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Artificial photosynthetic system for diluted CO2 reduction in gas-solid phase

Author

Listed:
  • Ya Wang

    (Harbin University of Science and Technology)

  • Jian-Xin Wei

    (Harbin University of Science and Technology)

  • Hong-Liang Tang

    (Harbin University of Science and Technology)

  • Lu-Hua Shao

    (Harbin University of Science and Technology)

  • Long-Zhang Dong

    (South China Normal University)

  • Xiao-Yu Chu

    (Harbin University of Science and Technology)

  • Yan-Xia Jiang

    (Harbin University of Science and Technology)

  • Gui-Ling Zhang

    (Harbin University of Science and Technology)

  • Feng-Ming Zhang

    (Harbin University of Science and Technology)

  • Ya-Qian Lan

    (South China Normal University)

Abstract

Rational design of robust photocatalytic systems to direct capture and in-situ convert diluted CO2 from flue gas is a promising but challenging way to achieve carbon neutrality. Here, we report a new type of host-guest photocatalysts by integrating CO2-enriching ionic liquids and photoactive metal-organic frameworks PCN-250-Fe2M (M = Fe, Co, Ni, Zn, Mn) for artificial photosynthetic diluted CO2 reduction in gas-solid phase. As a result, [Emim]BF4(39.3 wt%)@PCN-250-Fe2Co exhibits a record high CO2-to-CO reduction rate of 313.34 μmol g−1 h−1 under pure CO2 atmosphere and 153.42 μmol g−1 h−1 under diluted CO2 (15%) with about 100% selectivity. In scaled-up experiments with 1.0 g catalyst and natural sunlight irradiation, the concentration of pure and diluted CO2 (15%) could be significantly decreased to below 85% and 10%, respectively, indicating its industrial application potential. Further experiments and theoretical calculations reveal that ionic liquids not only benefit CO2 enrichment, but also form synergistic effect with Co2+ sites in PCN-250-Fe2Co, resulting in a significant reduction in Gibbs energy barrier during the rate-determining step of CO2-to-CO conversion.

Suggested Citation

  • Ya Wang & Jian-Xin Wei & Hong-Liang Tang & Lu-Hua Shao & Long-Zhang Dong & Xiao-Yu Chu & Yan-Xia Jiang & Gui-Ling Zhang & Feng-Ming Zhang & Ya-Qian Lan, 2024. "Artificial photosynthetic system for diluted CO2 reduction in gas-solid phase," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-53066-y
    DOI: 10.1038/s41467-024-53066-y
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