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Cation-selective two-dimensional polyimine membranes for high-performance osmotic energy conversion

Author

Listed:
  • Zhen Zhang

    (Technische Universität Dresden
    Max Planck Institute of Microstructure Physics
    University of Science and Technology of China
    University of Science and Technology of China)

  • Preeti Bhauriyal

    (Technische Universität Dresden)

  • Hafeesudeen Sahabudeen

    (Technische Universität Dresden)

  • Zhiyong Wang

    (Technische Universität Dresden
    Max Planck Institute of Microstructure Physics)

  • Xiaohui Liu

    (Technische Universität Dresden)

  • Mike Hambsch

    (Technische Universität Dresden)

  • Stefan C. B. Mannsfeld

    (Technische Universität Dresden)

  • Renhao Dong

    (Technische Universität Dresden)

  • Thomas Heine

    (Technische Universität Dresden
    Leipzig Research Branch
    Yonsei University)

  • Xinliang Feng

    (Technische Universität Dresden
    Max Planck Institute of Microstructure Physics)

Abstract

Two-dimensional (2D) membranes are emerging candidates for osmotic energy conversion. However, the trade-off between ion selectivity and conductivity remains the key bottleneck. Here we demonstrate a fully crystalline imine-based 2D polymer (2DPI) membrane capable of combining excellent ionic conductivity and high selectivity for osmotic energy conversion. The 2DPI can preferentially transport cations with Na+ selectivity coefficient of 0.98 (Na+/Cl− selectivity ratio ~84) and K+ selectivity coefficient of 0.93 (K+/Cl− ratio ~29). Moreover, the nanometer-scale thickness (~70 nm) generates a substantially high ionic flux, contributing to a record power density of up to ~53 W m−2, which is superior to most of nanoporous 2D membranes (0.8~35 W m−2). Density functional theory unveils that the oxygen and imine nitrogen can both function as the active sites depending on the ionization state of hydroxyl groups, and the enhanced interaction of Na+ versus K+ with 2DPI plays a significant role in directing the ion selectivity.

Suggested Citation

  • Zhen Zhang & Preeti Bhauriyal & Hafeesudeen Sahabudeen & Zhiyong Wang & Xiaohui Liu & Mike Hambsch & Stefan C. B. Mannsfeld & Renhao Dong & Thomas Heine & Xinliang Feng, 2022. "Cation-selective two-dimensional polyimine membranes for high-performance osmotic energy conversion," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-31523-w
    DOI: 10.1038/s41467-022-31523-w
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    Cited by:

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    2. Jiadong Tang & Yun Wang & Hongyang Yang & Qianqian Zhang & Ce Wang & Leyuan Li & Zilong Zheng & Yuhong Jin & Hao Wang & Yifan Gu & Tieyong Zuo, 2024. "All-natural 2D nanofluidics as highly-efficient osmotic energy generators," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    3. Thomas F. Magnera & Paul I. Dron & Jared P. Bozzone & Milena Jovanovic & Igor Rončević & Edward Tortorici & Wei Bu & Elisa M. Miller & Charles T. Rogers & Josef Michl, 2023. "Porphene and porphite as porphyrin analogs of graphene and graphite," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    4. Shijie Yin & Jianguo Li & Zhuozhi Lai & Qing-Wei Meng & Weipeng Xian & Zhifeng Dai & Sai Wang & Li Zhang & Yubing Xiong & Shengqian Ma & Qi Sun, 2024. "Giant gateable thermoelectric conversion by tuning the ion linkage interactions in covalent organic framework membranes," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    5. Quanquan Guo & Wei Li & Xiaodong Li & Jiaxu Zhang & Davood Sabaghi & Jianjun Zhang & Bowen Zhang & Dongqi Li & Jingwei Du & Xingyuan Chu & Sein Chung & Kilwon Cho & Nguyen Ngan Nguyen & Zhongquan Liao, 2024. "Proton-selective coating enables fast-kinetics high-mass-loading cathodes for sustainable zinc batteries," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

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