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Aligned Ti 3 C 2 T X Aerogel with High Rate Performance, Power Density and Sub-Zero-Temperature Stability

Author

Listed:
  • Xinchao Lu

    (State Key Laboratory of Clean Energy Utilization, College of Energy Engineering, Zhejiang University, Hangzhou 310027, China
    Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University, Hangzhou 311200, China)

  • Huachao Yang

    (State Key Laboratory of Clean Energy Utilization, College of Energy Engineering, Zhejiang University, Hangzhou 310027, China
    Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University, Hangzhou 311200, China)

  • Zheng Bo

    (State Key Laboratory of Clean Energy Utilization, College of Energy Engineering, Zhejiang University, Hangzhou 310027, China
    Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University, Hangzhou 311200, China)

  • Biyao Gong

    (State Key Laboratory of Clean Energy Utilization, College of Energy Engineering, Zhejiang University, Hangzhou 310027, China
    Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University, Hangzhou 311200, China)

  • Mengyu Cao

    (State Key Laboratory of Clean Energy Utilization, College of Energy Engineering, Zhejiang University, Hangzhou 310027, China
    Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University, Hangzhou 311200, China)

  • Xia Chen

    (State Key Laboratory of Clean Energy Utilization, College of Energy Engineering, Zhejiang University, Hangzhou 310027, China
    Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University, Hangzhou 311200, China)

  • Erka Wu

    (Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University, Hangzhou 311200, China)

  • Jianhua Yan

    (State Key Laboratory of Clean Energy Utilization, College of Energy Engineering, Zhejiang University, Hangzhou 310027, China
    Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University, Hangzhou 311200, China)

  • Kefa Cen

    (State Key Laboratory of Clean Energy Utilization, College of Energy Engineering, Zhejiang University, Hangzhou 310027, China
    Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University, Hangzhou 311200, China)

  • Kostya (Ken) Ostrikov

    (State Key Laboratory of Clean Energy Utilization, College of Energy Engineering, Zhejiang University, Hangzhou 310027, China
    School of Chemistry and Physics, Queensland University of Technology, Brisbane, QLD 4000, Australia
    Centre for Materials Science, Queensland University of Technology, Brisbane, QLD 4000, Australia)

Abstract

Ti 3 C 2 T x -based aerogels have attracted widespread attention for three-dimensional porous structures, which are promising to realize high-rate energy storage. However, disordered Ti 3 C 2 T x aerogels with highly tortuous porosity fabricated by conventional unidirectional freeze-casting substantially increase ion diffusion lengths and hinder electrolyte ions transport. Herein we demonstrate a new bidirectional ice-templated approach to synthesize porous ordered Ti 3 C 2 T x aerogel with straight and aligned channels, straight and short ion diffusion pathways, leading to better ion accessibility. The aligned Ti 3 C 2 T x aerogel exhibits the high specific capacitance of 345 F g −1 at 20 mV s −1 and rate capability of 52.2% from 10 to 5000 mV s −1 . The specific capacitance is insensitive of mass loadings even at 10 mg cm −2 and an excellent power density of 137.3 mW cm –2 is obtained in symmetric supercapacitors. The electrochemical properties of Ti 3 C 2 T x aerogel supercapacitors at sub-zero (to −30 °C) temperatures are reported for the first time. The aligned Ti 3 C 2 T x aerogel delivers temperature-independent rate performance and high capacitance retention (73% at 50 mV s −1 from 25 to −30 °C) due to the unique structure with metallic conductivity.

Suggested Citation

  • Xinchao Lu & Huachao Yang & Zheng Bo & Biyao Gong & Mengyu Cao & Xia Chen & Erka Wu & Jianhua Yan & Kefa Cen & Kostya (Ken) Ostrikov, 2022. "Aligned Ti 3 C 2 T X Aerogel with High Rate Performance, Power Density and Sub-Zero-Temperature Stability," Energies, MDPI, vol. 15(3), pages 1-12, February.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:3:p:1191-:d:743205
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    References listed on IDEAS

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