IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v15y2022i3p1191-d743205.html
   My bibliography  Save this article

Aligned Ti 3 C 2 T X Aerogel with High Rate Performance, Power Density and Sub-Zero-Temperature Stability

Author

Listed:
  • Xinchao Lu

    (State Key Laboratory of Clean Energy Utilization, College of Energy Engineering, Zhejiang University, Hangzhou 310027, China
    Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University, Hangzhou 311200, China)

  • Huachao Yang

    (State Key Laboratory of Clean Energy Utilization, College of Energy Engineering, Zhejiang University, Hangzhou 310027, China
    Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University, Hangzhou 311200, China)

  • Zheng Bo

    (State Key Laboratory of Clean Energy Utilization, College of Energy Engineering, Zhejiang University, Hangzhou 310027, China
    Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University, Hangzhou 311200, China)

  • Biyao Gong

    (State Key Laboratory of Clean Energy Utilization, College of Energy Engineering, Zhejiang University, Hangzhou 310027, China
    Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University, Hangzhou 311200, China)

  • Mengyu Cao

    (State Key Laboratory of Clean Energy Utilization, College of Energy Engineering, Zhejiang University, Hangzhou 310027, China
    Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University, Hangzhou 311200, China)

  • Xia Chen

    (State Key Laboratory of Clean Energy Utilization, College of Energy Engineering, Zhejiang University, Hangzhou 310027, China
    Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University, Hangzhou 311200, China)

  • Erka Wu

    (Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University, Hangzhou 311200, China)

  • Jianhua Yan

    (State Key Laboratory of Clean Energy Utilization, College of Energy Engineering, Zhejiang University, Hangzhou 310027, China
    Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University, Hangzhou 311200, China)

  • Kefa Cen

    (State Key Laboratory of Clean Energy Utilization, College of Energy Engineering, Zhejiang University, Hangzhou 310027, China
    Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University, Hangzhou 311200, China)

  • Kostya (Ken) Ostrikov

    (State Key Laboratory of Clean Energy Utilization, College of Energy Engineering, Zhejiang University, Hangzhou 310027, China
    School of Chemistry and Physics, Queensland University of Technology, Brisbane, QLD 4000, Australia
    Centre for Materials Science, Queensland University of Technology, Brisbane, QLD 4000, Australia)

Abstract

Ti 3 C 2 T x -based aerogels have attracted widespread attention for three-dimensional porous structures, which are promising to realize high-rate energy storage. However, disordered Ti 3 C 2 T x aerogels with highly tortuous porosity fabricated by conventional unidirectional freeze-casting substantially increase ion diffusion lengths and hinder electrolyte ions transport. Herein we demonstrate a new bidirectional ice-templated approach to synthesize porous ordered Ti 3 C 2 T x aerogel with straight and aligned channels, straight and short ion diffusion pathways, leading to better ion accessibility. The aligned Ti 3 C 2 T x aerogel exhibits the high specific capacitance of 345 F g −1 at 20 mV s −1 and rate capability of 52.2% from 10 to 5000 mV s −1 . The specific capacitance is insensitive of mass loadings even at 10 mg cm −2 and an excellent power density of 137.3 mW cm –2 is obtained in symmetric supercapacitors. The electrochemical properties of Ti 3 C 2 T x aerogel supercapacitors at sub-zero (to −30 °C) temperatures are reported for the first time. The aligned Ti 3 C 2 T x aerogel delivers temperature-independent rate performance and high capacitance retention (73% at 50 mV s −1 from 25 to −30 °C) due to the unique structure with metallic conductivity.

Suggested Citation

  • Xinchao Lu & Huachao Yang & Zheng Bo & Biyao Gong & Mengyu Cao & Xia Chen & Erka Wu & Jianhua Yan & Kefa Cen & Kostya (Ken) Ostrikov, 2022. "Aligned Ti 3 C 2 T X Aerogel with High Rate Performance, Power Density and Sub-Zero-Temperature Stability," Energies, MDPI, vol. 15(3), pages 1-12, February.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:3:p:1191-:d:743205
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/15/3/1191/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/15/3/1191/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Maria R. Lukatskaya & Sankalp Kota & Zifeng Lin & Meng-Qiang Zhao & Netanel Shpigel & Mikhael D. Levi & Joseph Halim & Pierre-Louis Taberna & Michel W. Barsoum & Patrice Simon & Yury Gogotsi, 2017. "Ultra-high-rate pseudocapacitive energy storage in two-dimensional transition metal carbides," Nature Energy, Nature, vol. 2(8), pages 1-6, August.
    2. Yu Xia & Tyler S. Mathis & Meng-Qiang Zhao & Babak Anasori & Alei Dang & Zehang Zhou & Hyesung Cho & Yury Gogotsi & Shu Yang, 2018. "Thickness-independent capacitance of vertically aligned liquid-crystalline MXenes," Nature, Nature, vol. 557(7705), pages 409-412, May.
    3. Xuehang Wang & Tyler S. Mathis & Ke Li & Zifeng Lin & Lukas Vlcek & Takeshi Torita & Naresh C. Osti & Christine Hatter & Patrick Urbankowski & Asia Sarycheva & Madhusudan Tyagi & Eugene Mamontov & Pat, 2019. "Influences from solvents on charge storage in titanium carbide MXenes," Nature Energy, Nature, vol. 4(3), pages 241-248, March.
    4. Ruiyuan Tian & Sang-Hoon Park & Paul J. King & Graeme Cunningham & João Coelho & Valeria Nicolosi & Jonathan N. Coleman, 2019. "Quantifying the factors limiting rate performance in battery electrodes," Nature Communications, Nature, vol. 10(1), pages 1-11, December.
    5. Tomasz N. Kołtunowicz & Piotr Gałaszkiewicz & Konrad Kierczyński & Przemysław Rogalski & Paweł Okal & Alexander D. Pogrebnjak & Vladimir Buranich & Maksym Pogorielov & Kateryna Diedkova & Veronika Zah, 2021. "Investigation of AC Electrical Properties of MXene-PCL Nanocomposites for Application in Small and Medium Power Generation," Energies, MDPI, vol. 14(21), pages 1-21, November.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ke Li & Juan Zhao & Ainur Zhussupbekova & Christopher E. Shuck & Lucia Hughes & Yueyao Dong & Sebastian Barwich & Sebastien Vaesen & Igor V. Shvets & Matthias Möbius & Wolfgang Schmitt & Yury Gogotsi , 2022. "4D printing of MXene hydrogels for high-efficiency pseudocapacitive energy storage," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    2. Changjae Lee & Soon Mo Park & Soobin Kim & Yun-Seok Choi & Geonhyeong Park & Yun Chan Kang & Chong Min Koo & Seon Joon Kim & Dong Ki Yoon, 2022. "Field-induced orientational switching produces vertically aligned Ti3C2Tx MXene nanosheets," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    3. Pandey, Mayank & Deshmukh, Kalim & Raman, Akhila & Asok, Aparna & Appukuttan, Saritha & Suman, G.R., 2024. "Prospects of MXene and graphene for energy storage and conversion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PB).
    4. Entwistle, Jake & Ge, Ruihuan & Pardikar, Kunal & Smith, Rachel & Cumming, Denis, 2022. "Carbon binder domain networks and electrical conductivity in lithium-ion battery electrodes: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 166(C).
    5. Bandara, T.G. Thusitha Asela & Viera, J.C. & González, M., 2022. "The next generation of fast charging methods for Lithium-ion batteries: The natural current-absorption methods," Renewable and Sustainable Energy Reviews, Elsevier, vol. 162(C).
    6. Cian Gabbett & Luke Doolan & Kevin Synnatschke & Laura Gambini & Emmet Coleman & Adam G. Kelly & Shixin Liu & Eoin Caffrey & Jose Munuera & Catriona Murphy & Stefano Sanvito & Lewys Jones & Jonathan N, 2024. "Quantitative analysis of printed nanostructured networks using high-resolution 3D FIB-SEM nanotomography," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    7. Hatherall, Ollie & Barai, Anup & Niri, Mona Faraji & Wang, Zeyuan & Marco, James, 2024. "Novel battery power capability assessment for improved eVTOL aircraft landing," Applied Energy, Elsevier, vol. 361(C).
    8. Tang, Hong & Jiang, Mengjin & Ren, Erhui & Zhang, Yue & Lai, Xiaoxu & Cui, Ce & Jiang, Shouxiang & Zhou, Mi & Qin, Qin & Guo, Ronghui, 2020. "Integrate electrical conductivity and Li+ ion mobility into hierarchical heterostructure Ti3C2@CoO/ZnO composites toward high-performance lithium ion storage," Energy, Elsevier, vol. 212(C).
    9. Mailis Lounasvuori & Yangyunli Sun & Tyler S. Mathis & Ljiljana Puskar & Ulrich Schade & De-En Jiang & Yury Gogotsi & Tristan Petit, 2023. "Vibrational signature of hydrated protons confined in MXene interlayers," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    10. Tianze Zhang & Libo Chang & Xiaofeng Zhang & Hujie Wan & Na Liu & Liujiang Zhou & Xu Xiao, 2022. "Simultaneously tuning interlayer spacing and termination of MXenes by Lewis-basic halides," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    11. Yongjiu Yuan & Xin Li & Lan Jiang & Misheng Liang & Xueqiang Zhang & Shouyu Wu & Junrui Wu & Mengyao Tian & Yang Zhao & Liangti Qu, 2023. "Laser maskless fast patterning for multitype microsupercapacitors," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    12. Heba Ahmed & Hossein Alijani & Ahmed El-Ghazaly & Joseph Halim & Billy J. Murdoch & Yemima Ehrnst & Emily Massahud & Amgad R. Rezk & Johanna Rosen & Leslie Y. Yeo, 2023. "Recovery of oxidized two-dimensional MXenes through high frequency nanoscale electromechanical vibration," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    13. Wu, Bin & Zhang, Buyi & Deng, Changyu & Lu, Wei, 2022. "Physics-encoded deep learning in identifying battery parameters without direct knowledge of ground truth," Applied Energy, Elsevier, vol. 321(C).
    14. Saxena, Shatakshi & Johnson, Michael & Dixit, Fuhar & Zimmermann, Karl & Chaudhuri, Shreya & Kaka, Fiyanshu & Kandasubramanian, Balasubramanian, 2023. "Thinking green with 2-D and 3-D MXenes: Environment friendly synthesis and industrial scale applications and global impact," Renewable and Sustainable Energy Reviews, Elsevier, vol. 178(C).
    15. Zhang, Fan & Jia, Zirui & Wang, Chao & Feng, Ailing & Wang, Kuikui & Hou, Tianqi & Liu, Jiajia & Zhang, Yi & Wu, Guanglei, 2020. "Sandwich-like silicon/Ti3C2Tx MXene composite by electrostatic self-assembly for high performance lithium ion battery," Energy, Elsevier, vol. 195(C).
    16. Tholkappiyan Ramachandran & Abdel-Hamid Ismail Mourad & Mostafa S. A. ElSayed, 2023. "Nb 2 CT x -Based MXenes Most Recent Developments: From Principles to New Applications," Energies, MDPI, vol. 16(8), pages 1-27, April.
    17. Marc Brunet Cabré & Dahnan Spurling & Pietro Martinuz & Mariangela Longhi & Christian Schröder & Hugo Nolan & Valeria Nicolosi & Paula E. Colavita & Kim McKelvey, 2023. "Isolation of pseudocapacitive surface processes at monolayer MXene flakes reveals delocalized charging mechanism," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
    18. Khabibulla A. Abdullin & Maratbek T. Gabdullin & Zhanar K. Kalkozova & Shyryn T. Nurbolat & Mojtaba Mirzaeian, 2023. "Symmetrical Composite Supercapacitor Based on Activated Carbon and Cobalt Nanoparticles with High Cyclic Stability and Current Load," Energies, MDPI, vol. 16(11), pages 1-19, May.
    19. Kunwar, Ria & Pal, Bhupender & Izwan Misnon, Izan & Daniyal, Hamdan & Zabihi, Fatemeh & Yang, Shengyuan & Sofer, Zděnek & Yang, Chun-Chen & Jose, Rajan, 2023. "Characterization of electrochemical double layer capacitor electrode using self-discharge measurements and modeling," Applied Energy, Elsevier, vol. 334(C).
    20. Yongjiu Lei & Wenli Zhao & Jun Yin & Yinchang Ma & Zhiming Zhao & Jian Yin & Yusuf Khan & Mohamed Nejib Hedhili & Long Chen & Qingxiao Wang & Youyou Yuan & Xixiang Zhang & Osman M. Bakr & Omar F. Moha, 2023. "Discovery of a three-proton insertion mechanism in α-molybdenum trioxide leading to enhanced charge storage capacity," Nature Communications, Nature, vol. 14(1), pages 1-11, December.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:15:y:2022:i:3:p:1191-:d:743205. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.