IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-36338-x.html
   My bibliography  Save this article

Engineering β-ketoamine covalent organic frameworks for photocatalytic overall water splitting

Author

Listed:
  • Yan Yang

    (Harbin University of Science and Technology)

  • Xiaoyu Chu

    (Harbin University of Science and Technology)

  • Hong-Yu Zhang

    (Harbin University of Science and Technology)

  • Rui Zhang

    (Harbin University of Science and Technology)

  • Yu-Han Liu

    (Harbin University of Science and Technology)

  • Feng-Ming Zhang

    (Harbin University of Science and Technology)

  • Meng Lu

    (South China Normal University)

  • Zhao-Di Yang

    (Harbin University of Science and Technology)

  • Ya-Qian Lan

    (South China Normal University)

Abstract

Covalent organic frameworks (COFs) are an emerging type of crystalline and porous photocatalysts for hydrogen evolution, however, the overall water splitting activity of COFs is rarely known. In this work, we firstly realized overall water splitting activity of β-ketoamine COFs by systematically engineering N-sites, architecture, and morphology. By in situ incorporating sub-nanometer platinum (Pt) nanoparticles co-catalyst into the pores of COFs nanosheets, both Pt@TpBpy-NS and Pt@TpBpy-2-NS show visible-light-driven overall water splitting activity, with the optimal H2 and O2 evolution activities of 9.9 and 4.8 μmol in 5 h for Pt@TpBpy-NS, respectively, and a maximum solar-to-hydrogen efficiency of 0.23%. The crucial factors affecting the activity including N-sites position, nano morphology, and co-catalyst distribution were systematically explored. Further mechanism investigation reveals the tiny diversity of N sites in COFs that induces great differences in electron transfer as well as reaction potential barriers.

Suggested Citation

  • Yan Yang & Xiaoyu Chu & Hong-Yu Zhang & Rui Zhang & Yu-Han Liu & Feng-Ming Zhang & Meng Lu & Zhao-Di Yang & Ya-Qian Lan, 2023. "Engineering β-ketoamine covalent organic frameworks for photocatalytic overall water splitting," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-36338-x
    DOI: 10.1038/s41467-023-36338-x
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-36338-x
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-023-36338-x?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Yu Qi & Jiangwei Zhang & Yuan Kong & Yue Zhao & Shanshan Chen & Deng Li & Wei Liu & Yifan Chen & Tengfeng Xie & Junyan Cui & Can Li & Kazunari Domen & Fuxiang Zhang, 2022. "Unraveling of cocatalysts photodeposited selectively on facets of BiVO4 to boost solar water splitting," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    2. Rufan Chen & Yang Wang & Yuan Ma & Arindam Mal & Xiao-Ya Gao & Lei Gao & Lijie Qiao & Xu-Bing Li & Li-Zhu Wu & Cheng Wang, 2021. "Rational design of isostructural 2D porphyrin-based covalent organic frameworks for tunable photocatalytic hydrogen evolution," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    3. Tsuyoshi Takata & Junzhe Jiang & Yoshihisa Sakata & Mamiko Nakabayashi & Naoya Shibata & Vikas Nandal & Kazuhiko Seki & Takashi Hisatomi & Kazunari Domen, 2020. "Photocatalytic water splitting with a quantum efficiency of almost unity," Nature, Nature, vol. 581(7809), pages 411-414, May.
    4. Panlong Zhai & Yanxue Zhang & Yunzhen Wu & Junfeng Gao & Bo Zhang & Shuyan Cao & Yanting Zhang & Zhuwei Li & Licheng Sun & Jungang Hou, 2020. "Engineering active sites on hierarchical transition bimetal oxides/sulfides heterostructure array enabling robust overall water splitting," Nature Communications, Nature, vol. 11(1), pages 1-12, December.
    5. Vijay S. Vyas & Frederik Haase & Linus Stegbauer & Gökcen Savasci & Filip Podjaski & Christian Ochsenfeld & Bettina V. Lotsch, 2015. "A tunable azine covalent organic framework platform for visible light-induced hydrogen generation," Nature Communications, Nature, vol. 6(1), pages 1-9, December.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Peng Gao & Yezi Hu & Zewen Shen & Guixia Zhao & Ruiqing Cai & Feng Chu & Zhuoyu Ji & Xiangke Wang & Xiubing Huang, 2024. "Ultra-highly efficient enrichment of uranium from seawater via studtite nanodots growth-elution cycle," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    2. Guangri Jia & Fusai Sun & Tao Zhou & Ying Wang & Xiaoqiang Cui & Zhengxiao Guo & Fengtao Fan & Jimmy C. Yu, 2024. "Charge redistribution of a spatially differentiated ferroelectric Bi4Ti3O12 single crystal for photocatalytic overall water splitting," Nature Communications, Nature, vol. 15(1), pages 1-10, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yimeng Li & Li Yang & Huijie He & Lei Sun & Honglei Wang & Xu Fang & Yanliang Zhao & Daoyuan Zheng & Yu Qi & Zhen Li & Weiqiao Deng, 2022. "In situ photodeposition of platinum clusters on a covalent organic framework for photocatalytic hydrogen production," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    2. Wei Zhao & Liang Luo & Muyu Cong & Xueyan Liu & Zhiyun Zhang & Mounib Bahri & Boyu Li & Jing Yang & Miaojie Yu & Lunjie Liu & Yu Xia & Nigel D. Browning & Wei-Hong Zhu & Weiwei Zhang & Andrew I. Coope, 2024. "Nanoscale covalent organic frameworks for enhanced photocatalytic hydrogen production," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    3. Ting He & Wenlong Zhen & Yongzhi Chen & Yuanyuan Guo & Zhuoer Li & Ning Huang & Zhongping Li & Ruoyang Liu & Yuan Liu & Xu Lian & Can Xue & Tze Chien Sum & Wei Chen & Donglin Jiang, 2023. "Integrated interfacial design of covalent organic framework photocatalysts to promote hydrogen evolution from water," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    4. Guangri Jia & Fusai Sun & Tao Zhou & Ying Wang & Xiaoqiang Cui & Zhengxiao Guo & Fengtao Fan & Jimmy C. Yu, 2024. "Charge redistribution of a spatially differentiated ferroelectric Bi4Ti3O12 single crystal for photocatalytic overall water splitting," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    5. Vikas Nandal & Ryota Shoji & Hiroyuki Matsuzaki & Akihiro Furube & Lihua Lin & Takashi Hisatomi & Masanori Kaneko & Koichi Yamashita & Kazunari Domen & Kazuhiko Seki, 2021. "Unveiling charge dynamics of visible light absorbing oxysulfide for efficient overall water splitting," Nature Communications, Nature, vol. 12(1), pages 1-8, December.
    6. Chunzhi Li & Jiali Liu & He Li & Kaifeng Wu & Junhui Wang & Qihua Yang, 2022. "Covalent organic frameworks with high quantum efficiency in sacrificial photocatalytic hydrogen evolution," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    7. Qitao Chen & Baodong Mao & Yanhong Liu & Yunjie Zhou & Hui Huang & Song Wang & Longhua Li & Wei-Cheng Yan & Weidong Shi & Zhenhui Kang, 2024. "Designing 2D carbon dot nanoreactors for alcohol oxidation coupled with hydrogen evolution," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    8. Xiaoyi Xu & Xinyu Wu & Kai Xu & Hong Xu & Hongzheng Chen & Ning Huang, 2023. "Pore partition in two-dimensional covalent organic frameworks," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    9. Yannan Liu & Cheng-Hao Liu & Tushar Debnath & Yong Wang & Darius Pohl & Lucas V. Besteiro & Debora Motta Meira & Shengyun Huang & Fan Yang & Bernd Rellinghaus & Mohamed Chaker & Dmytro F. Perepichka &, 2023. "Silver nanoparticle enhanced metal-organic matrix with interface-engineering for efficient photocatalytic hydrogen evolution," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    10. Chen, Yu & Gao, Xiang & Liu, Xinwei & Ji, Guipeng & Fu, Li & Yang, Yingze & Yu, Qiqi & Zhang, Wenjing & Xue, Xiaomeng, 2020. "Water collection from air by ionic liquids for efficient visible-light-driven hydrogen evolution by metal-free conjugated polymer photocatalysts," Renewable Energy, Elsevier, vol. 147(P1), pages 594-601.
    11. Yang Gao & Yurui Xue & Lu Qi & Chengyu Xing & Xuchen Zheng & Feng He & Yuliang Li, 2022. "Rhodium nanocrystals on porous graphdiyne for electrocatalytic hydrogen evolution from saline water," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    12. Xianlong Li & Zhiliang Wang & Alireza Sasani & Ardeshir Baktash & Kai Wang & Haijiao Lu & Jiakang You & Peng Chen & Ping Chen & Yifan Bao & Shujun Zhang & Gang Liu & Lianzhou Wang, 2024. "Oxygen vacancy induced defect dipoles in BiVO4 for photoelectrocatalytic partial oxidation of methane," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    13. Jin Ming Wang & Qin Yao Zhu & Jeong Heon Lee & Tae Gyun Woo & Yue Xing Zhang & Woo-Dong Jang & Tae Kyu Kim, 2023. "Asymmetric gradient orbital interaction of hetero-diatomic active sites for promoting C − C coupling," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    14. Takuya Suguro & Fuminao Kishimoto & Nobuko Kariya & Tsuyoshi Fukui & Mamiko Nakabayashi & Naoya Shibata & Tsuyoshi Takata & Kazunari Domen & Kazuhiro Takanabe, 2022. "A hygroscopic nano-membrane coating achieves efficient vapor-fed photocatalytic water splitting," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    15. Yuyan Huang & Minhui Shen & Huijie Yan & Yingge He & Jianqiao Xu & Fang Zhu & Xin Yang & Yu-Xin Ye & Gangfeng Ouyang, 2024. "Achieving a solar-to-chemical efficiency of 3.6% in ambient conditions by inhibiting interlayer charges transport," Nature Communications, Nature, vol. 15(1), pages 1-15, December.
    16. Kenji Katayama & Kei Kawaguchi & Yuta Egawa & Zhenhua Pan, 2022. "Local Charge Carrier Dynamics for Photocatalytic Materials Using Pattern-Illumination Time-Resolved Phase Microscopy," Energies, MDPI, vol. 15(24), pages 1-13, December.
    17. Yang Hu & Yao Zheng & Jing Jin & Yantao Wang & Yong Peng & Jie Yin & Wei Shen & Yichao Hou & Liu Zhu & Li An & Min Lu & Pinxian Xi & Chun-Hua Yan, 2023. "Understanding the sulphur-oxygen exchange process of metal sulphides prior to oxygen evolution reaction," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    18. Lu, Buchu & Yan, Xiangyu & Liu, Qibin, 2023. "Enhanced solar hydrogen generation with the direct coupling of photo and thermal energy – An experimental and mechanism study," Applied Energy, Elsevier, vol. 331(C).
    19. Veeramani, Krishnan & Janani, Gnanaprakasam & Kim, Joonyoung & Surendran, Subramani & Lim, Jaehyoung & Jesudass, Sebastian Cyril & Mahadik, Shivraj & lee, Hyunjung & Kim, Tae-Hoon & Kim, Jung Kyu & Si, 2023. "Hydrogen and value-added products yield from hybrid water electrolysis: A critical review on recent developments," Renewable and Sustainable Energy Reviews, Elsevier, vol. 177(C).
    20. Wei Zhou & Xiao Wang & Wenling Zhao & Naijia Lu & Die Cong & Zhen Li & Peigeng Han & Guoqing Ren & Lei Sun & Chengcheng Liu & Wei-Qiao Deng, 2023. "Photocatalytic CO2 reduction to syngas using metallosalen covalent organic frameworks," Nature Communications, Nature, vol. 14(1), pages 1-9, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-36338-x. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.