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A facile dual-template-directed successive assembly approach to hollow multi-shell mesoporous metal–organic framework particles

Author

Listed:
  • Haidong Xu

    (College of Chemistry, Jilin University)

  • Ji Han

    (College of Chemistry, Jilin University)

  • Bin Zhao

    (College of Chemistry, Jilin University)

  • Ruigang Sun

    (College of Chemistry, Jilin University)

  • Guiyuan Zhong

    (College of Chemistry, Jilin University)

  • Guangrui Chen

    (College of Chemistry, Jilin University)

  • Yusuke Yamauchi

    (The University of Queensland
    Nagoya University, Furo-cho, Chikusa-ku)

  • Buyuan Guan

    (College of Chemistry, Jilin University
    Jilin University)

Abstract

Hollow multi-shell mesoporous metal–organic framework (MOF) particles with accessible compartmentalization environments, plentiful heterogeneous interfaces, and abundant framework diversity are expected to hold great potential for catalysis, energy conversion, and biotechnology. However, their synthetic methodology has not yet been established. In this work, a facile dual-template-directed successive assembly approach has been developed for the preparation of monodisperse hollow multi-shell mesoporous MOF (UiO-66-NH2) particles through one-step selective etching of successively grown multi-layer MOFs with alternating two types of mesostructured layers. This strategy enables the preparation of hollow multi-shell mesoporous UiO-66-NH2 nanostructures with controllable shell numbers, accessible mesochannels, large pore volume, tunable shell thickness and chamber sizes. The methodology relies on creating multiple alternating layers of two different mesostructured MOFs via dual-template-directed successive assembly and their difference in framework stability upon chemical etching. Benefiting from the highly accessible Lewis acidic sites and the accumulation of reactants within the multi-compartment architecture, the resultant hollow multi-shell mesoporous UiO-66-NH2 particles exhibit enhanced catalytic activity for CO2 cycloaddition reaction. The dual-template-directed successive assembly strategy paves the way toward the rational construction of elaborate hierarchical MOF nanoarchitectures with specific physical and chemical features for different applications.

Suggested Citation

  • Haidong Xu & Ji Han & Bin Zhao & Ruigang Sun & Guiyuan Zhong & Guangrui Chen & Yusuke Yamauchi & Buyuan Guan, 2023. "A facile dual-template-directed successive assembly approach to hollow multi-shell mesoporous metal–organic framework particles," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-43259-2
    DOI: 10.1038/s41467-023-43259-2
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    References listed on IDEAS

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    1. Ke Li & Yucheng Zhao & Jian Yang & Jinlou Gu, 2022. "Nanoemulsion-directed growth of MOFs with versatile architectures for the heterogeneous regeneration of coenzymes," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    2. Tiantian Man & Caixia Xu & Xiao-Yuan Liu & Dan Li & Chia-Kuang Tsung & Hao Pei & Ying Wan & Li Li, 2022. "Hierarchically encapsulating enzymes with multi-shelled metal-organic frameworks for tandem biocatalytic reactions," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    3. Xu Han & Tianyu Zhang & Xinhe Wang & Zedong Zhang & Yaping Li & Yongji Qin & Bingqing Wang & Aijuan Han & Junfeng Liu, 2022. "Hollow mesoporous atomically dispersed metal-nitrogen-carbon catalysts with enhanced diffusion for catalysis involving larger molecules," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
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