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NiPS3 ultrathin nanosheets as versatile platform advancing highly active photocatalytic H2 production

Author

Listed:
  • Jingrun Ran

    (University of Adelaide)

  • Hongping Zhang

    (Southwest University of Science and Technology)

  • Sijia Fu

    (University of Adelaide)

  • Mietek Jaroniec

    (Kent State University)

  • Jieqiong Shan

    (University of Adelaide)

  • Bingquan Xia

    (University of Adelaide)

  • Yang Qu

    (Heilongjiang University)

  • Jiangtao Qu

    (The University of Sydney)

  • Shuangming Chen

    (University of Science and Technology of China)

  • Li Song

    (University of Science and Technology of China)

  • Julie M. Cairney

    (The University of Sydney)

  • Liqiang Jing

    (Heilongjiang University)

  • Shi-Zhang Qiao

    (University of Adelaide)

Abstract

High-performance and low-cost photocatalysts play the key role in achieving the large-scale solar hydrogen production. In this work, we report a liquid-exfoliation approach to prepare NiPS3 ultrathin nanosheets as a versatile platform to greatly improve the light-induced hydrogen production on various photocatalysts, including TiO2, CdS, In2ZnS4 and C3N4. The superb visible-light-induced hydrogen production rate (13,600 μmol h−1 g−1) is achieved on NiPS3/CdS hetero-junction with the highest improvement factor (~1,667%) compared with that of pure CdS. This significantly better performance is attributed to the strongly correlated NiPS3/CdS interface assuring efficient electron-hole dissociation/transport, as well as abundant atomic-level edge P/S sites and activated basal S sites on NiPS3 ultrathin nanosheets advancing hydrogen evolution. These findings are revealed by the state-of-art characterizations and theoretical computations. Our work for the first time demonstrates the great potential of metal phosphorous chalcogenide as a general platform to tremendously raise the performance of different photocatalysts.

Suggested Citation

  • Jingrun Ran & Hongping Zhang & Sijia Fu & Mietek Jaroniec & Jieqiong Shan & Bingquan Xia & Yang Qu & Jiangtao Qu & Shuangming Chen & Li Song & Julie M. Cairney & Liqiang Jing & Shi-Zhang Qiao, 2022. "NiPS3 ultrathin nanosheets as versatile platform advancing highly active photocatalytic H2 production," Nature Communications, Nature, vol. 13(1), pages 1-17, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-32256-6
    DOI: 10.1038/s41467-022-32256-6
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    References listed on IDEAS

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    Cited by:

    1. Xin Wang & Boyan Liu & Siqing Ma & Yingjuan Zhang & Lianzhou Wang & Gangqiang Zhu & Wei Huang & Songcan Wang, 2024. "Induced dipole moments in amorphous ZnCdS catalysts facilitate photocatalytic H2 evolution," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

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