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The Landé factors of electrons and holes in lead halide perovskites: universal dependence on the band gap

Author

Listed:
  • E. Kirstein

    (Experimentelle Physik 2, Technische Universität Dortmund)

  • D. R. Yakovlev

    (Experimentelle Physik 2, Technische Universität Dortmund
    Ioffe Institute, Russian Academy of Sciences)

  • M. M. Glazov

    (Ioffe Institute, Russian Academy of Sciences)

  • E. A. Zhukov

    (Experimentelle Physik 2, Technische Universität Dortmund
    Ioffe Institute, Russian Academy of Sciences)

  • D. Kudlacik

    (Experimentelle Physik 2, Technische Universität Dortmund)

  • I. V. Kalitukha

    (Ioffe Institute, Russian Academy of Sciences)

  • V. F. Sapega

    (Ioffe Institute, Russian Academy of Sciences)

  • G. S. Dimitriev

    (Ioffe Institute, Russian Academy of Sciences)

  • M. A. Semina

    (Ioffe Institute, Russian Academy of Sciences)

  • M. O. Nestoklon

    (Ioffe Institute, Russian Academy of Sciences)

  • E. L. Ivchenko

    (Ioffe Institute, Russian Academy of Sciences)

  • N. E. Kopteva

    (Experimentelle Physik 2, Technische Universität Dortmund)

  • D. N. Dirin

    (ETH Zürich)

  • O. Nazarenko

    (ETH Zürich)

  • M. V. Kovalenko

    (ETH Zürich
    Department of Advanced Materials and Surfaces, Laboratory for Thin Films and Photovoltaics, Empa—Swiss Federal Laboratories for Materials Science and Technology)

  • A. Baumann

    (Experimental Physics VI, Julius-Maximilian University of Würzburg)

  • J. Höcker

    (Experimental Physics VI, Julius-Maximilian University of Würzburg)

  • V. Dyakonov

    (Experimental Physics VI, Julius-Maximilian University of Würzburg)

  • M. Bayer

    (Experimentelle Physik 2, Technische Universität Dortmund
    Ioffe Institute, Russian Academy of Sciences)

Abstract

The Landé or g-factors of charge carriers are decisive for the spin-dependent phenomena in solids and provide also information about the underlying electronic band structure. We present a comprehensive set of experimental data for values and anisotropies of the electron and hole Landé factors in hybrid organic-inorganic (MAPbI3, MAPb(Br0.5Cl0.5)3, MAPb(Br0.05Cl0.95)3, FAPbBr3, FA0.9Cs0.1PbI2.8Br0.2, MA=methylammonium and FA=formamidinium) and all-inorganic (CsPbBr3) lead halide perovskites, determined by pump-probe Kerr rotation and spin-flip Raman scattering in magnetic fields up to 10 T at cryogenic temperatures. Further, we use first-principles density functional theory (DFT) calculations in combination with tight-binding and k ⋅ p approaches to calculate microscopically the Landé factors. The results demonstrate their universal dependence on the band gap energy across the different perovskite material classes, which can be summarized in a universal semi-phenomenological expression, in good agreement with experiment.

Suggested Citation

  • E. Kirstein & D. R. Yakovlev & M. M. Glazov & E. A. Zhukov & D. Kudlacik & I. V. Kalitukha & V. F. Sapega & G. S. Dimitriev & M. A. Semina & M. O. Nestoklon & E. L. Ivchenko & N. E. Kopteva & D. N. Di, 2022. "The Landé factors of electrons and holes in lead halide perovskites: universal dependence on the band gap," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-30701-0
    DOI: 10.1038/s41467-022-30701-0
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    References listed on IDEAS

    as
    1. Haotong Wei & Jinsong Huang, 2019. "Halide lead perovskites for ionizing radiation detection," Nature Communications, Nature, vol. 10(1), pages 1-12, December.
    2. Vasilii V. Belykh & Dmitri R. Yakovlev & Mikhail M. Glazov & Philipp S. Grigoryev & Mujtaba Hussain & Janina Rautert & Dmitry N. Dirin & Maksym V. Kovalenko & Manfred Bayer, 2019. "Coherent spin dynamics of electrons and holes in CsPbBr3 perovskite crystals," Nature Communications, Nature, vol. 10(1), pages 1-6, December.
    3. Vasilii V. Belykh & Dmitri R. Yakovlev & Mikhail M. Glazov & Philipp S. Grigoryev & Mujtaba Hussain & Janina Rautert & Dmitry N. Dirin & Maksym V. Kovalenko & Manfred Bayer, 2019. "Author Correction: Coherent spin dynamics of electrons and holes in CsPbBr3 perovskite crystals," Nature Communications, Nature, vol. 10(1), pages 1-1, December.
    4. Jingying Wang & Chuang Zhang & Haoliang Liu & Ryan McLaughlin & Yaxin Zhai & Shai R. Vardeny & Xiaojie Liu & Stephen McGill & Dmitry Semenov & Hangwen Guo & Ryuichi Tsuchikawa & Vikram V. Deshpande & , 2019. "Spin-optoelectronic devices based on hybrid organic-inorganic trihalide perovskites," Nature Communications, Nature, vol. 10(1), pages 1-6, December.
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    Cited by:

    1. E. Kirstein & N. E. Kopteva & D. R. Yakovlev & E. A. Zhukov & E. V. Kolobkova & M. S. Kuznetsova & V. V. Belykh & I. A. Yugova & M. M. Glazov & M. Bayer & A. Greilich, 2023. "Mode locking of hole spin coherences in CsPb(Cl, Br)3 perovskite nanocrystals," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
    2. Junqing Xu & Kejun Li & Uyen N. Huynh & Mayada Fadel & Jinsong Huang & Ravishankar Sundararaman & Valy Vardeny & Yuan Ping, 2024. "How spin relaxes and dephases in bulk halide perovskites," Nature Communications, Nature, vol. 15(1), pages 1-13, December.

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