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Direct investigation of the reorientational dynamics of A-site cations in 2D organic-inorganic hybrid perovskite by solid-state NMR

Author

Listed:
  • Cheng-Chieh Lin

    (National Taiwan University
    Academia Sinica)

  • Shing-Jong Huang

    (National Taiwan University)

  • Pei-Hao Wu

    (Academia Sinica)

  • Tzu-Pei Chen

    (National Taiwan University)

  • Chih-Ying Huang

    (National Taiwan University
    Academia Sinica)

  • Ying-Chiao Wang

    (National Taiwan University)

  • Po-Tuan Chen

    (National Taipei University of Technology)

  • Denitsa Radeva

    (Sofia University)

  • Ognyan Petrov

    (Sofia University)

  • Vladimir M. Gelev

    (Sofia University)

  • Raman Sankar

    (Academia Sinica)

  • Chia-Chun Chen

    (National Taiwan Normal University)

  • Chun-Wei Chen

    (National Taiwan University
    National Taiwan University
    National Taiwan University)

  • Tsyr-Yan Yu

    (National Taiwan University
    Academia Sinica
    Academia Sinica)

Abstract

Limited methods are available for investigating the reorientational dynamics of A-site cations in two-dimensional organic–inorganic hybrid perovskites (2D OIHPs), which play a pivotal role in determining their physical properties. Here, we describe an approach to study the dynamics of A-site cations using solid-state NMR and stable isotope labelling. 2H NMR of 2D OIHPs incorporating methyl-d3-ammonium cations (d3-MA) reveals the existence of multiple modes of reorientational motions of MA. Rotational-echo double resonance (REDOR) NMR of 2D OIHPs incorporating 15N- and ¹³C-labeled methylammonium cations (13C,15N-MA) reflects the averaged dipolar coupling between the C and N nuclei undergoing different modes of motions. Our study reveals the interplay between the A-site cation dynamics and the structural rigidity of the organic spacers, so providing a molecular-level insight into the design of 2D OIHPs.

Suggested Citation

  • Cheng-Chieh Lin & Shing-Jong Huang & Pei-Hao Wu & Tzu-Pei Chen & Chih-Ying Huang & Ying-Chiao Wang & Po-Tuan Chen & Denitsa Radeva & Ognyan Petrov & Vladimir M. Gelev & Raman Sankar & Chia-Chun Chen &, 2022. "Direct investigation of the reorientational dynamics of A-site cations in 2D organic-inorganic hybrid perovskite by solid-state NMR," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-29207-6
    DOI: 10.1038/s41467-022-29207-6
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    1. Hsinhan Tsai & Wanyi Nie & Jean-Christophe Blancon & Constantinos C. Stoumpos & Reza Asadpour & Boris Harutyunyan & Amanda J. Neukirch & Rafael Verduzco & Jared J. Crochet & Sergei Tretiak & Laurent P, 2016. "High-efficiency two-dimensional Ruddlesden–Popper perovskite solar cells," Nature, Nature, vol. 536(7616), pages 312-316, August.
    2. Carlo Motta & Fedwa El-Mellouhi & Sabre Kais & Nouar Tabet & Fahhad Alharbi & Stefano Sanvito, 2015. "Revealing the role of organic cations in hybrid halide perovskite CH3NH3PbI3," Nature Communications, Nature, vol. 6(1), pages 1-7, November.
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