IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v15y2024i1d10.1038_s41467-024-45085-6.html
   My bibliography  Save this article

Overcoming small-bandgap charge recombination in visible and NIR-light-driven hydrogen evolution by engineering the polymer photocatalyst structure

Author

Listed:
  • Mohamed Hammad Elsayed

    (Al-Azhar University
    Academia Sinica
    National Taiwan University
    National Tsing Hua University)

  • Mohamed Abdellah

    (United Arab Emirates University
    South Valley University
    Lund University)

  • Ahmed Zaki Alhakemy

    (Al-Azhar University)

  • Islam M. A. Mekhemer

    (National Tsing Hua University)

  • Ahmed Esmail A. Aboubakr

    (Taiwan International Graduate Program
    National Yang Ming Chiao Tung University
    Institute of Chemistry)

  • Bo-Han Chen

    (National Tsing Hua University)

  • Amr Sabbah

    (National Taiwan University
    National Taiwan University)

  • Kun-Han Lin

    (National Tsing Hua University)

  • Wen-Sheng Chiu

    (National Chung Hsing University)

  • Sheng-Jie Lin

    (National Chung Hsing University)

  • Che-Yi Chu

    (National Chung Hsing University)

  • Chih-Hsuan Lu

    (National Tsing Hua University)

  • Shang-Da Yang

    (National Tsing Hua University)

  • Mohamed Gamal Mohamed

    (National Sun Yat-Sen University)

  • Shiao-Wei Kuo

    (National Sun Yat-Sen University)

  • Chen-Hsiung Hung

    (Institute of Chemistry)

  • Li-Chyong Chen

    (National Taiwan University
    National Taiwan University
    National Taiwan University)

  • Kuei-Hsien Chen

    (Academia Sinica
    National Taiwan University)

  • Ho-Hsiu Chou

    (National Tsing Hua University)

Abstract

Designing an organic polymer photocatalyst for efficient hydrogen evolution with visible and near-infrared (NIR) light activity is still a major challenge. Unlike the common behavior of gradually increasing the charge recombination while shrinking the bandgap, we present here a series of polymer nanoparticles (Pdots) based on ITIC and BTIC units with different π-linkers between the acceptor-donor-acceptor (A-D-A) repeated moieties of the polymer. These polymers act as an efficient single polymer photocatalyst for H2 evolution under both visible and NIR light, without combining or hybridizing with other materials. Importantly, the difluorothiophene (ThF) π-linker facilitates the charge transfer between acceptors of different repeated moieties (A-D-A-(π-Linker)-A-D-A), leading to the enhancement of charge separation between D and A. As a result, the PITIC-ThF Pdots exhibit superior hydrogen evolution rates of 279 µmol/h and 20.5 µmol/h with visible (>420 nm) and NIR (>780 nm) light irradiation, respectively. Furthermore, PITIC-ThF Pdots exhibit a promising apparent quantum yield (AQY) at 700 nm (4.76%).

Suggested Citation

  • Mohamed Hammad Elsayed & Mohamed Abdellah & Ahmed Zaki Alhakemy & Islam M. A. Mekhemer & Ahmed Esmail A. Aboubakr & Bo-Han Chen & Amr Sabbah & Kun-Han Lin & Wen-Sheng Chiu & Sheng-Jie Lin & Che-Yi Chu, 2024. "Overcoming small-bandgap charge recombination in visible and NIR-light-driven hydrogen evolution by engineering the polymer photocatalyst structure," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-45085-6
    DOI: 10.1038/s41467-024-45085-6
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-024-45085-6
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-024-45085-6?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Christian M. Wolff & Peter D. Frischmann & Marcus Schulze & Bernhard J. Bohn & Robin Wein & Panajotis Livadas & Michael T. Carlson & Frank Jäckel & Jochen Feldmann & Frank Würthner & Jacek K. Stolarcz, 2018. "All-in-one visible-light-driven water splitting by combining nanoparticulate and molecular co-catalysts on CdS nanorods," Nature Energy, Nature, vol. 3(10), pages 862-869, October.
    2. Michael Sachs & Reiner Sebastian Sprick & Drew Pearce & Sam A. J. Hillman & Adriano Monti & Anne A. Y. Guilbert & Nick J. Brownbill & Stoichko Dimitrov & Xingyuan Shi & Frédéric Blanc & Martijn A. Zwi, 2018. "Understanding structure-activity relationships in linear polymer photocatalysts for hydrogen evolution," Nature Communications, Nature, vol. 9(1), pages 1-11, December.
    3. Jan Kosco & Soranyel Gonzalez-Carrero & Calvyn T. Howells & Teng Fei & Yifan Dong & Rachid Sougrat & George T. Harrison & Yuliar Firdaus & Rajendar Sheelamanthula & Balaji Purushothaman & Floriana Mor, 2022. "Generation of long-lived charges in organic semiconductor heterojunction nanoparticles for efficient photocatalytic hydrogen evolution," Nature Energy, Nature, vol. 7(4), pages 340-351, April.
    4. Yiou Wang & Anastasia Vogel & Michael Sachs & Reiner Sebastian Sprick & Liam Wilbraham & Savio J. A. Moniz & Robert Godin & Martijn A. Zwijnenburg & James R. Durrant & Andrew I. Cooper & Junwang Tang, 2019. "Current understanding and challenges of solar-driven hydrogen generation using polymeric photocatalysts," Nature Energy, Nature, vol. 4(9), pages 746-760, September.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ting He & Wenlong Zhen & Yongzhi Chen & Yuanyuan Guo & Zhuoer Li & Ning Huang & Zhongping Li & Ruoyang Liu & Yuan Liu & Xu Lian & Can Xue & Tze Chien Sum & Wei Chen & Donglin Jiang, 2023. "Integrated interfacial design of covalent organic framework photocatalysts to promote hydrogen evolution from water," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    2. Chih-Li Chang & Wei-Cheng Lin & Li-Yu Ting & Chin-Hsuan Shih & Shih-Yuan Chen & Tse-Fu Huang & Hiroyuki Tateno & Jayachandran Jayakumar & Wen-Yang Jao & Chen-Wei Tai & Che-Yi Chu & Chin-Wen Chen & Chi, 2022. "Main-chain engineering of polymer photocatalysts with hydrophilic non-conjugated segments for visible-light-driven hydrogen evolution," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    3. Jingrun Ran & Hongping Zhang & Sijia Fu & Mietek Jaroniec & Jieqiong Shan & Bingquan Xia & Yang Qu & Jiangtao Qu & Shuangming Chen & Li Song & Julie M. Cairney & Liqiang Jing & Shi-Zhang Qiao, 2022. "NiPS3 ultrathin nanosheets as versatile platform advancing highly active photocatalytic H2 production," Nature Communications, Nature, vol. 13(1), pages 1-17, December.
    4. Chong Wang & Bo Wu & Yang Li & Shen Zhou & Conghui Wu & Tianyang Dong & Ying Jiang & Zihui Hua & Yupeng Song & Wei Wen & Jianxin Tian & Yongqiang Chai & Rui Wen & Chunru Wang, 2024. "Aggregation promotes charge separation in fullerene-indacenodithiophene dyad," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    5. Li Zhai & Sara T. Gebre & Bo Chen & Dan Xu & Junze Chen & Zijian Li & Yawei Liu & Hua Yang & Chongyi Ling & Yiyao Ge & Wei Zhai & Changsheng Chen & Lu Ma & Qinghua Zhang & Xuefei Li & Yujie Yan & Xiny, 2023. "Epitaxial growth of highly symmetrical branched noble metal-semiconductor heterostructures with efficient plasmon-induced hot-electron transfer," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    6. Guo, Liejin & Chen, Yubin & Su, Jinzhan & Liu, Maochang & Liu, Ya, 2019. "Obstacles of solar-powered photocatalytic water splitting for hydrogen production: A perspective from energy flow and mass flow," Energy, Elsevier, vol. 172(C), pages 1079-1086.
    7. Wei Zhao & Liang Luo & Muyu Cong & Xueyan Liu & Zhiyun Zhang & Mounib Bahri & Boyu Li & Jing Yang & Miaojie Yu & Lunjie Liu & Yu Xia & Nigel D. Browning & Wei-Hong Zhu & Weiwei Zhang & Andrew I. Coope, 2024. "Nanoscale covalent organic frameworks for enhanced photocatalytic hydrogen production," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    8. Qitao Chen & Baodong Mao & Yanhong Liu & Yunjie Zhou & Hui Huang & Song Wang & Longhua Li & Wei-Cheng Yan & Weidong Shi & Zhenhui Kang, 2024. "Designing 2D carbon dot nanoreactors for alcohol oxidation coupled with hydrogen evolution," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    9. Liu, Enli & Lin, Xue & Hong, Yuanzhi & Yang, Lan & Luo, Bifu & Shi, Weilong & Shi, Junyou, 2021. "Rational copolymerization strategy engineered C self-doped g-C3N4 for efficient and robust solar photocatalytic H2 evolution," Renewable Energy, Elsevier, vol. 178(C), pages 757-765.
    10. Floriana Moruzzi & Weimin Zhang & Balaji Purushothaman & Soranyel Gonzalez-Carrero & Catherine M. Aitchison & Benjamin Willner & Fabien Ceugniet & Yuanbao Lin & Jan Kosco & Hu Chen & Junfu Tian & Mary, 2023. "Solution-processable polymers of intrinsic microporosity for gas-phase carbon dioxide photoreduction," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    11. Choon, S.L. & Lim, H.N. & Ibrahim, I. & Zainal, Z. & Tan, K.B. & Foo, C.Y. & Ng, C.H., 2023. "New potential materials in advancement of photovoltaic and optoelectronic applications: Metal halide perovskite nanorods," Renewable and Sustainable Energy Reviews, Elsevier, vol. 171(C).
    12. Artem Musiienko & Fengjiu Yang & Thomas William Gries & Chiara Frasca & Dennis Friedrich & Amran Al-Ashouri & Elifnaz Sağlamkaya & Felix Lang & Danny Kojda & Yi-Teng Huang & Valerio Stacchini & Robert, 2024. "Resolving electron and hole transport properties in semiconductor materials by constant light-induced magneto transport," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    13. Yan Guo & Qixin Zhou & Jun Nan & Wenxin Shi & Fuyi Cui & Yongfa Zhu, 2022. "Perylenetetracarboxylic acid nanosheets with internal electric fields and anisotropic charge migration for photocatalytic hydrogen evolution," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    14. Wei-Wei Fang & Gui-Yu Yang & Zi-Hui Fan & Zi-Chao Chen & Xun-Liang Hu & Zhen Zhan & Irshad Hussain & Yang Lu & Tao He & Bi-En Tan, 2023. "Conjugated cross-linked phosphine as broadband light or sunlight-driven photocatalyst for large-scale atom transfer radical polymerization," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    15. Lei Luo & Lei Fu & Huifen Liu & Youxun Xu & Jialiang Xing & Chun-Ran Chang & Dong-Yuan Yang & Junwang Tang, 2022. "Synergy of Pd atoms and oxygen vacancies on In2O3 for methane conversion under visible light," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    16. Yunyang Qian & Yulan Han & Xiyuan Zhang & Ge Yang & Guozhen Zhang & Hai-Long Jiang, 2023. "Computation-based regulation of excitonic effects in donor-acceptor covalent organic frameworks for enhanced photocatalysis," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    17. Shujiao Yang & Kaihang Yue & Xiaohan Liu & Sisi Li & Haoquan Zheng & Ya Yan & Rui Cao & Wei Zhang, 2024. "Electrocatalytic water oxidation with manganese phosphates," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    18. Yuanding Fang & Youxing Liu & Haojie Huang & Jianzhe Sun & Jiaxing Hong & Fan Zhang & Xiaofang Wei & Wenqiang Gao & Mingchao Shao & Yunlong Guo & Qingxin Tang & Yunqi Liu, 2024. "Design and synthesis of broadband absorption covalent organic framework for efficient artificial photocatalytic amine coupling," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    19. Xu Xin & Youzi Zhang & Ruiling Wang & Yijin Wang & Peng Guo & Xuanhua Li, 2023. "Hydrovoltaic effect-enhanced photocatalysis by polyacrylic acid/cobaltous oxide–nitrogen doped carbon system for efficient photocatalytic water splitting," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    20. Fei Chen & Chang-Wei Bai & Pi-Jun Duan & Zhi-Quan Zhang & Yi-Jiao Sun & Xin-Jia Chen & Qi Yang & Han-Qing Yu, 2024. "Merging semi-crystallization and multispecies iodine intercalation at photo-redox interfaces for dual high-value synthesis," Nature Communications, Nature, vol. 15(1), pages 1-17, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-45085-6. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.