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Nitrogen Migration during Pyrolysis of Raw and Acid Leached Maize Straw

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  • Huan Li

    (Bioenergy and Environment Science & Technology Laboratory, College of Engineering, China Agricultural University, Beijing 100083, China
    Key Laboratory of Clean Production and Utilization of Renewable Energy, Ministry of Agriculture and Rural Affairs, Beijing 100083, China
    National Center for International Research of BioEnergy Science and Technology, Ministry of Science and Technology, Beijing 100083, China)

  • Huawei Mou

    (Bioenergy and Environment Science & Technology Laboratory, College of Engineering, China Agricultural University, Beijing 100083, China
    Key Laboratory of Clean Production and Utilization of Renewable Energy, Ministry of Agriculture and Rural Affairs, Beijing 100083, China
    National Center for International Research of BioEnergy Science and Technology, Ministry of Science and Technology, Beijing 100083, China)

  • Nan Zhao

    (Bioenergy and Environment Science & Technology Laboratory, College of Engineering, China Agricultural University, Beijing 100083, China
    Key Laboratory of Clean Production and Utilization of Renewable Energy, Ministry of Agriculture and Rural Affairs, Beijing 100083, China
    National Center for International Research of BioEnergy Science and Technology, Ministry of Science and Technology, Beijing 100083, China)

  • Yaohong Yu

    (Bioenergy and Environment Science & Technology Laboratory, College of Engineering, China Agricultural University, Beijing 100083, China
    Key Laboratory of Clean Production and Utilization of Renewable Energy, Ministry of Agriculture and Rural Affairs, Beijing 100083, China
    National Center for International Research of BioEnergy Science and Technology, Ministry of Science and Technology, Beijing 100083, China)

  • Quan Hong

    (Bioenergy and Environment Science & Technology Laboratory, College of Engineering, China Agricultural University, Beijing 100083, China
    Key Laboratory of Clean Production and Utilization of Renewable Energy, Ministry of Agriculture and Rural Affairs, Beijing 100083, China
    National Center for International Research of BioEnergy Science and Technology, Ministry of Science and Technology, Beijing 100083, China)

  • Mperejekumana Philbert

    (Bioenergy and Environment Science & Technology Laboratory, College of Engineering, China Agricultural University, Beijing 100083, China
    Key Laboratory of Clean Production and Utilization of Renewable Energy, Ministry of Agriculture and Rural Affairs, Beijing 100083, China
    National Center for International Research of BioEnergy Science and Technology, Ministry of Science and Technology, Beijing 100083, China)

  • Yuguang Zhou

    (Bioenergy and Environment Science & Technology Laboratory, College of Engineering, China Agricultural University, Beijing 100083, China
    Key Laboratory of Clean Production and Utilization of Renewable Energy, Ministry of Agriculture and Rural Affairs, Beijing 100083, China
    National Center for International Research of BioEnergy Science and Technology, Ministry of Science and Technology, Beijing 100083, China
    Prataculture Machinery and Equipment Research Center, College of Engineering, China Agricultural University, Beijing 100083, China)

  • Hossein Beidaghy Dizaji

    (Thermo-chemical Conversion Department, DBFZ Deutsches Biomasseforschungszentrum Gemeinnützige GmbH, Torgauer Straße 116, 04347 Leipzig, Germany)

  • Renjie Dong

    (Bioenergy and Environment Science & Technology Laboratory, College of Engineering, China Agricultural University, Beijing 100083, China
    Key Laboratory of Clean Production and Utilization of Renewable Energy, Ministry of Agriculture and Rural Affairs, Beijing 100083, China
    National Center for International Research of BioEnergy Science and Technology, Ministry of Science and Technology, Beijing 100083, China
    Yantai Institute, China Agricultural University, No. 2006 Binhai Zhonglu, Laishan District, Yantai 264670, China)

Abstract

Solid biofuel is considered as a possible substitute for coal in household heat production because of the available and sustainable raw materials, while NO x emissions from its combustion have become a serious problem. Nitrogen-containing compounds in pyrolysis products have important effects on the conversion of fuel-N into NO x -N. Understanding these converting pathways is important for the environmentally friendly use of biomass fuels. The nitrogen migration during pyrolysis of raw and acid leached maize straw at various temperatures was investigated in this study. Thermal gravimetric analysis and X-ray photoelectron spectroscopy were used to investigate the performances of thermal decomposition and pyrolysis products from samples. The main nitrogen functional groups in biomass and biochar products were N-A (amine-N/amide-N/protein-N), pyridine-N, and pyrrole-N, according to the findings. The most common gaseous NO x precursor was NH 3 , which was produced primarily during the conversion of N-A to pyridine-N and pyrrole-N. The formation of HCN mainly came from the secondary decomposition of heterocyclic-N at high temperatures. Before the pyrolysis temperature increased to 650 °C, more than half of the fuel-N was stored in the biochar. At the same pyrolysis temperature, acid-leached maize straw yielded more gas-N and char-N than the raw biomass. The highest char-N yield of 76.39 wt% was obtained from acid-leached maize straw (AMS) pyrolysis at 350 °C. Low pyrolysis temperature and acid-leaching treatment can help to decrease nitrogen release from stable char structure, providing support for reducing nitrogenous pollutant emissions from straw fuel.

Suggested Citation

  • Huan Li & Huawei Mou & Nan Zhao & Yaohong Yu & Quan Hong & Mperejekumana Philbert & Yuguang Zhou & Hossein Beidaghy Dizaji & Renjie Dong, 2021. "Nitrogen Migration during Pyrolysis of Raw and Acid Leached Maize Straw," Sustainability, MDPI, vol. 13(7), pages 1-15, March.
    • Handle: RePEc:gam:jsusta:v:13:y:2021:i:7:p:3786-:d:526180
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    References listed on IDEAS

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    Cited by:

    1. Hossein Beidaghy Dizaji & Thomas Zeng & Volker Lenz & Dirk Enke, 2022. "Valorization of Residues from Energy Conversion of Biomass for Advanced and Sustainable Material Applications," Sustainability, MDPI, vol. 14(9), pages 1-5, April.

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