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Non defect-stabilized thermally stable single-atom catalyst

Author

Listed:
  • Rui Lang

    (Dalian Institute of Chemical Physics, Chinese Academy of Sciences)

  • Wei Xi

    (Tianjin University of Technology)

  • Jin-Cheng Liu

    (Tsinghua University)

  • Yi-Tao Cui

    (The University of Tokyo)

  • Tianbo Li

    (Dalian Institute of Chemical Physics, Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Adam Fraser Lee

    (Royal Melbourne Institute of Technology University)

  • Fang Chen

    (Dalian Institute of Chemical Physics, Chinese Academy of Sciences)

  • Yang Chen

    (Dalian Institute of Chemical Physics, Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Lei Li

    (Synchrotron Radiation Nanotechnology Center, University of Hyogo)

  • Lin Li

    (Dalian Institute of Chemical Physics, Chinese Academy of Sciences)

  • Jian Lin

    (Dalian Institute of Chemical Physics, Chinese Academy of Sciences)

  • Shu Miao

    (Dalian Institute of Chemical Physics, Chinese Academy of Sciences)

  • Xiaoyan Liu

    (Dalian Institute of Chemical Physics, Chinese Academy of Sciences)

  • Ai-Qin Wang

    (Dalian Institute of Chemical Physics, Chinese Academy of Sciences)

  • Xiaodong Wang

    (Dalian Institute of Chemical Physics, Chinese Academy of Sciences)

  • Jun Luo

    (Tianjin University of Technology)

  • Botao Qiao

    (Dalian Institute of Chemical Physics, Chinese Academy of Sciences
    Dalian National Laboratory for Clean Energy)

  • Jun Li

    (Tsinghua University
    Southern University of Science and Technology)

  • Tao Zhang

    (Dalian Institute of Chemical Physics, Chinese Academy of Sciences)

Abstract

Surface-supported isolated atoms in single-atom catalysts (SACs) are usually stabilized by diverse defects. The fabrication of high-metal-loading and thermally stable SACs remains a formidable challenge due to the difficulty of creating high densities of underpinning stable defects. Here we report that isolated Pt atoms can be stabilized through a strong covalent metal-support interaction (CMSI) that is not associated with support defects, yielding a high-loading and thermally stable SAC by trapping either the already deposited Pt atoms or the PtO2 units vaporized from nanoparticles during high-temperature calcination. Experimental and computational modeling studies reveal that iron oxide reducibility is crucial to anchor isolated Pt atoms. The resulting high concentrations of single atoms enable specific activities far exceeding those of conventional nanoparticle catalysts. This non defect-stabilization strategy can be extended to non-reducible supports by simply doping with iron oxide, thus paving a new way for constructing high-loading SACs for diverse industrially important catalytic reactions.

Suggested Citation

  • Rui Lang & Wei Xi & Jin-Cheng Liu & Yi-Tao Cui & Tianbo Li & Adam Fraser Lee & Fang Chen & Yang Chen & Lei Li & Lin Li & Jian Lin & Shu Miao & Xiaoyan Liu & Ai-Qin Wang & Xiaodong Wang & Jun Luo & Bot, 2019. "Non defect-stabilized thermally stable single-atom catalyst," Nature Communications, Nature, vol. 10(1), pages 1-10, December.
  • Handle: RePEc:nat:natcom:v:10:y:2019:i:1:d:10.1038_s41467-018-08136-3
    DOI: 10.1038/s41467-018-08136-3
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    Cited by:

    1. Xiaohui He & Hao Zhang & Xingcong Zhang & Ying Zhang & Qian He & Hongyu Chen & Yujie Cheng & Mi Peng & Xuetao Qin & Hongbing Ji & Ding Ma, 2022. "Building up libraries and production line for single atom catalysts with precursor-atomization strategy," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    2. Jingyi Yang & Yike Huang & Haifeng Qi & Chaobin Zeng & Qike Jiang & Yitao Cui & Yang Su & Xiaorui Du & Xiaoli Pan & Xiaoyan Liu & Weizhen Li & Botao Qiao & Aiqin Wang & Tao Zhang, 2022. "Modulating the strong metal-support interaction of single-atom catalysts via vicinal structure decoration," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    3. Xiongwei Zhong & Xiao Xiao & Qizhen Li & Mengtian Zhang & Zhitong Li & Leyi Gao & Biao Chen & Zhiyang Zheng & Qingjin Fu & Xingzhu Wang & Guangmin Zhou & Baomin Xu, 2024. "Understanding the active site in chameleon-like bifunctional catalyst for practical rechargeable zinc-air batteries," Nature Communications, Nature, vol. 15(1), pages 1-17, December.
    4. Junjie Li & Ya-fei Jiang & Qi Wang & Cong-Qiao Xu & Duojie Wu & Mohammad Norouzi Banis & Keegan R. Adair & Kieran Doyle-Davis & Debora Motta Meira & Y. Zou Finfrock & Weihan Li & Lei Zhang & Tsun-Kong, 2021. "A general strategy for preparing pyrrolic-N4 type single-atom catalysts via pre-located isolated atoms," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    5. Jiaxin Li & Kai Li & Zhao Li & Chunxue Wang & Yifei Liang & Yatong Pang & Jinzhu Ma & Fei Wang & Ping Ning & Hong He, 2024. "Capture of single Ag atoms through high-temperature-induced crystal plane reconstruction," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    6. Song Shi & Piaoping Yang & Chaochao Dun & Weiqing Zheng & Jeffrey J. Urban & Dionisios G. Vlachos, 2023. "Selective hydrogenation via precise hydrogen bond interactions on catalytic scaffolds," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    7. Weiwei Fu & Jin Wan & Huijuan Zhang & Jian Li & Weigen Chen & Yuke Li & Zaiping Guo & Yu Wang, 2022. "Photoinduced loading of electron-rich Cu single atoms by moderate coordination for hydrogen evolution," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    8. Lili Lin & Jinjia Liu & Xi Liu & Zirui Gao & Ning Rui & Siyu Yao & Feng Zhang & Maolin Wang & Chang Liu & Lili Han & Feng Yang & Sen Zhang & Xiao-dong Wen & Sanjaya D. Senanayake & Yichao Wu & Xiaonia, 2021. "Reversing sintering effect of Ni particles on γ-Mo2N via strong metal support interaction," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    9. Khandelwal, Akshat & Maarisetty, Dileep & Baral, Saroj Sundar, 2022. "Fundamentals and application of single-atom photocatalyst in sustainable energy and environmental applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    10. Leong, Kee Wah & Wang, Yifei & Ni, Meng & Pan, Wending & Luo, Shijing & Leung, Dennis Y.C., 2022. "Rechargeable Zn-air batteries: Recent trends and future perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).

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