "Halide Perovskite Single Crystals: Optoelectronic Applications and Strategical Approaches," Energies, MDPI, vol. 13(16), pages 1-27, August.
    10. Sunihl Ma & Young-Kwang Jung & Jihoon Ahn & Jihoon Kyhm & Jeiwan Tan & Hyungsoo Lee & Gyumin Jang & Chan Uk Lee & Aron Walsh & Jooho Moon, 2022. "Elucidating the origin of chiroptical activity in chiral 2D perovskites through nano-confined growth," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    11. Sean A. Bourelle & Franco V. A. Camargo & Soumen Ghosh & Timo Neumann & Tim W. J. Goor & Ravichandran Shivanna & Thomas Winkler & Giulio Cerullo & Felix Deschler, 2022. "Optical control of exciton spin dynamics in layered metal halide perovskites via polaronic state formation," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    12. Zihao Song & Xinyuan Du & Xin He & Hanqi Wang & Zhiqiang Liu & Haodi Wu & Hongde Luo & Libo Jin & Ling Xu & Zhiping Zheng & Guangda Niu & Jiang Tang, 2023. "Rheological engineering of perovskite suspension toward high-resolution X-ray flat-panel detector," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    13. Wanting Pan & Yuhong He & Weijun Li & Lulu Liu & Keke Guo & Jianglei Zhang & Chao Wang & Bao Li & Hu Huang & Junhu Zhang & Bai Yang & Haotong Wei, 2024. "Cation-π interactions enabled water-stable perovskite X-ray flat mini-panel imager," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    14. Guankui Long & Giorgio Adamo & Jingyi Tian & Maciej Klein & Harish N. S. Krishnamoorthy & Elena Feltri & Hebin Wang & Cesare Soci, 2022. "Perovskite metasurfaces with large superstructural chirality," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    15. Yingjie Tang & Peng Jin & Yan Wang & Dingwei Li & Yitong Chen & Peng Ran & Wei Fan & Kun Liang & Huihui Ren & Xuehui Xu & Rui Wang & Yang (Michael) Yang & Bowen Zhu, 2023. "Enabling low-drift flexible perovskite photodetectors by electrical modulation for wearable health monitoring and weak light imaging," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    16. Nan Gan & Xin Zou & Mengyang Dong & Yanze Wang & Xiao Wang & Anqi Lv & Zhicheng Song & Yuanyuan Zhang & Wenqi Gong & Zhu Zhao & Ziyang Wang & Zixing Zhou & Huili Ma & Xiaowang Liu & Qiushui Chen & Hui, 2022. "Organic phosphorescent scintillation from copolymers by X-ray irradiation," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    17. Sujung Min & Hara Kang & Bumkyung Seo & JaeHak Cheong & Changhyun Roh & Sangbum Hong, 2021. "A Review of Nanomaterial Based Scintillators," Energies, MDPI, vol. 14(22), pages 1-43, November.
    18. Pei-Nan Ni & Pan Fu & Pei-Pei Chen & Chen Xu & Yi-Yang Xie & Patrice Genevet, 2022. "Spin-decoupling of vertical cavity surface-emitting lasers with complete phase modulation using on-chip integrated Jones matrix metasurfaces," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    19. Kai Peng & Renjie Tao & Louis Haeberlé & Quanwei Li & Dafei Jin & Graham R. Fleming & Stéphane Kéna-Cohen & Xiang Zhang & Wei Bao, 2022. "Room-temperature polariton quantum fluids in halide perovskites," Nature Communications, Nature, vol. 13(1), pages 1-9, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-30701-0. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.