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Strain and crystallographic identification of the helically concaved gap surfaces of chiral nanoparticles

Author

Listed:
  • Sungwook Choi

    (Sogang University)

  • Sang Won Im

    (Seoul National University)

  • Ji-Hyeok Huh

    (Korea University)

  • Sungwon Kim

    (Sogang University)

  • Jaeseung Kim

    (Sogang University)

  • Yae-Chan Lim

    (Seoul National University)

  • Ryeong Myeong Kim

    (Seoul National University)

  • Jeong Hyun Han

    (Seoul National University)

  • Hyeohn Kim

    (Seoul National University)

  • Michael Sprung

    (Deutsches Elektronen-Synchrotron (DESY))

  • Su Yong Lee

    (Pohang Accelerator Laboratory, POSTECH)

  • Wonsuk Cha

    (Argonne National Laboratory)

  • Ross Harder

    (Argonne National Laboratory)

  • Seungwoo Lee

    (Korea University
    Korea University)

  • Ki Tae Nam

    (Seoul National University)

  • Hyunjung Kim

    (Sogang University)

Abstract

Identifying the three-dimensional (3D) crystal plane and strain-field distributions of nanocrystals is essential for optical, catalytic, and electronic applications. However, it remains a challenge to image concave surfaces of nanoparticles. Here, we develop a methodology for visualizing the 3D information of chiral gold nanoparticles ≈ 200 nm in size with concave gap structures by Bragg coherent X-ray diffraction imaging. The distribution of the high-Miller-index planes constituting the concave chiral gap is precisely determined. The highly strained region adjacent to the chiral gaps is resolved, which was correlated to the 432-symmetric morphology of the nanoparticles and its corresponding plasmonic properties are numerically predicted from the atomically defined structures. This approach can serve as a comprehensive characterization platform for visualizing the 3D crystallographic and strain distributions of nanoparticles with a few hundred nanometers, especially for applications where structural complexity and local heterogeneity are major determinants, as exemplified in plasmonics.

Suggested Citation

  • Sungwook Choi & Sang Won Im & Ji-Hyeok Huh & Sungwon Kim & Jaeseung Kim & Yae-Chan Lim & Ryeong Myeong Kim & Jeong Hyun Han & Hyeohn Kim & Michael Sprung & Su Yong Lee & Wonsuk Cha & Ross Harder & Seu, 2023. "Strain and crystallographic identification of the helically concaved gap surfaces of chiral nanoparticles," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-39255-1
    DOI: 10.1038/s41467-023-39255-1
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    References listed on IDEAS

    as
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    2. Dongjin Kim & Myungwoo Chung & Jerome Carnis & Sungwon Kim & Kyuseok Yun & Jinback Kang & Wonsuk Cha & Mathew J. Cherukara & Evan Maxey & Ross Harder & Kiran Sasikumar & Subramanian Sankaranarayanan &, 2018. "Active site localization of methane oxidation on Pt nanocrystals," Nature Communications, Nature, vol. 9(1), pages 1-7, December.
    3. Hye-Eun Lee & Hyo-Yong Ahn & Jungho Mun & Yoon Young Lee & Minkyung Kim & Nam Heon Cho & Kiseok Chang & Wook Sung Kim & Junsuk Rho & Ki Tae Nam, 2018. "Amino-acid- and peptide-directed synthesis of chiral plasmonic gold nanoparticles," Nature, Nature, vol. 556(7701), pages 360-365, April.
    4. Rui Xu & Huaidong Jiang & Changyong Song & Jose A. Rodriguez & Zhifeng Huang & Chien-Chun Chen & Daewoong Nam & Jaehyun Park & Marcus Gallagher-Jones & Sangsoo Kim & Sunam Kim & Akihiro Suzuki & Yuki , 2014. "Single-shot three-dimensional structure determination of nanocrystals with femtosecond X-ray free-electron laser pulses," Nature Communications, Nature, vol. 5(1), pages 1-9, September.
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