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Reversing sintering effect of Ni particles on γ-Mo2N via strong metal support interaction

Author

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  • Lili Lin

    (Zhejiang University of Technology
    College of Chemistry and Molecular Engineering and College of Engineering and BIC-ESAT Peking University)

  • Jinjia Liu

    (Chinese Academy of Sciences
    Synfuels China Co. Ltd)

  • Xi Liu

    (Shanghai Jiao Tong University)

  • Zirui Gao

    (College of Chemistry and Molecular Engineering and College of Engineering and BIC-ESAT Peking University)

  • Ning Rui

    (Brookhaven National Laboratory)

  • Siyu Yao

    (Zhejiang University)

  • Feng Zhang

    (State University of New York)

  • Maolin Wang

    (College of Chemistry and Molecular Engineering and College of Engineering and BIC-ESAT Peking University)

  • Chang Liu

    (University of Virginia)

  • Lili Han

    (Brookhaven National Laboratory)

  • Feng Yang

    (Southern University of Science and Technology)

  • Sen Zhang

    (University of Virginia)

  • Xiao-dong Wen

    (Chinese Academy of Sciences
    Synfuels China Co. Ltd)

  • Sanjaya D. Senanayake

    (Brookhaven National Laboratory)

  • Yichao Wu

    (Zhejiang University of Technology)

  • Xiaonian Li

    (Zhejiang University of Technology)

  • José A. Rodriguez

    (Brookhaven National Laboratory
    State University of New York)

  • Ding Ma

    (College of Chemistry and Molecular Engineering and College of Engineering and BIC-ESAT Peking University)

Abstract

Reversing the thermal induced sintering phenomenon and forming high temperature stable fine dispersed metallic centers with unique structural and electronic properties is one of the ever-lasting targets of heterogeneous catalysis. Here we report that the dispersion of metallic Ni particles into under-coordinated two-dimensional Ni clusters over γ-Mo2N is a thermodynamically favorable process based on the AIMD simulation. A Ni-4nm/γ-Mo2N model catalyst is synthesized and used to further study the reverse sintering effect by the combination of multiple in-situ characterization methods, including in-situ quick XANES and EXAFS, ambient pressure XPS and environmental SE/STEM etc. The under-coordinated two-dimensional layered Ni clusters on molybdenum nitride support generated from the Ni-4nm/γ-Mo2N has been demonstrated to be a thermally stable catalyst in 50 h stability test in CO2 hydrogenation, and exhibits a remarkable catalytic selectivity reverse compared with traditional Ni particles-based catalyst, leading to a chemo-specific CO2 hydrogenation to CO.

Suggested Citation

  • Lili Lin & Jinjia Liu & Xi Liu & Zirui Gao & Ning Rui & Siyu Yao & Feng Zhang & Maolin Wang & Chang Liu & Lili Han & Feng Yang & Sen Zhang & Xiao-dong Wen & Sanjaya D. Senanayake & Yichao Wu & Xiaonia, 2021. "Reversing sintering effect of Ni particles on γ-Mo2N via strong metal support interaction," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:12:y:2021:i:1:d:10.1038_s41467-021-27116-8
    DOI: 10.1038/s41467-021-27116-8
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    Cited by:

    1. Cong-Xiao Wang & Hao-Xin Liu & Hao Gu & Jin-Ying Li & Xiao-Meng Lai & Xin-Pu Fu & Wei-Wei Wang & Qiang Fu & Feng Ryan Wang & Chao Ma & Chun-Jiang Jia, 2024. "Hydroxylated TiO2-induced high-density Ni clusters for breaking the activity-selectivity trade-off of CO2 hydrogenation," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    2. Yamei Fan & Rongtan Li & Beibei Wang & Xiaohui Feng & Xiangze Du & Chengxiang Liu & Fei Wang & Conghui Liu & Cui Dong & Yanxiao Ning & Rentao Mu & Qiang Fu, 2024. "Water-assisted oxidative redispersion of Cu particles through formation of Cu hydroxide at room temperature," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    3. Xin Tang & Chuqiao Song & Haibo Li & Wenyu Liu & Xinyu Hu & Qiaoli Chen & Hanfeng Lu & Siyu Yao & Xiao-nian Li & Lili Lin, 2024. "Thermally stable Ni foam-supported inverse CeAlOx/Ni ensemble as an active structured catalyst for CO2 hydrogenation to methane," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    4. Zhongzhe Wei & Zijiang Zhao & Chenglong Qiu & Songtao Huang & Zihao Yao & Mingxuan Wang & Yi Chen & Yue Lin & Xing Zhong & Xiaonian Li & Jianguo Wang, 2023. "Tripodal Pd metallenes mediated by Nb2C MXenes for boosting alkynes semihydrogenation," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    5. Yaguang Li & Xianhua Bai & Dachao Yuan & Chenyang Yu & Xingyuan San & Yunna Guo & Liqiang Zhang & Jinhua Ye, 2023. "Cu-based high-entropy two-dimensional oxide as stable and active photothermal catalyst," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    6. Hao-Xin Liu & Jin-Ying Li & Xuetao Qin & Chao Ma & Wei-Wei Wang & Kai Xu & Han Yan & Dequan Xiao & Chun-Jiang Jia & Qiang Fu & Ding Ma, 2022. "Ptn–Ov synergistic sites on MoOx/γ-Mo2N heterostructure for low-temperature reverse water–gas shift reaction," Nature Communications, Nature, vol. 13(1), pages 1-10, December.

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