IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v13y2022i1d10.1038_s41467-022-29253-0.html
   My bibliography  Save this article

Perovskite metasurfaces with large superstructural chirality

Author

Listed:
  • Guankui Long

    (Nanyang Technological University
    Nankai University)

  • Giorgio Adamo

    (Nanyang Technological University
    Nanyang Technological University)

  • Jingyi Tian

    (Nanyang Technological University
    Nanyang Technological University)

  • Maciej Klein

    (Nanyang Technological University
    Nanyang Technological University)

  • Harish N. S. Krishnamoorthy

    (Nanyang Technological University
    Nanyang Technological University)

  • Elena Feltri

    (Nanyang Technological University
    Nanyang Technological University
    Politecnico di Milano)

  • Hebin Wang

    (Nankai University)

  • Cesare Soci

    (Nanyang Technological University
    Nanyang Technological University)

Abstract

Recent attempts to synthesize hybrid perovskites with large chirality have been hampered by large size mismatch and weak interaction between their structure and the wavelength of light. Here we adopt a planar nanostructure design to overcome these limitations and realize all-dielectric perovskite metasurfaces with giant superstructural chirality. We identify a direct spectral correspondence between the near- and the far- field chirality, and tune the electric and magnetic multipole moments of the resonant chiral metamolecules to obtain large anisotropy factor of 0.49 and circular dichroism of 6350 mdeg. Simulations show that larger area metasurfaces could yield even higher optical activity, approaching the theoretical limits. Our results clearly demonstrate the advantages of nanostructrure engineering for the implementation of perovskite chiral photonic, optoelectronic, and spintronic devices.

Suggested Citation

  • Guankui Long & Giorgio Adamo & Jingyi Tian & Maciej Klein & Harish N. S. Krishnamoorthy & Elena Feltri & Hebin Wang & Cesare Soci, 2022. "Perovskite metasurfaces with large superstructural chirality," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-29253-0
    DOI: 10.1038/s41467-022-29253-0
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-022-29253-0
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-022-29253-0?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Yang Zhao & Amir N. Askarpour & Liuyang Sun & Jinwei Shi & Xiaoqin Li & Andrea Alù, 2017. "Chirality detection of enantiomers using twisted optical metamaterials," Nature Communications, Nature, vol. 8(1), pages 1-8, April.
    2. Jingying Wang & Chuang Zhang & Haoliang Liu & Ryan McLaughlin & Yaxin Zhai & Shai R. Vardeny & Xiaojie Liu & Stephen McGill & Dmitry Semenov & Hangwen Guo & Ryuichi Tsuchikawa & Vikram V. Deshpande & , 2019. "Spin-optoelectronic devices based on hybrid organic-inorganic trihalide perovskites," Nature Communications, Nature, vol. 10(1), pages 1-6, December.
    3. Shuang Zhang & Jiangfeng Zhou & Yong-Shik Park & Junsuk Rho & Ranjan Singh & Sunghyun Nam & Abul K. Azad & Hou-Tong Chen & Xiaobo Yin & Antoinette J. Taylor & Xiang Zhang, 2012. "Photoinduced handedness switching in terahertz chiral metamolecules," Nature Communications, Nature, vol. 3(1), pages 1-7, January.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Ufuk Kilic & Matthew Hilfiker & Shawn Wimer & Alexander Ruder & Eva Schubert & Mathias Schubert & Christos Argyropoulos, 2024. "Controlling the broadband enhanced light chirality with L-shaped dielectric metamaterials," Nature Communications, Nature, vol. 15(1), pages 1-10, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Chi Zhang & Huatian Hu & Chunmiao Ma & Yawen Li & Xujie Wang & Dongyao Li & Artur Movsesyan & Zhiming Wang & Alexander Govorov & Quan Gan & Tao Ding, 2024. "Quantum plasmonics pushes chiral sensing limit to single molecules: a paradigm for chiral biodetections," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    2. Xueli Yang & Ankang Guo & Jie Yang & Jinyang Chen & Ke Meng & Shunhua Hu & Ran Duan & Mingliang Zhu & Wenkang Shi & Yang Qin & Rui Zhang & Haijun Yang & Jikun Li & Lidan Guo & Xiangnan Sun & Yunqi Liu, 2024. "Halogenated-edge polymeric semiconductor for efficient spin transport," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    3. E. Kirstein & N. E. Kopteva & D. R. Yakovlev & E. A. Zhukov & E. V. Kolobkova & M. S. Kuznetsova & V. V. Belykh & I. A. Yugova & M. M. Glazov & M. Bayer & A. Greilich, 2023. "Mode locking of hole spin coherences in CsPb(Cl, Br)3 perovskite nanocrystals," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
    4. Geon Yeong Kim & Shinho Kim & Ki Hyun Park & Hanhwi Jang & Moohyun Kim & Tae Won Nam & Kyeong Min Song & Hongjoo Shin & Yemin Park & Yeongin Cho & Jihyeon Yeom & Min-Jae Choi & Min Seok Jang & Yeon Si, 2024. "Chiral 3D structures through multi-dimensional transfer printing of multilayer quantum dot patterns," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    5. Sunihl Ma & Young-Kwang Jung & Jihoon Ahn & Jihoon Kyhm & Jeiwan Tan & Hyungsoo Lee & Gyumin Jang & Chan Uk Lee & Aron Walsh & Jooho Moon, 2022. "Elucidating the origin of chiroptical activity in chiral 2D perovskites through nano-confined growth," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    6. Sean A. Bourelle & Franco V. A. Camargo & Soumen Ghosh & Timo Neumann & Tim W. J. Goor & Ravichandran Shivanna & Thomas Winkler & Giulio Cerullo & Felix Deschler, 2022. "Optical control of exciton spin dynamics in layered metal halide perovskites via polaronic state formation," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    7. Yijie Shen & Zhensong Wan & Xing Fu & Mali Gong & Xilin Yang & Ruoyang Qi & Mali Gong, 2018. "Recent Advances on Tunable Vortex Beam Devices for Biomedical Applications," Biomedical Journal of Scientific & Technical Research, Biomedical Research Network+, LLC, vol. 9(3), pages 7134-7138, September.
    8. Sungwook Choi & Sang Won Im & Ji-Hyeok Huh & Sungwon Kim & Jaeseung Kim & Yae-Chan Lim & Ryeong Myeong Kim & Jeong Hyun Han & Hyeohn Kim & Michael Sprung & Su Yong Lee & Wonsuk Cha & Ross Harder & Seu, 2023. "Strain and crystallographic identification of the helically concaved gap surfaces of chiral nanoparticles," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    9. Jason Soric & Younes Ra’di & Diego Farfan & Andrea Alù, 2022. "Radio-transparent dipole antenna based on a metasurface cloak," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    10. E. Kirstein & D. R. Yakovlev & M. M. Glazov & E. A. Zhukov & D. Kudlacik & I. V. Kalitukha & V. F. Sapega & G. S. Dimitriev & M. A. Semina & M. O. Nestoklon & E. L. Ivchenko & N. E. Kopteva & D. N. Di, 2022. "The Landé factors of electrons and holes in lead halide perovskites: universal dependence on the band gap," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    11. Pei-Nan Ni & Pan Fu & Pei-Pei Chen & Chen Xu & Yi-Yang Xie & Patrice Genevet, 2022. "Spin-decoupling of vertical cavity surface-emitting lasers with complete phase modulation using on-chip integrated Jones matrix metasurfaces," Nature Communications, Nature, vol. 13(1), pages 1-10, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-29253-0. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.