IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v13y2022i1d10.1038_s41467-022-32256-6.html
   My bibliography  Save this article

NiPS3 ultrathin nanosheets as versatile platform advancing highly active photocatalytic H2 production

Author

Listed:
  • Jingrun Ran

    (University of Adelaide)

  • Hongping Zhang

    (Southwest University of Science and Technology)

  • Sijia Fu

    (University of Adelaide)

  • Mietek Jaroniec

    (Kent State University)

  • Jieqiong Shan

    (University of Adelaide)

  • Bingquan Xia

    (University of Adelaide)

  • Yang Qu

    (Heilongjiang University)

  • Jiangtao Qu

    (The University of Sydney)

  • Shuangming Chen

    (University of Science and Technology of China)

  • Li Song

    (University of Science and Technology of China)

  • Julie M. Cairney

    (The University of Sydney)

  • Liqiang Jing

    (Heilongjiang University)

  • Shi-Zhang Qiao

    (University of Adelaide)

Abstract

High-performance and low-cost photocatalysts play the key role in achieving the large-scale solar hydrogen production. In this work, we report a liquid-exfoliation approach to prepare NiPS3 ultrathin nanosheets as a versatile platform to greatly improve the light-induced hydrogen production on various photocatalysts, including TiO2, CdS, In2ZnS4 and C3N4. The superb visible-light-induced hydrogen production rate (13,600 μmol h−1 g−1) is achieved on NiPS3/CdS hetero-junction with the highest improvement factor (~1,667%) compared with that of pure CdS. This significantly better performance is attributed to the strongly correlated NiPS3/CdS interface assuring efficient electron-hole dissociation/transport, as well as abundant atomic-level edge P/S sites and activated basal S sites on NiPS3 ultrathin nanosheets advancing hydrogen evolution. These findings are revealed by the state-of-art characterizations and theoretical computations. Our work for the first time demonstrates the great potential of metal phosphorous chalcogenide as a general platform to tremendously raise the performance of different photocatalysts.

Suggested Citation

  • Jingrun Ran & Hongping Zhang & Sijia Fu & Mietek Jaroniec & Jieqiong Shan & Bingquan Xia & Yang Qu & Jiangtao Qu & Shuangming Chen & Li Song & Julie M. Cairney & Liqiang Jing & Shi-Zhang Qiao, 2022. "NiPS3 ultrathin nanosheets as versatile platform advancing highly active photocatalytic H2 production," Nature Communications, Nature, vol. 13(1), pages 1-17, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-32256-6
    DOI: 10.1038/s41467-022-32256-6
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-022-32256-6
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-022-32256-6?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Christian M. Wolff & Peter D. Frischmann & Marcus Schulze & Bernhard J. Bohn & Robin Wein & Panajotis Livadas & Michael T. Carlson & Frank Jäckel & Jochen Feldmann & Frank Würthner & Jacek K. Stolarcz, 2018. "All-in-one visible-light-driven water splitting by combining nanoparticulate and molecular co-catalysts on CdS nanorods," Nature Energy, Nature, vol. 3(10), pages 862-869, October.
    2. Peng Zhou & Hui Chen & Yuguang Chao & Qinghua Zhang & Weiyu Zhang & Fan Lv & Lin Gu & Qiang Zhao & Ning Wang & Jinshu Wang & Shaojun Guo, 2021. "Single-atom Pt-I3 sites on all-inorganic Cs2SnI6 perovskite for efficient photocatalytic hydrogen production," Nature Communications, Nature, vol. 12(1), pages 1-8, December.
    3. Makoto Ebihara & Takeshi Ikeda & Sayuri Okunaka & Hiromasa Tokudome & Kazunari Domen & Kenji Katayama, 2021. "Charge carrier mapping for Z-scheme photocatalytic water-splitting sheet via categorization of microscopic time-resolved image sequences," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    4. Yiou Wang & Anastasia Vogel & Michael Sachs & Reiner Sebastian Sprick & Liam Wilbraham & Savio J. A. Moniz & Robert Godin & Martijn A. Zwijnenburg & James R. Durrant & Andrew I. Cooper & Junwang Tang, 2019. "Current understanding and challenges of solar-driven hydrogen generation using polymeric photocatalysts," Nature Energy, Nature, vol. 4(9), pages 746-760, September.
    5. Rufan Chen & Yang Wang & Yuan Ma & Arindam Mal & Xiao-Ya Gao & Lei Gao & Lijie Qiao & Xu-Bing Li & Li-Zhu Wu & Cheng Wang, 2021. "Rational design of isostructural 2D porphyrin-based covalent organic frameworks for tunable photocatalytic hydrogen evolution," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Xin Wang & Boyan Liu & Siqing Ma & Yingjuan Zhang & Lianzhou Wang & Gangqiang Zhu & Wei Huang & Songcan Wang, 2024. "Induced dipole moments in amorphous ZnCdS catalysts facilitate photocatalytic H2 evolution," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yunyang Qian & Yulan Han & Xiyuan Zhang & Ge Yang & Guozhen Zhang & Hai-Long Jiang, 2023. "Computation-based regulation of excitonic effects in donor-acceptor covalent organic frameworks for enhanced photocatalysis," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    2. Mohamed Hammad Elsayed & Mohamed Abdellah & Ahmed Zaki Alhakemy & Islam M. A. Mekhemer & Ahmed Esmail A. Aboubakr & Bo-Han Chen & Amr Sabbah & Kun-Han Lin & Wen-Sheng Chiu & Sheng-Jie Lin & Che-Yi Chu, 2024. "Overcoming small-bandgap charge recombination in visible and NIR-light-driven hydrogen evolution by engineering the polymer photocatalyst structure," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    3. Yimeng Li & Li Yang & Huijie He & Lei Sun & Honglei Wang & Xu Fang & Yanliang Zhao & Daoyuan Zheng & Yu Qi & Zhen Li & Weiqiao Deng, 2022. "In situ photodeposition of platinum clusters on a covalent organic framework for photocatalytic hydrogen production," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    4. Li Zhai & Sara T. Gebre & Bo Chen & Dan Xu & Junze Chen & Zijian Li & Yawei Liu & Hua Yang & Chongyi Ling & Yiyao Ge & Wei Zhai & Changsheng Chen & Lu Ma & Qinghua Zhang & Xuefei Li & Yujie Yan & Xiny, 2023. "Epitaxial growth of highly symmetrical branched noble metal-semiconductor heterostructures with efficient plasmon-induced hot-electron transfer," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    5. Guo, Liejin & Chen, Yubin & Su, Jinzhan & Liu, Maochang & Liu, Ya, 2019. "Obstacles of solar-powered photocatalytic water splitting for hydrogen production: A perspective from energy flow and mass flow," Energy, Elsevier, vol. 172(C), pages 1079-1086.
    6. Wei Zhao & Liang Luo & Muyu Cong & Xueyan Liu & Zhiyun Zhang & Mounib Bahri & Boyu Li & Jing Yang & Miaojie Yu & Lunjie Liu & Yu Xia & Nigel D. Browning & Wei-Hong Zhu & Weiwei Zhang & Andrew I. Coope, 2024. "Nanoscale covalent organic frameworks for enhanced photocatalytic hydrogen production," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    7. Qitao Chen & Baodong Mao & Yanhong Liu & Yunjie Zhou & Hui Huang & Song Wang & Longhua Li & Wei-Cheng Yan & Weidong Shi & Zhenhui Kang, 2024. "Designing 2D carbon dot nanoreactors for alcohol oxidation coupled with hydrogen evolution," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    8. Liu, Enli & Lin, Xue & Hong, Yuanzhi & Yang, Lan & Luo, Bifu & Shi, Weilong & Shi, Junyou, 2021. "Rational copolymerization strategy engineered C self-doped g-C3N4 for efficient and robust solar photocatalytic H2 evolution," Renewable Energy, Elsevier, vol. 178(C), pages 757-765.
    9. Floriana Moruzzi & Weimin Zhang & Balaji Purushothaman & Soranyel Gonzalez-Carrero & Catherine M. Aitchison & Benjamin Willner & Fabien Ceugniet & Yuanbao Lin & Jan Kosco & Hu Chen & Junfu Tian & Mary, 2023. "Solution-processable polymers of intrinsic microporosity for gas-phase carbon dioxide photoreduction," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    10. Sijie Wan & Wang Wang & Bei Cheng & Guoqiang Luo & Qiang Shen & Jiaguo Yu & Jianjun Zhang & Shaowen Cao & Lianmeng Zhang, 2024. "A superlattice interface and S-scheme heterojunction for ultrafast charge separation and transfer in photocatalytic H2 evolution," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    11. Zhongshan Chen & Jingyi Wang & Mengjie Hao & Yinghui Xie & Xiaolu Liu & Hui Yang & Geoffrey I. N. Waterhouse & Xiangke Wang & Shengqian Ma, 2023. "Tuning excited state electronic structure and charge transport in covalent organic frameworks for enhanced photocatalytic performance," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    12. Choon, S.L. & Lim, H.N. & Ibrahim, I. & Zainal, Z. & Tan, K.B. & Foo, C.Y. & Ng, C.H., 2023. "New potential materials in advancement of photovoltaic and optoelectronic applications: Metal halide perovskite nanorods," Renewable and Sustainable Energy Reviews, Elsevier, vol. 171(C).
    13. Jin Ming Wang & Qin Yao Zhu & Jeong Heon Lee & Tae Gyun Woo & Yue Xing Zhang & Woo-Dong Jang & Tae Kyu Kim, 2023. "Asymmetric gradient orbital interaction of hetero-diatomic active sites for promoting C − C coupling," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    14. Ting He & Wenlong Zhen & Yongzhi Chen & Yuanyuan Guo & Zhuoer Li & Ning Huang & Zhongping Li & Ruoyang Liu & Yuan Liu & Xu Lian & Can Xue & Tze Chien Sum & Wei Chen & Donglin Jiang, 2023. "Integrated interfacial design of covalent organic framework photocatalysts to promote hydrogen evolution from water," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    15. Wei-Wei Fang & Gui-Yu Yang & Zi-Hui Fan & Zi-Chao Chen & Xun-Liang Hu & Zhen Zhan & Irshad Hussain & Yang Lu & Tao He & Bi-En Tan, 2023. "Conjugated cross-linked phosphine as broadband light or sunlight-driven photocatalyst for large-scale atom transfer radical polymerization," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    16. Chih-Li Chang & Wei-Cheng Lin & Li-Yu Ting & Chin-Hsuan Shih & Shih-Yuan Chen & Tse-Fu Huang & Hiroyuki Tateno & Jayachandran Jayakumar & Wen-Yang Jao & Chen-Wei Tai & Che-Yi Chu & Chin-Wen Chen & Chi, 2022. "Main-chain engineering of polymer photocatalysts with hydrophilic non-conjugated segments for visible-light-driven hydrogen evolution," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    17. Lei Luo & Lei Fu & Huifen Liu & Youxun Xu & Jialiang Xing & Chun-Ran Chang & Dong-Yuan Yang & Junwang Tang, 2022. "Synergy of Pd atoms and oxygen vacancies on In2O3 for methane conversion under visible light," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    18. Fuyang Liu & Peng Zhou & Yanghui Hou & Hao Tan & Yin Liang & Jialiang Liang & Qing Zhang & Shaojun Guo & Meiping Tong & Jinren Ni, 2023. "Covalent organic frameworks for direct photosynthesis of hydrogen peroxide from water, air and sunlight," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    19. Shujiao Yang & Kaihang Yue & Xiaohan Liu & Sisi Li & Haoquan Zheng & Ya Yan & Rui Cao & Wei Zhang, 2024. "Electrocatalytic water oxidation with manganese phosphates," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    20. Wei Zhou & Xiao Wang & Wenling Zhao & Naijia Lu & Die Cong & Zhen Li & Peigeng Han & Guoqing Ren & Lei Sun & Chengcheng Liu & Wei-Qiao Deng, 2023. "Photocatalytic CO2 reduction to syngas using metallosalen covalent organic frameworks," Nature Communications, Nature, vol. 14(1), pages 1-9, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-32256-6. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.