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Chiral 3D structures through multi-dimensional transfer printing of multilayer quantum dot patterns

Author

Listed:
  • Geon Yeong Kim

    (Korea Advanced Institute of Science and Technology (KAIST))

  • Shinho Kim

    (Yuseong-gu)

  • Ki Hyun Park

    (Korea Advanced Institute of Science and Technology (KAIST))

  • Hanhwi Jang

    (Korea Advanced Institute of Science and Technology (KAIST))

  • Moohyun Kim

    (Korea Advanced Institute of Science and Technology (KAIST))

  • Tae Won Nam

    (Korea Advanced Institute of Science and Technology (KAIST))

  • Kyeong Min Song

    (Korea Advanced Institute of Science and Technology (KAIST))

  • Hongjoo Shin

    (Korea Advanced Institute of Science and Technology (KAIST))

  • Yemin Park

    (Korea Advanced Institute of Science and Technology (KAIST))

  • Yeongin Cho

    (Korea Advanced Institute of Science and Technology (KAIST))

  • Jihyeon Yeom

    (Korea Advanced Institute of Science and Technology (KAIST))

  • Min-Jae Choi

    (Jung-gu)

  • Min Seok Jang

    (Yuseong-gu)

  • Yeon Sik Jung

    (Korea Advanced Institute of Science and Technology (KAIST))

Abstract

Three-dimensional optical nanostructures have garnered significant interest in photonics due to their extraordinary capabilities to manipulate the amplitude, phase, and polarization states of light. However, achieving complex three-dimensional optical nanostructures with bottom-up fabrication has remained challenging, despite its nanoscale precision and cost-effectiveness, mainly due to inherent limitations in structural controllability. Here, we report the optical characteristics of intricate two- and three-dimensional nanoarchitectures made of colloidal quantum dots fabricated with multi-dimensional transfer printing. Our customizable fabrication platform, directed by tailored interface polarity, enables flexible geometric control over a variety of one-, two-, and three-dimensional quantum dot architectures, achieving tunable and advanced optical features. For example, we demonstrate a two-dimensional quantum dot nanomesh with tuned subwavelength square perforations designed by finite-difference time-domain calculations, achieving an 8-fold enhanced photoluminescence due to the maximized optical resonance. Furthermore, a three-dimensional quantum dot chiral structure is also created via asymmetric stacking of one-dimensional quantum dot layers, realizing a pronounced circular dichroism intensity exceeding 20°.

Suggested Citation

  • Geon Yeong Kim & Shinho Kim & Ki Hyun Park & Hanhwi Jang & Moohyun Kim & Tae Won Nam & Kyeong Min Song & Hongjoo Shin & Yemin Park & Yeongin Cho & Jihyeon Yeom & Min-Jae Choi & Min Seok Jang & Yeon Si, 2024. "Chiral 3D structures through multi-dimensional transfer printing of multilayer quantum dot patterns," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-51179-y
    DOI: 10.1038/s41467-024-51179-y
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    References listed on IDEAS

    as
    1. Tae Won Nam & Moohyun Kim & Yanming Wang & Geon Yeong Kim & Wonseok Choi & Hunhee Lim & Kyeong Min Song & Min-Jae Choi & Duk Young Jeon & Jeffrey C. Grossman & Yeon Sik Jung, 2020. "Thermodynamic-driven polychromatic quantum dot patterning for light-emitting diodes beyond eye-limiting resolution," Nature Communications, Nature, vol. 11(1), pages 1-11, December.
    2. Hye-Eun Lee & Hyo-Yong Ahn & Jungho Mun & Yoon Young Lee & Minkyung Kim & Nam Heon Cho & Kiseok Chang & Wook Sung Kim & Junsuk Rho & Ki Tae Nam, 2018. "Amino-acid- and peptide-directed synthesis of chiral plasmonic gold nanoparticles," Nature, Nature, vol. 556(7701), pages 360-365, April.
    3. Yejing Liu & Hao Wang & Jinfa Ho & Ryan C. Ng & Ray J. H. Ng & Valerian H. Hall-Chen & Eleen H. H. Koay & Zhaogang Dong & Hailong Liu & Cheng-Wei Qiu & Julia R. Greer & Joel K. W. Yang, 2019. "Structural color three-dimensional printing by shrinking photonic crystals," Nature Communications, Nature, vol. 10(1), pages 1-8, December.
    4. Prashant Kumar & Thi Vo & Minjeong Cha & Anastasia Visheratina & Ji-Young Kim & Wenqian Xu & Jonathan Schwartz & Alexander Simon & Daniel Katz & Valentin Paul Nicu & Emanuele Marino & Won Jin Choi & M, 2023. "Photonically active bowtie nanoassemblies with chirality continuum," Nature, Nature, vol. 615(7952), pages 418-424, March.
    5. Yang Zhao & Amir N. Askarpour & Liuyang Sun & Jinwei Shi & Xiaoqin Li & Andrea Alù, 2017. "Chirality detection of enantiomers using twisted optical metamaterials," Nature Communications, Nature, vol. 8(1), pages 1-8, April.
    6. Jae Won Jeong & Se Ryeun Yang & Yoon Hyung Hur & Seong Wan Kim & Kwang Min Baek & Soonmin Yim & Hyun-Ik Jang & Jae Hong Park & Seung Yong Lee & Chong-Ook Park & Yeon Sik Jung, 2014. "High-resolution nanotransfer printing applicable to diverse surfaces via interface-targeted adhesion switching," Nature Communications, Nature, vol. 5(1), pages 1-12, December.
    7. Ryeong Myeong Kim & Ji-Hyeok Huh & SeokJae Yoo & Tae Gyun Kim & Changwon Kim & Hyeohn Kim & Jeong Hyun Han & Nam Heon Cho & Yae-Chan Lim & Sang Won Im & EunJi Im & Jae Ryeol Jeong & Min Hyung Lee & Ta, 2022. "Enantioselective sensing by collective circular dichroism," Nature, Nature, vol. 612(7940), pages 470-476, December.
    8. Masahiro Yoshida & Shumpei Katsuno & Takuya Inoue & John Gelleta & Koki Izumi & Menaka De Zoysa & Kenji Ishizaki & Susumu Noda, 2023. "High-brightness scalable continuous-wave single-mode photonic-crystal laser," Nature, Nature, vol. 618(7966), pages 727-732, June.
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