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Small-molecule ionic liquid-based adhesive with strong room-temperature adhesion promoted by electrostatic interaction

Author

Listed:
  • Jun Zhang

    (Hunan University)

  • Wenxiang Wang

    (Hunan University)

  • Yan Zhang

    (Hunan University)

  • Qiang Wei

    (Hunan University)

  • Fei Han

    (Hunan University)

  • Shengyi Dong

    (Hunan University)

  • Dongqing Liu

    (National University of Defense Technology)

  • Shiguo Zhang

    (Hunan University)

Abstract

Low-molecular-weight adhesives (LMWAs) possess many unique features compared to polymer adhesives. However, fabricating LMWAs with adhesion strengths higher than those of polymeric materials is a significant challenge, mainly because of the relatively weak and unbalanced cohesion and interfacial adhesion. Herein, an ionic liquid (IL)-based adhesive with high adhesion strength is demonstrated by introducing an IL moiety into a Y-shaped molecule replete with hydrogen bonding (H-bonding) interactions. The IL moieties not only destroyed the rigid and ordered H-bonding networks, releasing more free groups to form hydrogen bonds (H-bonds) at the substrate/adhesive interface, but also provided electrostatic interactions that improved the cohesion energy. The synthesized IL-based adhesive, Tri-HT, could directly form thin coatings on various substrates, with high adhesion strengths of up to 12.20 MPa. Advanced adhesives with electrical conductivity, self-healing behavior, and electrically-controlled adhesion could also be fabricated by combining Tri-HT with carbon nanotubes.

Suggested Citation

  • Jun Zhang & Wenxiang Wang & Yan Zhang & Qiang Wei & Fei Han & Shengyi Dong & Dongqing Liu & Shiguo Zhang, 2022. "Small-molecule ionic liquid-based adhesive with strong room-temperature adhesion promoted by electrostatic interaction," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-32997-4
    DOI: 10.1038/s41467-022-32997-4
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    References listed on IDEAS

    as
    1. Wei Zhang & Baohu Wu & Shengtong Sun & Peiyi Wu, 2021. "Skin-like mechanoresponsive self-healing ionic elastomer from supramolecular zwitterionic network," Nature Communications, Nature, vol. 12(1), pages 1-12, December.
    2. Chao Ma & Jing Sun & Bo Li & Yang Feng & Yao Sun & Li Xiang & Baiheng Wu & Lingling Xiao & Baimei Liu & Vladislav S. Petrovskii & Liu & Jinrui Zhang & Zili Wang & Hongyan Li & Lei Zhang & Jingjing Li , 2021. "Ultra-strong bio-glue from genetically engineered polypeptides," Nature Communications, Nature, vol. 12(1), pages 1-14, December.
    3. Anjeza Beharaj & Ethan Z. McCaslin & William A. Blessing & Mark W. Grinstaff, 2019. "Sustainable polycarbonate adhesives for dry and aqueous conditions with thermoresponsive properties," Nature Communications, Nature, vol. 10(1), pages 1-7, December.
    4. Dejin Jiao & Francisco Lossada & Jiaqi Guo & Oliver Skarsetz & Daniel Hoenders & Jin Liu & Andreas Walther, 2021. "Electrical switching of high-performance bioinspired nanocellulose nanocomposites," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
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    Cited by:

    1. Xihao Pan & Rui Li & Wenyue Li & Wei Sun & Yiyang Yan & Xiaochen Xiang & Jinghua Fang & Youguo Liao & Chang Xie & Xiaozhao Wang & Youzhi Cai & Xudong Yao & Hongwei Ouyang, 2024. "Silk fibroin hydrogel adhesive enables sealed-tight reconstruction of meniscus tears," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    2. Jun Zhang & Xuan Zhou & Qinyu Hu & Kaijian Zhou & Yan Zhang & Shengyi Dong & Gai Zhao & Shiguo Zhang, 2024. "Concentration-induced spontaneous polymerization of protic ionic liquids for efficient in situ adhesion," Nature Communications, Nature, vol. 15(1), pages 1-12, December.

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