IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v13y2022i1d10.1038_s41467-022-32367-0.html
   My bibliography  Save this article

Bromo- and iodo-bridged building units in metal-organic frameworks for enhanced carrier transport and CO2 photoreduction by water vapor

Author

Listed:
  • Xinfeng Chen

    (Tongji University)

  • Chengdong Peng

    (Tongji University)

  • Wenyan Dan

    (Tongji University)

  • Long Yu

    (Tongji University)

  • Yinan Wu

    (Tongji University
    Shanghai Institute of Pollution Control and Ecological Security)

  • Honghan Fei

    (Tongji University)

Abstract

Organolead halide hybrids have many promising attributes for photocatalysis, e.g. tunable bandgaps and excellent carrier transport, but their instability constraints render them vulnerable to polar molecules and limit their photocatalysis in moisture. Herein, we report the construction of metal–organic frameworks based on [Pb2X]3+ (X = Br–/I–) chains as secondary building units and 2-amino-terephthalate as organic linkers, and extend their applications in photocatalytic CO2 reduction with water vapor as the reductant. Hall effect measurement and ultrafast transient absorption spectroscopy demonstrate the bromo/iodo-bridged frameworks have substantially enhanced photocarrier transport, which results in photocatalytic performances superior to conventional metal-oxo metal-organic frameworks. Moreover, in contrast to lead perovskites, the [Pb2X]3+-based frameworks have accessible porosity and high moisture stability for gas-phase photocatalytic reaction between CO2 and H2O. This work significantly advances the excellent carrier transport of lead perovskites into the field of metal-organic frameworks.

Suggested Citation

  • Xinfeng Chen & Chengdong Peng & Wenyan Dan & Long Yu & Yinan Wu & Honghan Fei, 2022. "Bromo- and iodo-bridged building units in metal-organic frameworks for enhanced carrier transport and CO2 photoreduction by water vapor," Nature Communications, Nature, vol. 13(1), pages 1-14, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-32367-0
    DOI: 10.1038/s41467-022-32367-0
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-022-32367-0
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-022-32367-0?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Cameron Hepburn & Ella Adlen & John Beddington & Emily A. Carter & Sabine Fuss & Niall Mac Dowell & Jan C. Minx & Pete Smith & Charlotte K. Williams, 2019. "The technological and economic prospects for CO2 utilization and removal," Nature, Nature, vol. 575(7781), pages 87-97, November.
    2. Xiaodong Li & Yongfu Sun & Jiaqi Xu & Yanjie Shao & Ju Wu & Xiaoliang Xu & Yang Pan & Huanxin Ju & Junfa Zhu & Yi Xie, 2019. "Selective visible-light-driven photocatalytic CO2 reduction to CH4 mediated by atomically thin CuIn5S8 layers," Nature Energy, Nature, vol. 4(8), pages 690-699, August.
    3. Zhaoyong Lin & Chun Du & Bo Yan & Chengxin Wang & Guowei Yang, 2018. "Two-dimensional amorphous NiO as a plasmonic photocatalyst for solar H2 evolution," Nature Communications, Nature, vol. 9(1), pages 1-11, December.
    4. Yimin A. Wu & Ian McNulty & Cong Liu & Kah Chun Lau & Qi Liu & Arvydas P. Paulikas & Cheng-Jun Sun & Zhonghou Cai & Jeffrey R. Guest & Yang Ren & Vojislav Stamenkovic & Larry A. Curtiss & Yuzi Liu & T, 2019. "Facet-dependent active sites of a single Cu2O particle photocatalyst for CO2 reduction to methanol," Nature Energy, Nature, vol. 4(11), pages 957-968, November.
    5. Yuehan Cao & Lan Guo & Meng Dan & Dmitry E. Doronkin & Chunqiu Han & Zhiqiang Rao & Yang Liu & Jie Meng & Zeai Huang & Kaibo Zheng & Peng Chen & Fan Dong & Ying Zhou, 2021. "Modulating electron density of vacancy site by single Au atom for effective CO2 photoreduction," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
    6. Makhsud I. Saidaminov & Ahmed L. Abdelhady & Banavoth Murali & Erkki Alarousu & Victor M. Burlakov & Wei Peng & Ibrahim Dursun & Lingfei Wang & Yao He & Giacomo Maculan & Alain Goriely & Tom Wu & Omar, 2015. "High-quality bulk hybrid perovskite single crystals within minutes by inverse temperature crystallization," Nature Communications, Nature, vol. 6(1), pages 1-6, November.
    7. Zhuo Jiang & Xiaohui Xu & Yanhang Ma & Hae Sung Cho & Deng Ding & Chao Wang & Jie Wu & Peter Oleynikov & Mei Jia & Jun Cheng & Yi Zhou & Osamu Terasaki & Tianyou Peng & Ling Zan & Hexiang Deng, 2020. "Filling metal–organic framework mesopores with TiO2 for CO2 photoreduction," Nature, Nature, vol. 586(7830), pages 549-554, October.
    8. Shaolei Wang & Min Xu & Tianyou Peng & Chengxin Zhang & Tao Li & Irshad Hussain & Jingyu Wang & Bien Tan, 2019. "Porous hypercrosslinked polymer-TiO2-graphene composite photocatalysts for visible-light-driven CO2 conversion," Nature Communications, Nature, vol. 10(1), pages 1-10, December.
    9. Feiyan Xu & Kai Meng & Bei Cheng & Shengyao Wang & Jingsan Xu & Jiaguo Yu, 2020. "Unique S-scheme heterojunctions in self-assembled TiO2/CsPbBr3 hybrids for CO2 photoreduction," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Jie Zhou & Jie Li & Liang Kan & Lei Zhang & Qing Huang & Yong Yan & Yifa Chen & Jiang Liu & Shun-Li Li & Ya-Qian Lan, 2022. "Linking oxidative and reductive clusters to prepare crystalline porous catalysts for photocatalytic CO2 reduction with H2O," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    2. Yajuan Ma & Xiaoxuan Yi & Shaolei Wang & Tao Li & Bien Tan & Chuncheng Chen & Tetsuro Majima & Eric R. Waclawik & Huaiyong Zhu & Jingyu Wang, 2022. "Selective photocatalytic CO2 reduction in aerobic environment by microporous Pd-porphyrin-based polymers coated hollow TiO2," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    3. Yuan-Sheng Xia & Meizhong Tang & Lei Zhang & Jiang Liu & Cheng Jiang & Guang-Kuo Gao & Long-Zhang Dong & Lan-Gui Xie & Ya-Qian Lan, 2022. "Tandem utilization of CO2 photoreduction products for the carbonylation of aryl iodides," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    4. Yan Shen & Chunjin Ren & Lirong Zheng & Xiaoyong Xu & Ran Long & Wenqing Zhang & Yong Yang & Yongcai Zhang & Yingfang Yao & Haoqiang Chi & Jinlan Wang & Qing Shen & Yujie Xiong & Zhigang Zou & Yong Zh, 2023. "Room-temperature photosynthesis of propane from CO2 with Cu single atoms on vacancy-rich TiO2," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    5. Shengyao Wang & Bo Jiang & Joel Henzie & Feiyan Xu & Chengyuan Liu & Xianguang Meng & Sirong Zou & Hui Song & Yang Pan & Hexing Li & Jiaguo Yu & Hao Chen & Jinhua Ye, 2023. "Designing reliable and accurate isotope-tracer experiments for CO2 photoreduction," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    6. Yao Chai & Yuehua Kong & Min Lin & Wei Lin & Jinni Shen & Jinlin Long & Rusheng Yuan & Wenxin Dai & Xuxu Wang & Zizhong Zhang, 2023. "Metal to non-metal sites of metallic sulfides switching products from CO to CH4 for photocatalytic CO2 reduction," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    7. Mohammad Qorbani & Amr Sabbah & Ying-Ren Lai & Septia Kholimatussadiah & Shaham Quadir & Chih-Yang Huang & Indrajit Shown & Yi-Fan Huang & Michitoshi Hayashi & Kuei-Hsien Chen & Li-Chyong Chen, 2022. "Atomistic insights into highly active reconstructed edges of monolayer 2H-WSe2 photocatalyst," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    8. Xiaodong Li & Li Li & Guangbo Chen & Xingyuan Chu & Xiaohui Liu & Chandrasekhar Naisa & Darius Pohl & Markus Löffler & Xinliang Feng, 2023. "Accessing parity-forbidden d-d transitions for photocatalytic CO2 reduction driven by infrared light," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    9. Min Zhou & Zhiqing Wang & Aohan Mei & Zifan Yang & Wen Chen & Siyong Ou & Shengyao Wang & Keqiang Chen & Peter Reiss & Kun Qi & Jingyuan Ma & Yueli Liu, 2023. "Photocatalytic CO2 reduction using La-Ni bimetallic sites within a covalent organic framework," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    10. Xin Wang & Boyan Liu & Siqing Ma & Yingjuan Zhang & Lianzhou Wang & Gangqiang Zhu & Wei Huang & Songcan Wang, 2024. "Induced dipole moments in amorphous ZnCdS catalysts facilitate photocatalytic H2 evolution," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    11. Hui Li & Caikun Cheng & Zhijie Yang & Jingjing Wei, 2022. "Encapsulated CdSe/CdS nanorods in double-shelled porous nanocomposites for efficient photocatalytic CO2 reduction," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    12. Shikang Yin & Yiying Zhou & Zhonghuan Liu & Huijie Wang & Xiaoxue Zhao & Zhi Zhu & Yan Yan & Pengwei Huo, 2024. "Elucidating protonation pathways in CO2 photoreduction using the kinetic isotope effect," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    13. Fang Li & Xiaoyang Yue & Yulong Liao & Liang Qiao & Kangle Lv & Quanjun Xiang, 2023. "Understanding the unique S-scheme charge migration in triazine/heptazine crystalline carbon nitride homojunction," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    14. Sanchita Karmakar & Soumitra Barman & Faruk Ahamed Rahimi & Darsi Rambabu & Sukhendu Nath & Tapas Kumar Maji, 2023. "Confining charge-transfer complex in a metal-organic framework for photocatalytic CO2 reduction in water," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    15. Michael Carus & Lara Dammer & Achim Raschka & Pia Skoczinski, 2020. "Renewable carbon: Key to a sustainable and future‐oriented chemical and plastic industry: Definition, strategy, measures and potential," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 10(3), pages 488-505, June.
    16. Yihua Zhang & Guyang Peng & Shuankui Li & Haijun Wu & Kaidong Chen & Jiandong Wang & Zhihao Zhao & Tu Lyu & Yuan Yu & Chaohua Zhang & Yang Zhang & Chuansheng Ma & Shengwu Guo & Xiangdong Ding & Jun Su, 2024. "Phase interface engineering enables state-of-the-art half-Heusler thermoelectrics," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    17. Georgios Varvoutis & Athanasios Lampropoulos & Evridiki Mandela & Michalis Konsolakis & George E. Marnellos, 2022. "Recent Advances on CO 2 Mitigation Technologies: On the Role of Hydrogenation Route via Green H 2," Energies, MDPI, vol. 15(13), pages 1-38, June.
    18. Qitao Chen & Baodong Mao & Yanhong Liu & Yunjie Zhou & Hui Huang & Song Wang & Longhua Li & Wei-Cheng Yan & Weidong Shi & Zhenhui Kang, 2024. "Designing 2D carbon dot nanoreactors for alcohol oxidation coupled with hydrogen evolution," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    19. Subrato Acharjya & Jiacheng Chen & Minghui Zhu & Chong Peng, 2021. "Elucidating the reactivity and nature of active sites for tin phthalocyanine during CO2 reduction," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 11(6), pages 1191-1197, December.
    20. Chang, Yuan & Gao, Siqi & Ma, Qian & Wei, Ying & Li, Guoping, 2024. "Techno-economic analysis of carbon capture and utilization technologies and implications for China," Renewable and Sustainable Energy Reviews, Elsevier, vol. 199(C).

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-32367-0. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.