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Predictive control of selective secondary alcohol oxidation of glycerol on NiOOH

Author

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  • McKenna K. Goetz

    (University of Wisconsin-Madison)

  • Michael T. Bender

    (University of Wisconsin-Madison)

  • Kyoung-Shin Choi

    (University of Wisconsin-Madison)

Abstract

Many biomass intermediates are polyols and selectively oxidizing only a primary or secondary alcohol group is beneficial for the valorization of these intermediates. For example, production of 1,3-dihydroxyacetone, a highly valuable oxidation product of glycerol, requires selective secondary alcohol oxidation. However, selective secondary alcohol oxidation is challenging due to its steric disadvantage. This study demonstrates that NiOOH, which oxidizes alcohols via two dehydrogenation mechanisms, hydrogen atom transfer and hydride transfer, can convert glycerol to 1,3-dihydroxyacetone with high selectivity when the conditions are controlled to promote hydrogen atom transfer, favoring secondary alcohol oxidation. This rational production of 1,3-dihydroxyacetone achieved by selectively enabling one desired dehydrogenation pathway, without requiring alteration of catalyst composition, demonstrates how comprehensive mechanistic understanding can enable predictive control over selectivity.

Suggested Citation

  • McKenna K. Goetz & Michael T. Bender & Kyoung-Shin Choi, 2022. "Predictive control of selective secondary alcohol oxidation of glycerol on NiOOH," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-33637-7
    DOI: 10.1038/s41467-022-33637-7
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    References listed on IDEAS

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    1. Yan Li & Xinfa Wei & Lisong Chen & Jianlin Shi & Mingyuan He, 2019. "Nickel-molybdenum nitride nanoplate electrocatalysts for concurrent electrolytic hydrogen and formate productions," Nature Communications, Nature, vol. 10(1), pages 1-12, December.
    2. Michael T. Bender & Xin Yuan & Kyoung-Shin Choi, 2020. "Alcohol oxidation as alternative anode reactions paired with (photo)electrochemical fuel production reactions," Nature Communications, Nature, vol. 11(1), pages 1-4, December.
    3. Quispe, César A.G. & Coronado, Christian J.R. & Carvalho Jr., João A., 2013. "Glycerol: Production, consumption, prices, characterization and new trends in combustion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 27(C), pages 475-493.
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    Cited by:

    1. Yuan Lu & Byoung Guan Lee & Cheng Lin & Tae-Kyung Liu & Zhipeng Wang & Jiaming Miao & Sang Ho Oh & Ki Chul Kim & Kan Zhang & Jong Hyeok Park, 2024. "Solar-driven highly selective conversion of glycerol to dihydroxyacetone using surface atom engineered BiVO4 photoanodes," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

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