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Driving chemical reactions with polariton condensates

Author

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  • Sindhana Pannir-Sivajothi

    (University of California San Diego)

  • Jorge A. Campos-Gonzalez-Angulo

    (University of California San Diego)

  • Luis A. Martínez-Martínez

    (University of California San Diego)

  • Shubham Sinha

    (University of California San Diego)

  • Joel Yuen-Zhou

    (University of California San Diego)

Abstract

When molecular transitions strongly couple to photon modes, they form hybrid light-matter modes called polaritons. Collective vibrational strong coupling is a promising avenue for control of chemistry, but this can be deterred by the large number of quasi-degenerate dark modes. The macroscopic occupation of a single polariton mode by excitations, as observed in Bose-Einstein condensation, offers promise for overcoming this issue. Here we theoretically investigate the effect of vibrational polariton condensation on the kinetics of electron transfer processes. Compared with excitation with infrared laser sources, the vibrational polariton condensate changes the reaction yield significantly at room temperature due to additional channels with reduced activation barriers resulting from the large accumulation of energy in the lower polariton, and the many modes available for energy redistribution during the reaction. Our results offer tantalizing opportunities to use condensates for driving chemical reactions, kinetically bypassing usual constraints of fast intramolecular vibrational redistribution in condensed phase.

Suggested Citation

  • Sindhana Pannir-Sivajothi & Jorge A. Campos-Gonzalez-Angulo & Luis A. Martínez-Martínez & Shubham Sinha & Joel Yuen-Zhou, 2022. "Driving chemical reactions with polariton condensates," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-29290-9
    DOI: 10.1038/s41467-022-29290-9
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    References listed on IDEAS

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    1. D. G. Lidzey & D. D. C. Bradley & M. S. Skolnick & T. Virgili & S. Walker & D. M. Whittaker, 1998. "Strong exciton–photon coupling in an organic semiconductor microcavity," Nature, Nature, vol. 395(6697), pages 53-55, September.
    2. Xinyang Li & Arkajit Mandal & Pengfei Huo, 2021. "Cavity frequency-dependent theory for vibrational polariton chemistry," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    3. A. Shalabney & J. George & J. Hutchison & G. Pupillo & C. Genet & T. W. Ebbesen, 2015. "Coherent coupling of molecular resonators with a microcavity mode," Nature Communications, Nature, vol. 6(1), pages 1-6, May.
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    Cited by:

    1. Qi Yu & Joel M. Bowman, 2023. "Manipulating hydrogen bond dissociation rates and mechanisms in water dimer through vibrational strong coupling," Nature Communications, Nature, vol. 14(1), pages 1-12, December.

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