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Self-organized hetero-nanodomains actuating super Li+ conduction in glass ceramics

Author

Listed:
  • Yantao Wang

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Hongtao Qu

    (Radboud University)

  • Bowen Liu

    (Tianjin University of Technology)

  • Xiaoju Li

    (Shandong University)

  • Jiangwei Ju

    (Chinese Academy of Sciences)

  • Jiedong Li

    (Chinese Academy of Sciences)

  • Shu Zhang

    (Chinese Academy of Sciences)

  • Jun Ma

    (Chinese Academy of Sciences)

  • Chao Li

    (Tianjin University of Technology)

  • Zhiwei Hu

    (Max Plank Institute for Chemical Physics of Solids)

  • Chung-Kai Chang

    (National Synchrotron Radiation Research Center)

  • Hwo-Shuenn Sheu

    (National Synchrotron Radiation Research Center)

  • Longfei Cui

    (Chinese Academy of Sciences)

  • Feng Jiang

    (Chinese Academy of Sciences)

  • Ernst R. H. Eck

    (Radboud University)

  • Arno P. M. Kentgens

    (Radboud University)

  • Guanglei Cui

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Liquan Chen

    (Chinese Academy of Sciences)

Abstract

Easy-to-manufacture Li2S-P2S5 glass ceramics are the key to large-scale all-solid-state lithium batteries from an industrial point of view, while their commercialization is greatly hampered by the low room temperature Li+ conductivity, especially due to the lack of solutions. Herein, we propose a nanocrystallization strategy to fabricate super Li+-conductive glass ceramics. Through regulating the nucleation energy, the crystallites within glass ceramics can self-organize into hetero-nanodomains during the solid-state reaction. Cryogenic transmission electron microscope and electron holography directly demonstrate the numerous closely spaced grain boundaries with enriched charge carriers, which actuate superior Li+-conduction as confirmed by variable-temperature solid-state nuclear magnetic resonance. Glass ceramics with a record Li+ conductivity of 13.2 mS cm−1 are prepared. The high Li+ conductivity ensures stable operation of a 220 μm thick LiNi0.6Mn0.2Co0.2O2 composite cathode (8 mAh cm−2), with which the all-solid-state lithium battery reaches a high energy density of 420 Wh kg−1 by cell mass and 834 Wh L−1 by cell volume at room temperature. These findings bring about powerful new degrees of freedom for engineering super ionic conductors.

Suggested Citation

  • Yantao Wang & Hongtao Qu & Bowen Liu & Xiaoju Li & Jiangwei Ju & Jiedong Li & Shu Zhang & Jun Ma & Chao Li & Zhiwei Hu & Chung-Kai Chang & Hwo-Shuenn Sheu & Longfei Cui & Feng Jiang & Ernst R. H. Eck , 2023. "Self-organized hetero-nanodomains actuating super Li+ conduction in glass ceramics," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-35982-7
    DOI: 10.1038/s41467-023-35982-7
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    References listed on IDEAS

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