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Characterization of electrochemical double layer capacitor electrode using self-discharge measurements and modeling

Author

Listed:
  • Kunwar, Ria
  • Pal, Bhupender
  • Izwan Misnon, Izan
  • Daniyal, Hamdan
  • Zabihi, Fatemeh
  • Yang, Shengyuan
  • Sofer, Zděnek
  • Yang, Chun-Chen
  • Jose, Rajan

Abstract

A simple protocol to characterize the electrochemical double layer capacitors (EDLCs) using self-discharge (open circuit discharge) data and a three-branch electrical model is presented. The method relies on recording the self-discharge data of EDLCs and using it to estimate the parametric values of the variables in the model (time constants, maximum voltage, resistances, and capacitances). Porous carbon and metal oxide electrodes in three choice electrolytes are used for the experiments and the simulations are performed using MATLAB Simulink platform. The simulated and experimental self-discharge data are in close agreement for the EDLC storage mode but not for the battery type storage. The results are further validated by simulating the galvanostatic charge discharge (GCD) cycling data and fitting them to the experimental GCD of the assembled devices with high accuracies. The model presented here thus enables determination of charge storage parameters as well as whether a device is capacitive from a single self-discharge data, thereby providing an excellent tool to characterize EDLCs for both academia and industry.

Suggested Citation

  • Kunwar, Ria & Pal, Bhupender & Izwan Misnon, Izan & Daniyal, Hamdan & Zabihi, Fatemeh & Yang, Shengyuan & Sofer, Zděnek & Yang, Chun-Chen & Jose, Rajan, 2023. "Characterization of electrochemical double layer capacitor electrode using self-discharge measurements and modeling," Applied Energy, Elsevier, vol. 334(C).
    • Handle: RePEc:eee:appene:v:334:y:2023:i:c:s0306261923000223
    DOI: 10.1016/j.apenergy.2023.120658
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    References listed on IDEAS

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    1. Mingant, R. & Bernard, J. & Sauvant-Moynot, V., 2016. "Novel state-of-health diagnostic method for Li-ion battery in service," Applied Energy, Elsevier, vol. 183(C), pages 390-398.
    2. Zineb Cabrane & Soo Hyoung Lee, 2022. "Electrical and Mathematical Modeling of Supercapacitors: Comparison," Energies, MDPI, vol. 15(3), pages 1-12, January.
    3. Alexander C. Forse & John M. Griffin & Céline Merlet & Javier Carretero-Gonzalez & Abdul-Rahman O. Raji & Nicole M. Trease & Clare P. Grey, 2017. "Direct observation of ion dynamics in supercapacitor electrodes using in situ diffusion NMR spectroscopy," Nature Energy, Nature, vol. 2(3), pages 1-7, March.
    4. Krishnan, Syam G. & Arulraj, Arunachalam & Khalid, Mohammad & Reddy, M.V. & Jose, Rajan, 2021. "Energy storage in metal cobaltite electrodes: Opportunities & challenges in magnesium cobalt oxide," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).
    5. Maria R. Lukatskaya & Sankalp Kota & Zifeng Lin & Meng-Qiang Zhao & Netanel Shpigel & Mikhael D. Levi & Joseph Halim & Pierre-Louis Taberna & Michel W. Barsoum & Patrice Simon & Yury Gogotsi, 2017. "Ultra-high-rate pseudocapacitive energy storage in two-dimensional transition metal carbides," Nature Energy, Nature, vol. 2(8), pages 1-6, August.
    6. Sang-Eun Chun & Brian Evanko & Xingfeng Wang & David Vonlanthen & Xiulei Ji & Galen D. Stucky & Shannon W. Boettcher, 2015. "Design of aqueous redox-enhanced electrochemical capacitors with high specific energies and slow self-discharge," Nature Communications, Nature, vol. 6(1), pages 1-10, November.
    7. Pal, Bhupender & Yasin, Amina & Kaur, Rupinder & Tebyetekerwa, Mike & Zabihi, Fatemeh & Yang, Shengyuan & Yang, Chun-Chen & Sofer, Zděnek & Jose, Rajan, 2021. "Understanding electrochemical capacitors with in-situ techniques," Renewable and Sustainable Energy Reviews, Elsevier, vol. 149(C).
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