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Effect of washing with diluted acids on Enteromorpha clathrata pyrolysis products: Towards enhanced bio-oil from seaweeds

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  • Cao, Bin
  • Wang, Shuang
  • Hu, Yamin
  • Abomohra, Abd El-Fatah
  • Qian, Lili
  • He, Zhixia
  • Wang, Qian
  • Uzoejinwa, Benjamin Bernard
  • Esakkimuthu, Sivakumar

Abstract

Nowadays, macroalgae are widely discussed as advantageous alternative feedstock for crude bio-oil production using pyrolysis. In the present work, pyrolysis products of Enteromorpha clathrata washed with 7% phosphoric acid, hydrochloric acid and sulfuric acid were studied. In general, washing with diluted acids resulted in significant increase in the yields of bio-oil and non-condensable gas over the control in favor of the bio-char. In addition, HCl pretreatment enhanced the relative contents of aliphatic hydrocarbons in the bio-oil by 1.5 times over the control. Furthermore, HCl pretreatment showed 37% and 52.6% reduction in acids and oxygen-containing compounds, respectively, with respect to the control. FTIR analysis showed that acid-washing led to reduction in OH stretching vibration, confirming that it can disrupt hydroxyl bonds reducing phenols, carboxylic acids and water impurities in the bio-oil. In conclusion, washing of biomass using diluted acids could play a key role to enhance the bio-oil yield and significantly influence products characteristics; particularly, HCl enhanced bio-oil yield with higher aliphatic hydrocarbons proportion.

Suggested Citation

  • Cao, Bin & Wang, Shuang & Hu, Yamin & Abomohra, Abd El-Fatah & Qian, Lili & He, Zhixia & Wang, Qian & Uzoejinwa, Benjamin Bernard & Esakkimuthu, Sivakumar, 2019. "Effect of washing with diluted acids on Enteromorpha clathrata pyrolysis products: Towards enhanced bio-oil from seaweeds," Renewable Energy, Elsevier, vol. 138(C), pages 29-38.
    • Handle: RePEc:eee:renene:v:138:y:2019:i:c:p:29-38
    DOI: 10.1016/j.renene.2019.01.084
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    2. Kumar, R. & Strezov, V. & Weldekidan, H. & He, J. & Singh, S. & Kan, T. & Dastjerdi, B., 2020. "Lignocellulose biomass pyrolysis for bio-oil production: A review of biomass pre-treatment methods for production of drop-in fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 123(C).
    3. Badshah, Syed Lal & Shah, Zahir & Francisco Alves, José Luiz & Gomes da Silva, Jean Constantino & Iqbal, Arshad, 2021. "Pyrolysis of the freshwater macroalgae Spirogyra crassa: Evaluating its bioenergy potential using kinetic triplet and thermodynamic parameters," Renewable Energy, Elsevier, vol. 179(C), pages 1169-1178.
    4. Kumar, R. & Strezov, V., 2021. "Thermochemical production of bio-oil: A review of downstream processing technologies for bio-oil upgrading, production of hydrogen and high value-added products," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).

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