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Combustion Characteristics, Kinetics, SO 2 and NO Release of Low-Grade Biomass Materials and Briquettes

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  • Jianhui Qi

    (Shandong Engineering Laboratory for High-Efficiency Energy Conservation and Energy Storage Technology & Equipment, School of Energy and Power Engineering, Shandong University, Jinan 250061, China
    Beijing Key Laboratory of Multiphase Flow and Heat Transfer for Low Grade Energy Utilization, North China Electric Power University, Beijing 102206, China)

  • Haopeng Li

    (Shandong Engineering Laboratory for High-Efficiency Energy Conservation and Energy Storage Technology & Equipment, School of Energy and Power Engineering, Shandong University, Jinan 250061, China)

  • Qian Wang

    (School of Thermal Engineering, Shandong Jianzhu University, Jinan 250101, China)

  • Kuihua Han

    (Shandong Engineering Laboratory for High-Efficiency Energy Conservation and Energy Storage Technology & Equipment, School of Energy and Power Engineering, Shandong University, Jinan 250061, China)

Abstract

The influence of the briquetting process on SO 2 and NO release characteristics, combustion properties and kinetic characteristics during biomass combustion was investigated. Two biomass (Wheat straw and Tree bulk) and two obtained briquettes were analysed. The briquetting process helps to prevent the release of SO 2 and NO. The experimental results show that once the biomass is made into a briquette, when the reaction temperature is 900 ∘ C , the sulphur release ratio for TB was reduced from 34.7% to 4.3% and for WS was reduced from 12.4% to 1.6%. When the reaction temperature increases to 1000 ∘ C , the sulphur release ratio for TB was reduced from 73.4% to 30.4%, for WS it was reduced from 58.4% to 10.2%. SEM micrographs show that the compact structure of the TB-Briquette and WS-Briquette reduce the rate of SO 2 and NO release during combustion. The thermogravimetry confirmed that the combustion performance of WS-Briquette is the best, while the TB-Briquette is the worst. According to the Coats-Redfern method, the fitting was performed at segments of 250 ∘ C to 550 ∘ C , and the correlation coefficient of the fitting degree was above 0.99. The effective collision rate of WS-Briquette is much higher than that of other briquettes. Compared to BR-1 and BR-2, trying to mix TB with WS to make a compound biomass briquette can enhance the combustion performance of TB-Briquette. The results may guide the upgrading of biomass briquettes technology and benefit the efficient application of biomass briquettes.

Suggested Citation

  • Jianhui Qi & Haopeng Li & Qian Wang & Kuihua Han, 2021. "Combustion Characteristics, Kinetics, SO 2 and NO Release of Low-Grade Biomass Materials and Briquettes," Energies, MDPI, vol. 14(9), pages 1-13, May.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:9:p:2655-:d:549371
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    References listed on IDEAS

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    1. Qi, Jianhui & Li, Hui & Han, Kuihua & Zuo, Qi & Gao, Jie & Wang, Qian & Lu, Chunmei, 2016. "Influence of ammonium dihydrogen phosphate on potassium retention and ash melting characteristics during combustion of biomass," Energy, Elsevier, vol. 102(C), pages 244-251.
    2. Andrés Niño & Nelson Arzola & Oscar Araque, 2020. "Experimental Study on the Mechanical Properties of Biomass Briquettes from a Mixture of Rice Husk and Pine Sawdust," Energies, MDPI, vol. 13(5), pages 1-19, February.
    3. Qi, Jianhui & Han, Kuihua & Wang, Qian & Gao, Jie, 2017. "Carbonization of biomass: Effect of additives on alkali metals residue, SO2 and NO emission of chars during combustion," Energy, Elsevier, vol. 130(C), pages 560-569.
    4. Zhou, Yuguang & Zhang, Zongxi & Zhang, Yixiang & Wang, Yungang & Yu, Yang & Ji, Fang & Ahmad, Riaz & Dong, Renjie, 2016. "A comprehensive review on densified solid biofuel industry in China," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 1412-1428.
    5. Han, Kuihua & Gao, Jie & Qi, Jianhui, 2019. "The study of sulphur retention characteristics of biomass briquettes during combustion," Energy, Elsevier, vol. 186(C).
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