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Photocatalytic CO2 reduction to syngas using metallosalen covalent organic frameworks

Author

Listed:
  • Wei Zhou

    (Shandong University)

  • Xiao Wang

    (Shandong University)

  • Wenling Zhao

    (Shandong University)

  • Naijia Lu

    (Shandong University)

  • Die Cong

    (Shandong University)

  • Zhen Li

    (Shandong University)

  • Peigeng Han

    (Shandong University)

  • Guoqing Ren

    (Shandong University)

  • Lei Sun

    (Shandong University)

  • Chengcheng Liu

    (Shandong University)

  • Wei-Qiao Deng

    (Shandong University)

Abstract

Metallosalen-covalent organic frameworks have recently gained attention in photocatalysis. However, their use in CO2 photoreduction is yet to be reported. Moreover, facile preparation of metallosalen-covalent organic frameworks with good crystallinity remains considerably challenging. Herein, we report a series of metallosalen-covalent organic frameworks produced via a one-step synthesis strategy that does not require vacuum evacuation. Metallosalen-covalent organic frameworks possessing controllable coordination environments of mononuclear and binuclear metal sites are obtained and act as photocatalysts for tunable syngas production from CO2. Metallosalen-covalent organic frameworks obtained via one-step synthesis exhibit higher crystallinity and catalytic activities than those obtained from two-step synthesis. The optimal framework material containing cobalt and triazine achieves a syngas production rate of 19.7 mmol g−1 h−1 (11:8 H2/CO), outperforming previously reported porous crystalline materials. This study provides a facile strategy for producing metallosalen-covalent organic frameworks of high quality and can accelerate their exploration in various applications.

Suggested Citation

  • Wei Zhou & Xiao Wang & Wenling Zhao & Naijia Lu & Die Cong & Zhen Li & Peigeng Han & Guoqing Ren & Lei Sun & Chengcheng Liu & Wei-Qiao Deng, 2023. "Photocatalytic CO2 reduction to syngas using metallosalen covalent organic frameworks," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-42757-7
    DOI: 10.1038/s41467-023-42757-7
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    1. Hai-Sen Xu & Yi Luo & Xing Li & Pei Zhen See & Zhongxin Chen & Tianqiong Ma & Lin Liang & Kai Leng & Ibrahim Abdelwahab & Lin Wang & Runlai Li & Xiangyan Shi & Yi Zhou & Xiu Fang Lu & Xiaoxu Zhao & Cu, 2020. "Single crystal of a one-dimensional metallo-covalent organic framework," Nature Communications, Nature, vol. 11(1), pages 1-6, December.
    2. Dongbo Yu & Qi Shao & Qingjing Song & Jiewu Cui & Yongli Zhang & Bin Wu & Liang Ge & Yan Wang & Yong Zhang & Yongqiang Qin & Robert Vajtai & Pulickel M. Ajayan & Huanting Wang & Tongwen Xu & Yucheng W, 2020. "A solvent-assisted ligand exchange approach enables metal-organic frameworks with diverse and complex architectures," Nature Communications, Nature, vol. 11(1), pages 1-10, December.
    3. Rufan Chen & Yang Wang & Yuan Ma & Arindam Mal & Xiao-Ya Gao & Lei Gao & Lijie Qiao & Xu-Bing Li & Li-Zhu Wu & Cheng Wang, 2021. "Rational design of isostructural 2D porphyrin-based covalent organic frameworks for tunable photocatalytic hydrogen evolution," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
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