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4D printing of MXene hydrogels for high-efficiency pseudocapacitive energy storage

Author

Listed:
  • Ke Li

    (Trinity College Dublin
    Trinity College Dublin)

  • Juan Zhao

    (Trinity College Dublin
    Trinity College Dublin)

  • Ainur Zhussupbekova

    (Trinity College Dublin
    Trinity College Dublin)

  • Christopher E. Shuck

    (Drexel University)

  • Lucia Hughes

    (Trinity College Dublin
    Trinity College Dublin)

  • Yueyao Dong

    (Trinity College Dublin)

  • Sebastian Barwich

    (Trinity College Dublin)

  • Sebastien Vaesen

    (Trinity College Dublin
    Trinity College Dublin)

  • Igor V. Shvets

    (Trinity College Dublin)

  • Matthias Möbius

    (Trinity College Dublin)

  • Wolfgang Schmitt

    (Trinity College Dublin
    Trinity College Dublin)

  • Yury Gogotsi

    (Drexel University)

  • Valeria Nicolosi

    (Trinity College Dublin
    Trinity College Dublin)

Abstract

2D material hydrogels have recently sparked tremendous interest owing to their potential in diverse applications. However, research on the emerging 2D MXene hydrogels is still in its infancy. Herein, we show a universal 4D printing technology for manufacturing MXene hydrogels with customizable geometries, which suits a family of MXenes such as Nb2CTx, Ti3C2Tx, and Mo2Ti2C3Tx. The obtained MXene hydrogels offer 3D porous architectures, large specific surface areas, high electrical conductivities, and satisfying mechanical properties. Consequently, ultrahigh capacitance (3.32 F cm−2 (10 mV s−1) and 233 F g−1 (10 V s−1)) and mass loading/thickness-independent rate capabilities are achieved. The further 4D-printed Ti3C2Tx hydrogel micro-supercapacitors showcase great low-temperature tolerance (down to –20 °C) and deliver high energy and power densities up to 93 μWh cm−2 and 7 mW cm−2, respectively, surpassing most state-of-the-art devices. This work brings new insights into MXene hydrogel manufacturing and expands the range of their potential applications.

Suggested Citation

  • Ke Li & Juan Zhao & Ainur Zhussupbekova & Christopher E. Shuck & Lucia Hughes & Yueyao Dong & Sebastian Barwich & Sebastien Vaesen & Igor V. Shvets & Matthias Möbius & Wolfgang Schmitt & Yury Gogotsi , 2022. "4D printing of MXene hydrogels for high-efficiency pseudocapacitive energy storage," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-34583-0
    DOI: 10.1038/s41467-022-34583-0
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    References listed on IDEAS

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    1. Maria R. Lukatskaya & Sankalp Kota & Zifeng Lin & Meng-Qiang Zhao & Netanel Shpigel & Mikhael D. Levi & Joseph Halim & Pierre-Louis Taberna & Michel W. Barsoum & Patrice Simon & Yury Gogotsi, 2017. "Ultra-high-rate pseudocapacitive energy storage in two-dimensional transition metal carbides," Nature Energy, Nature, vol. 2(8), pages 1-6, August.
    2. Yu Xia & Tyler S. Mathis & Meng-Qiang Zhao & Babak Anasori & Alei Dang & Zehang Zhou & Hyesung Cho & Yury Gogotsi & Shu Yang, 2018. "Thickness-independent capacitance of vertically aligned liquid-crystalline MXenes," Nature, Nature, vol. 557(7705), pages 409-412, May.
    3. Xiang Gao & Xuan Du & Tyler S. Mathis & Mengmeng Zhang & Xuehang Wang & Jianglan Shui & Yury Gogotsi & Ming Xu, 2020. "Maximizing ion accessibility in MXene-knotted carbon nanotube composite electrodes for high-rate electrochemical energy storage," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    4. Xuehang Wang & Tyler S. Mathis & Ke Li & Zifeng Lin & Lukas Vlcek & Takeshi Torita & Naresh C. Osti & Christine Hatter & Patrick Urbankowski & Asia Sarycheva & Madhusudan Tyagi & Eugene Mamontov & Pat, 2019. "Influences from solvents on charge storage in titanium carbide MXenes," Nature Energy, Nature, vol. 4(3), pages 241-248, March.
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    Cited by:

    1. Ming Yang & Lufang Wang & Wenliang Liu & Wenlong Li & Yewei Huang & Qiaofeng Jin & Li Zhang & Yuanwen Jiang & Zhiqiang Luo, 2024. "Highly-stable, injectable, conductive hydrogel for chronic neuromodulation," Nature Communications, Nature, vol. 15(1), pages 1-14, December.

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