IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v13y2022i1d10.1038_s41467-022-31703-8.html
   My bibliography  Save this article

Energy-efficient pathway for selectively exciting solute molecules to high vibrational states via solvent vibration-polariton pumping

Author

Listed:
  • Tao E. Li

    (University of Pennsylvania
    Yale University)

  • Abraham Nitzan

    (University of Pennsylvania
    Tel Aviv University)

  • Joseph E. Subotnik

    (University of Pennsylvania)

Abstract

Selectively exciting target molecules to high vibrational states is inefficient in the liquid phase, which restricts the use of IR pumping to catalyze ground-state chemical reactions. Here, we demonstrate that this inefficiency can sometimes be solved by confining the liquid to an optical cavity under vibrational strong coupling conditions. For a liquid solution of 13CO2 solute in a 12CO2 solvent, cavity molecular dynamics simulations show that exciting a polariton (hybrid light-matter state) of the solvent with an intense laser pulse, under suitable resonant conditions, may lead to a very strong (>3 quanta) and ultrafast (

Suggested Citation

  • Tao E. Li & Abraham Nitzan & Joseph E. Subotnik, 2022. "Energy-efficient pathway for selectively exciting solute molecules to high vibrational states via solvent vibration-polariton pumping," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-31703-8
    DOI: 10.1038/s41467-022-31703-8
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-022-31703-8
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-022-31703-8?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Andrea B. Grafton & Adam D. Dunkelberger & Blake S. Simpkins & Johan F. Triana & Federico J. Hernández & Felipe Herrera & Jeffrey C. Owrutsky, 2021. "Excited-state vibration-polariton transitions and dynamics in nitroprusside," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    2. Xinyang Li & Arkajit Mandal & Pengfei Huo, 2021. "Cavity frequency-dependent theory for vibrational polariton chemistry," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    3. A. Shalabney & J. George & J. Hutchison & G. Pupillo & C. Genet & T. W. Ebbesen, 2015. "Coherent coupling of molecular resonators with a microcavity mode," Nature Communications, Nature, vol. 6(1), pages 1-6, May.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Connor K. Terry Weatherly & Justin Provazza & Emily A. Weiss & Roel Tempelaar, 2023. "Theory predicts UV/vis-to-IR photonic down conversion mediated by excited state vibrational polaritons," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    2. Kaihong Sun & Raphael F. Ribeiro, 2024. "Theoretical formulation of chemical equilibrium under vibrational strong coupling," Nature Communications, Nature, vol. 15(1), pages 1-12, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Qi Yu & Joel M. Bowman, 2023. "Manipulating hydrogen bond dissociation rates and mechanisms in water dimer through vibrational strong coupling," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    2. Connor K. Terry Weatherly & Justin Provazza & Emily A. Weiss & Roel Tempelaar, 2023. "Theory predicts UV/vis-to-IR photonic down conversion mediated by excited state vibrational polaritons," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    3. Kaihong Sun & Raphael F. Ribeiro, 2024. "Theoretical formulation of chemical equilibrium under vibrational strong coupling," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    4. Sindhana Pannir-Sivajothi & Jorge A. Campos-Gonzalez-Angulo & Luis A. Martínez-Martínez & Shubham Sinha & Joel Yuen-Zhou, 2022. "Driving chemical reactions with polariton condensates," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    5. Lachlan P. Lindoy & Arkajit Mandal & David R. Reichman, 2023. "Quantum dynamical effects of vibrational strong coupling in chemical reactivity," Nature Communications, Nature, vol. 14(1), pages 1-14, December.
    6. Fan Wu & Daniel Finkelstein-Shapiro & Mao Wang & Ilmari Rosenkampff & Arkady Yartsev & Torbjörn Pascher & Tu C. Nguyen- Phan & Richard Cogdell & Karl Börjesson & Tönu Pullerits, 2022. "Optical cavity-mediated exciton dynamics in photosynthetic light harvesting 2 complexes," Nature Communications, Nature, vol. 13(1), pages 1-7, December.
    7. Rosario R. Riso & Tor S. Haugland & Enrico Ronca & Henrik Koch, 2022. "Molecular orbital theory in cavity QED environments," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    8. Irene Dolado & Carlos Maciel-Escudero & Elizaveta Nikulina & Evgenii Modin & Francesco Calavalle & Shu Chen & Andrei Bylinkin & Francisco Javier Alfaro-Mozaz & Jiahan Li & James H. Edgar & Fèlix Casan, 2022. "Remote near-field spectroscopy of vibrational strong coupling between organic molecules and phononic nanoresonators," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    9. Christian Schäfer & Johannes Flick & Enrico Ronca & Prineha Narang & Angel Rubio, 2022. "Shining light on the microscopic resonant mechanism responsible for cavity-mediated chemical reactivity," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    10. Minjung Son & Zachary T. Armstrong & Ryan T. Allen & Abitha Dhavamani & Michael S. Arnold & Martin T. Zanni, 2022. "Energy cascades in donor-acceptor exciton-polaritons observed by ultrafast two-dimensional white-light spectroscopy," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    11. Fabijan Pavošević & Robert L. Smith & Angel Rubio, 2023. "Computational study on the catalytic control of endo/exo Diels-Alder reactions by cavity quantum vacuum fluctuations," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    12. Tingting Wu & Chongwu Wang & Guangwei Hu & Zhixun Wang & Jiaxin Zhao & Zhe Wang & Ksenia Chaykun & Lin Liu & Mengxiao Chen & Dong Li & Song Zhu & Qihua Xiong & Zexiang Shen & Huajian Gao & Francisco J, 2024. "Ultrastrong exciton-plasmon couplings in WS2 multilayers synthesized with a random multi-singular metasurface at room temperature," Nature Communications, Nature, vol. 15(1), pages 1-9, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-31703-8. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.