IDEAS home Printed from https://ideas.repec.org/a/eee/rensus/v66y2016icp449-475.html
   My bibliography  Save this article

Potential applications of crude glycerol in polymer technology–Current state and perspectives

Author

Listed:
  • Hejna, Aleksander
  • Kosmela, Paulina
  • Formela, Krzysztof
  • Piszczyk, Łukasz
  • Haponiuk, Józef T.

Abstract

The increasing use of bio-based fuels and fuel additives, among them biodiesel, causes significant surplus of crude glycerol on the market which creates new challenges in terms of its sustainable utilization. A lot of ways for the incorporation of this by-product into different branches of industry requires purification by expensive and complicated processes. Therefore, researchers are seeking for applications of untreated crude glycerol. Among the possibilities, much attention is drawn to the polymer chemistry and technology. This branch of industry is one of the biggest consumers of glycerol after food, pharmaceutical and personal care applications sectors, and probably the biggest one that does not require complicated purification of glycerol resulting from biodiesel technology. Crude glycerol can be applied in the number of processes such as fermentation, oxidation, esterification and transesterification, biomass liquefaction, oligomerization and polymerization, carboxylation, glycerolysis, hydrogenolysis, dehydration or dihydroxylation. This paper summarizes the use of glycerol in polymer technology and the attempts of crude glycerol incorporation into this field reported in literature.

Suggested Citation

  • Hejna, Aleksander & Kosmela, Paulina & Formela, Krzysztof & Piszczyk, Łukasz & Haponiuk, Józef T., 2016. "Potential applications of crude glycerol in polymer technology–Current state and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 66(C), pages 449-475.
    • Handle: RePEc:eee:rensus:v:66:y:2016:i:c:p:449-475
    DOI: 10.1016/j.rser.2016.08.020
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S1364032116304324
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.rser.2016.08.020?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Puri, Munish & Abraham, Reinu E. & Barrow, Colin J., 2012. "Biofuel production: Prospects, challenges and feedstock in Australia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(8), pages 6022-6031.
    2. Gholami, Zahra & Abdullah, Ahmad Zuhairi & Lee, Keat-Teong, 2014. "Dealing with the surplus of glycerol production from biodiesel industry through catalytic upgrading to polyglycerols and other value-added products," Renewable and Sustainable Energy Reviews, Elsevier, vol. 39(C), pages 327-341.
    3. Shota Atsumi & Taizo Hanai & James C. Liao, 2008. "Non-fermentative pathways for synthesis of branched-chain higher alcohols as biofuels," Nature, Nature, vol. 451(7174), pages 86-89, January.
    4. Kenkel, Philip L. & Holcomb, Rodney B., 2008. "Feasibility of on-farm or small scale oilseed processing and biodiesel production," Integration of Agricultural and Energy Systems Conference, February 12-13, 2008, Atlanta, Georgia 48710, Farm Foundation.
    5. Brand, Steffen & Susanti, Ratna Frida & Kim, Seok Ki & Lee, Hong-shik & Kim, Jaehoon & Sang, Byung-In, 2013. "Supercritical ethanol as an enhanced medium for lignocellulosic biomass liquefaction: Influence of physical process parameters," Energy, Elsevier, vol. 59(C), pages 173-182.
    6. Chatzifragkou, Afroditi & Makri, Anna & Belka, Aikaterini & Bellou, Stamatina & Mavrou, Marilena & Mastoridou, Maria & Mystrioti, Paraskevi & Onjaro, Grace & Aggelis, George & Papanikolaou, Seraphim, 2011. "Biotechnological conversions of biodiesel derived waste glycerol by yeast and fungal species," Energy, Elsevier, vol. 36(2), pages 1097-1108.
    7. Azad, A.K. & Rasul, M.G. & Khan, M.M.K. & Sharma, Subhash C. & Hazrat, M.A., 2015. "Prospect of biofuels as an alternative transport fuel in Australia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 331-351.
    8. Pan, Hui, 2011. "Synthesis of polymers from organic solvent liquefied biomass: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(7), pages 3454-3463, September.
    9. Rahmat, Norhasyimi & Abdullah, Ahmad Zuhairi & Mohamed, Abdul Rahman, 2010. "Recent progress on innovative and potential technologies for glycerol transformation into fuel additives: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(3), pages 987-1000, April.
    10. Tan, H.W. & Abdul Aziz, A.R. & Aroua, M.K., 2013. "Glycerol production and its applications as a raw material: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 27(C), pages 118-127.
    11. Quispe, César A.G. & Coronado, Christian J.R. & Carvalho Jr., João A., 2013. "Glycerol: Production, consumption, prices, characterization and new trends in combustion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 27(C), pages 475-493.
    12. Atadashi, I.M. & Aroua, M.K. & Aziz, A. Abdul, 2011. "Biodiesel separation and purification: A review," Renewable Energy, Elsevier, vol. 36(2), pages 437-443.
    13. Ayoub, Muhammad & Abdullah, Ahmad Zuhairi, 2012. "Critical review on the current scenario and significance of crude glycerol resulting from biodiesel industry towards more sustainable renewable energy industry," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 2671-2686.
    14. Leoneti, Alexandre Bevilacqua & Aragão-Leoneti, Valquiria & de Oliveira, Sonia Valle Walter Borges, 2012. "Glycerol as a by-product of biodiesel production in Brazil: Alternatives for the use of unrefined glycerol," Renewable Energy, Elsevier, vol. 45(C), pages 138-145.
    15. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Hezaveh, Hadi, 2014. "Glycerol for renewable acrolein production by catalytic dehydration," Renewable and Sustainable Energy Reviews, Elsevier, vol. 40(C), pages 28-59.
    16. Lee, C.S. & Aroua, M.K. & Daud, W.M.A.W. & Cognet, P. & Pérès-Lucchese, Y. & Fabre, P-L & Reynes, O. & Latapie, L., 2015. "A review: Conversion of bioglycerol into 1,3-propanediol via biological and chemical method," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 963-972.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Chen, Jiaxin & Zhang, Xiaolei & Tyagi, Rajeshwar Dayal, 2021. "Impact of nitrogen on the industrial feasibility of biodiesel production from lipid accumulated in oleaginous yeast with wastewater sludge and crude glycerol," Energy, Elsevier, vol. 217(C).
    2. Okoye, P.U. & Abdullah, A.Z. & Hameed, B.H., 2017. "A review on recent developments and progress in the kinetics and deactivation of catalytic acetylation of glycerol—A byproduct of biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 387-401.
    3. Monteiro, Marcos Roberto & Kugelmeier, Cristie Luis & Pinheiro, Rafael Sanaiotte & Batalha, Mario Otávio & da Silva César, Aldara, 2018. "Glycerol from biodiesel production: Technological paths for sustainability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 88(C), pages 109-122.
    4. Muhammad Harussani Moklis & Shou Cheng & Jeffrey S. Cross, 2023. "Current and Future Trends for Crude Glycerol Upgrading to High Value-Added Products," Sustainability, MDPI, vol. 15(4), pages 1-30, February.
    5. He, Quan (Sophia) & McNutt, Josiah & Yang, Jie, 2017. "Utilization of the residual glycerol from biodiesel production for renewable energy generation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 71(C), pages 63-76.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Monteiro, Marcos Roberto & Kugelmeier, Cristie Luis & Pinheiro, Rafael Sanaiotte & Batalha, Mario Otávio & da Silva César, Aldara, 2018. "Glycerol from biodiesel production: Technological paths for sustainability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 88(C), pages 109-122.
    2. He, Quan (Sophia) & McNutt, Josiah & Yang, Jie, 2017. "Utilization of the residual glycerol from biodiesel production for renewable energy generation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 71(C), pages 63-76.
    3. Okoye, P.U. & Hameed, B.H., 2016. "Review on recent progress in catalytic carboxylation and acetylation of glycerol as a byproduct of biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 558-574.
    4. Kong, Pei San & Aroua, Mohamed Kheireddine & Daud, Wan Mohd Ashri Wan, 2016. "Conversion of crude and pure glycerol into derivatives: A feasibility evaluation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 63(C), pages 533-555.
    5. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Hezaveh, Hadi, 2014. "Glycerol for renewable acrolein production by catalytic dehydration," Renewable and Sustainable Energy Reviews, Elsevier, vol. 40(C), pages 28-59.
    6. Silva, Wellington Costa & Castro, Maria Priscila Pessanha & Perez, Victor Haber & Machado, Francisco A. & Mota, Leonardo & Sthel, Marcelo Silva, 2016. "Thermal degradation of ethanolic biodiesel: Physicochemical and thermal properties evaluation," Energy, Elsevier, vol. 114(C), pages 1093-1099.
    7. Ardi, M.S. & Aroua, M.K. & Hashim, N. Awanis, 2015. "Progress, prospect and challenges in glycerol purification process: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1164-1173.
    8. Muhammad Harussani Moklis & Shou Cheng & Jeffrey S. Cross, 2023. "Current and Future Trends for Crude Glycerol Upgrading to High Value-Added Products," Sustainability, MDPI, vol. 15(4), pages 1-30, February.
    9. Cornejo, A. & Barrio, I. & Campoy, M. & Lázaro, J. & Navarrete, B., 2017. "Oxygenated fuel additives from glycerol valorization. Main production pathways and effects on fuel properties and engine performance: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1400-1413.
    10. Lee, C.S. & Aroua, M.K. & Daud, W.M.A.W. & Cognet, P. & Pérès-Lucchese, Y. & Fabre, P-L & Reynes, O. & Latapie, L., 2015. "A review: Conversion of bioglycerol into 1,3-propanediol via biological and chemical method," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 963-972.
    11. Zhang, Jianan & Wang, Yuesen & Muldoon, Valerie L. & Deng, Sili, 2022. "Crude glycerol and glycerol as fuels and fuel additives in combustion applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 159(C).
    12. Ramalingam, Senthil & Ezhumalai, Manikandan & Govindasamy, Mohan, 2019. "Syngas: Derived from biodiesel and its influence on CI engine," Energy, Elsevier, vol. 189(C).
    13. Mohsin Raza & Abrar Inayat & Basim Abu-Jdayil, 2021. "Crude Glycerol as a Potential Feedstock for Future Energy via Thermochemical Conversion Processes: A Review," Sustainability, MDPI, vol. 13(22), pages 1-27, November.
    14. Lapuerta, Magín & Rodríguez-Fernández, José & García-Contreras, Reyes, 2015. "Effect of a glycerol-derived advanced biofuel –FAGE (fatty acid formal glycerol ester)– on the emissions of a diesel engine tested under the New European Driving Cycle," Energy, Elsevier, vol. 93(P1), pages 568-579.
    15. Mamtani, Kapil & Shahbaz, Kaveh & Farid, Mohammed M., 2021. "Glycerolysis of free fatty acids: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 137(C).
    16. Da Seul Kong & Eun Joo Park & Sakuntala Mutyala & Minsoo Kim & Yunchul Cho & Sang Eun Oh & Changman Kim & Jung Rae Kim, 2021. "Bioconversion of Crude Glycerol into 1,3-Propanediol(1,3-PDO) with Bioelectrochemical System and Zero-Valent Iron Using Klebsiella pneumoniae L17," Energies, MDPI, vol. 14(20), pages 1-10, October.
    17. Francesco Asdrubali & Franco Cotana & Federico Rossi & Andrea Presciutti & Antonella Rotili & Claudia Guattari, 2015. "Life Cycle Assessment of New Oxy-Fuels from Biodiesel-Derived Glycerol," Energies, MDPI, vol. 8(3), pages 1-16, February.
    18. Marta Ramos & Ana Paula Soares Dias & Jaime Filipe Puna & João Gomes & João Carlos Bordado, 2019. "Biodiesel Production Processes and Sustainable Raw Materials," Energies, MDPI, vol. 12(23), pages 1-30, November.
    19. Severo, Ihana Aguiar & Siqueira, Stefania Fortes & Deprá, Mariany Costa & Maroneze, Mariana Manzoni & Zepka, Leila Queiroz & Jacob-Lopes, Eduardo, 2019. "Biodiesel facilities: What can we address to make biorefineries commercially competitive?," Renewable and Sustainable Energy Reviews, Elsevier, vol. 112(C), pages 686-705.
    20. Azad, A.K. & Rasul, M.G. & Khan, M.M.K. & Sharma, Subhash C. & Mofijur, M. & Bhuiya, M.M.K., 2016. "Prospects, feedstocks and challenges of biodiesel production from beauty leaf oil and castor oil: A nonedible oil sources in Australia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 302-318.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:rensus:v:66:y:2016:i:c:p:449-475. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/600126/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.