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Anomalous thermo-osmotic conversion performance of ionic covalent-organic-framework membranes in response to charge variations

Author

Listed:
  • Weipeng Xian

    (Zhejiang University)

  • Xiuhui Zuo

    (Zhejiang University)

  • Changjia Zhu

    (University of North Texas)

  • Qing Guo

    (Zhejiang University)

  • Qing-Wei Meng

    (Zhejiang University)

  • Xincheng Zhu

    (Zhejiang University)

  • Sai Wang

    (Zhejiang University)

  • Shengqian Ma

    (University of North Texas)

  • Qi Sun

    (Zhejiang University)

Abstract

Increasing the charge density of ionic membranes is believed to be beneficial for generating high output osmotic energy. Herein, we systematically investigated how the membrane charge populations affect permselectivity by decoupling their effects from the impact of the pore structure using a multivariate strategy for constructing covalent-organic-framework membranes. The thermo-osmotic energy conversion efficiency is improved by increasing the membrane charge density, affording 210 W m−2 with a temperature gradient of 40 K. However, this enhancement occurs only within a narrow window, and subsequently, the efficiency plateaued beyond a threshold density (0.04 C m−2). The complex interplay between pore-pore interactions in response to charge variations for ion transport across the upscaled nanoporous membranes helps explain the obtained results. This study has far-reaching implications for the rational design of ionic membranes to augment energy extraction rather than intuitively focusing on achieving high densities.

Suggested Citation

  • Weipeng Xian & Xiuhui Zuo & Changjia Zhu & Qing Guo & Qing-Wei Meng & Xincheng Zhu & Sai Wang & Shengqian Ma & Qi Sun, 2022. "Anomalous thermo-osmotic conversion performance of ionic covalent-organic-framework membranes in response to charge variations," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-31183-w
    DOI: 10.1038/s41467-022-31183-w
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    Cited by:

    1. Chengcheng Zhu & Li Xu & Yazi Liu & Jiang Liu & Jin Wang & Hanjun Sun & Ya-Qian Lan & Chen Wang, 2024. "Polyoxometalate-based plasmonic electron sponge membrane for nanofluidic osmotic energy conversion," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    2. Shijie Yin & Jianguo Li & Zhuozhi Lai & Qing-Wei Meng & Weipeng Xian & Zhifeng Dai & Sai Wang & Li Zhang & Yubing Xiong & Shengqian Ma & Qi Sun, 2024. "Giant gateable thermoelectric conversion by tuning the ion linkage interactions in covalent organic framework membranes," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

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