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A dynamic assembly-induced emissive system for advanced information encryption with time-dependent security

Author

Listed:
  • Qian Wang

    (East China University of Science and Technology)

  • Biyan Lin

    (East China University of Science and Technology)

  • Meng Chen

    (East China University of Science and Technology)

  • Chengxi Zhao

    (East China University of Science and Technology)

  • He Tian

    (East China University of Science and Technology)

  • Da-Hui Qu

    (East China University of Science and Technology)

Abstract

The development of advanced materials for information encryption with time-dependent features is essential to meet the increasing demand on encryption security. Herein, smart materials with orthogonal and temporal encryption properties are successfully developed based on a dynamic assembly-induced multicolour supramolecular system. Multicolour fluorescence, including blue, orange and even white light emissions, is achieved by controlling the supramolecular assembly of pyrene derivatives by tailoring the solvent composition. By taking advantage of the tuneable fluorescence, dynamically controlled information encryption materials with orthogonal encryption functions, e.g., 3D codes, are successfully developed. Moreover, time-dependent information encryption materials, such as temporal multi-information displays and 4D codes, are also developed by enabling the fluorescence-controllable supramolecular system in the solid phase, showing multiple pieces of information on a time scale, and the correct information can be identified only at a specified time. This work provides an inspiring point for the design of information encryption materials with higher security requirements.

Suggested Citation

  • Qian Wang & Biyan Lin & Meng Chen & Chengxi Zhao & He Tian & Da-Hui Qu, 2022. "A dynamic assembly-induced emissive system for advanced information encryption with time-dependent security," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-31978-x
    DOI: 10.1038/s41467-022-31978-x
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    References listed on IDEAS

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    1. Yannan Liu & Hao Wang & Shanlong Li & Chuanshuang Chen & Li Xu & Ping Huang & Feng Liu & Yue Su & Meiwei Qi & Chunyang Yu & Yongfeng Zhou, 2020. "In situ supramolecular polymerization-enhanced self-assembly of polymer vesicles for highly efficient photothermal therapy," Nature Communications, Nature, vol. 11(1), pages 1-12, December.
    2. Qian Wang & Qi Zhang & Qi-Wei Zhang & Xin Li & Cai-Xin Zhao & Tian-Yi Xu & Da-Hui Qu & He Tian, 2020. "Color-tunable single-fluorophore supramolecular system with assembly-encoded emission," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    3. Zhiqiang Li & Xiao Liu & Guannan Wang & Bin Li & Hongzhong Chen & Huanrong Li & Yanli Zhao, 2021. "Photoresponsive supramolecular coordination polyelectrolyte as smart anticounterfeiting inks," Nature Communications, Nature, vol. 12(1), pages 1-8, December.
    4. Yu-Dong Yang & Xiaofan Ji & Zhi-Hao Lu & Jian Yang & Chao Gao & Haoke Zhang & Ben Zhong Tang & Jonathan L. Sessler & Han-Yuan Gong, 2020. "Time-dependent solid-state molecular motion and colour tuning of host-guest systems by organic solvents," Nature Communications, Nature, vol. 11(1), pages 1-8, December.
    5. Long Gu & Hongwei Wu & Huili Ma & Wenpeng Ye & Wenyong Jia & He Wang & Hongzhong Chen & Nan Zhang & Dongdong Wang & Cheng Qian & Zhongfu An & Wei Huang & Yanli Zhao, 2020. "Color-tunable ultralong organic room temperature phosphorescence from a multicomponent copolymer," Nature Communications, Nature, vol. 11(1), pages 1-8, December.
    6. Remi Merindol & Giovanne Delechiave & Laura Heinen & Luiz Henrique Catalani & Andreas Walther, 2019. "Modular Design of Programmable Mechanofluorescent DNA Hydrogels," Nature Communications, Nature, vol. 10(1), pages 1-10, December.
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    Cited by:

    1. Tongtong Zhang & Lingzhi Wang & Jing Wang & Zhongqiang Wang & Madhav Gupta & Xuyun Guo & Ye Zhu & Yau Chuen Yiu & Tony K. C. Hui & Yan Zhou & Can Li & Dangyuan Lei & Kwai Hei Li & Xinqiang Wang & Qi W, 2023. "Multimodal dynamic and unclonable anti-counterfeiting using robust diamond microparticles on heterogeneous substrate," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    2. Siyang Lin & Yuqi Tang & Wenxin Kang & Hari Krishna Bisoyi & Jinbao Guo & Quan Li, 2023. "Photo-triggered full-color circularly polarized luminescence based on photonic capsules for multilevel information encryption," Nature Communications, Nature, vol. 14(1), pages 1-11, December.

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