IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v15y2022i23p8908-d983944.html
   My bibliography  Save this article

Metal-Organic Framework Adsorbent Materials in HVAC Systems: General Survey and Theoretical Assessment

Author

Listed:
  • Andrea Rocchetti

    (Department of Industrial Engineering, University of Florence, 50139 Florence, Italy)

  • Martina Lippi

    (Department of Industrial Engineering, University of Florence, 50139 Florence, Italy)

  • Luca Socci

    (Department of Industrial Engineering, University of Florence, 50139 Florence, Italy)

  • Paride Gullo

    (Department of Mechanical and Electrical Engineering, University of Southern Denmark, 6400 Sønderborg, Denmark)

  • Vahid Khorshidi

    (RAC R&D Innovation Lab, Danfoss A/S, 6430 Nordborg, Denmark)

  • Lorenzo Talluri

    (Department of Industrial Engineering, University of Florence, 50139 Florence, Italy)

Abstract

In this paper, the use of Metal-Organic Framework (MOF) materials as an option for the energy efficiency enhancement of HVAC systems is investigated. In particular, the possibility of using MOFs as dehumidifying materials to reduce the latent load associated with the moisture content of the airflows is studied. A literature review is proposed, highlighting the benefits of using MOFs instead of other adsorbents (e.g., silica-gel) and discussing the unique features (high water uptake capacity and low regeneration temperatures) that make MOFs a preferential desiccant. The possibility to finely tune these properties is also underlined, reporting some explicative examples. A theoretical proposal of a psychrometric transformation, to be performed in a HVAC system equipped with a MOF-Assisted Dehumidifier (MAD), is presented. This transformation is compared with a traditional one (cooling and dehumidification operated by a cooling coil with low temperatures of the coolant). The preliminary numerical simulations, conducted on a reference case study in Florence, Italy, show an estimated energy saving of 30–50%, leading us to consider the use of this technology as a very competitive one in the air-conditioning sector.

Suggested Citation

  • Andrea Rocchetti & Martina Lippi & Luca Socci & Paride Gullo & Vahid Khorshidi & Lorenzo Talluri, 2022. "Metal-Organic Framework Adsorbent Materials in HVAC Systems: General Survey and Theoretical Assessment," Energies, MDPI, vol. 15(23), pages 1-14, November.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:23:p:8908-:d:983944
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/15/23/8908/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/15/23/8908/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Sultan, Muhammad & El-Sharkawy, Ibrahim I. & Miyazaki, Takahiko & Saha, Bidyut Baran & Koyama, Shigeru, 2015. "An overview of solid desiccant dehumidification and air conditioning systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 46(C), pages 16-29.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Gao, D.C. & Sun, Y.J. & Ma, Z. & Ren, H., 2021. "A review on integration and design of desiccant air-conditioning systems for overall performance improvements," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).
    2. Speerforck, Arne & Schmitz, Gerhard, 2016. "Experimental investigation of a ground-coupled desiccant assisted air conditioning system," Applied Energy, Elsevier, vol. 181(C), pages 575-585.
    3. Mahmood, Muhammad H. & Sultan, Muhammad & Miyazaki, Takahiko & Koyama, Shigeru & Maisotsenko, Valeriy S., 2016. "Overview of the Maisotsenko cycle – A way towards dew point evaporative cooling," Renewable and Sustainable Energy Reviews, Elsevier, vol. 66(C), pages 537-555.
    4. Hafiz M. Asfahan & Uzair Sajjad & Muhammad Sultan & Imtiyaz Hussain & Khalid Hamid & Mubasher Ali & Chi-Chuan Wang & Redmond R. Shamshiri & Muhammad Usman Khan, 2021. "Artificial Intelligence for the Prediction of the Thermal Performance of Evaporative Cooling Systems," Energies, MDPI, vol. 14(13), pages 1-20, July.
    5. Gordeeva, L.G. & Aristov, Yu.I., 2019. "Adsorptive heat storage and amplification: New cycles and adsorbents," Energy, Elsevier, vol. 167(C), pages 440-453.
    6. Shamim, Jubair A. & Hsu, Wei-Lun & Paul, Soumyadeep & Yu, Lili & Daiguji, Hirofumi, 2021. "A review of solid desiccant dehumidifiers: Current status and near-term development goals in the context of net zero energy buildings," Renewable and Sustainable Energy Reviews, Elsevier, vol. 137(C).
    7. Elnagar, Essam & Pezzutto, Simon & Duplessis, Bruno & Fontenaille, Théodore & Lemort, Vincent, 2023. "A comprehensive scouting of space cooling technologies in Europe: Key characteristics and development trends," Renewable and Sustainable Energy Reviews, Elsevier, vol. 186(C).
    8. Salehi, Ali Akbar & Ghannadi-Maragheh, Mohammad & Torab-Mostaedi, Meisam & Torkaman, Rezvan & Asadollahzadeh, Mehdi, 2020. "A review on the water-energy nexus for drinking water production from humid air," Renewable and Sustainable Energy Reviews, Elsevier, vol. 120(C).
    9. Shabir, Faizan & Sultan, Muhammad & Miyazaki, Takahiko & Saha, Bidyut B. & Askalany, Ahmed & Ali, Imran & Zhou, Yuguang & Ahmad, Riaz & Shamshiri, Redmond R., 2020. "Recent updates on the adsorption capacities of adsorbent-adsorbate pairs for heat transformation applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    10. Hadeed Ashraf & Muhammad Sultan & Redmond R. Shamshiri & Farrukh Abbas & Muhammad Farooq & Uzair Sajjad & Hafiz Md-Tahir & Muhammad H. Mahmood & Fiaz Ahmad & Yousaf R. Taseer & Aamir Shahzad & Badar M, 2021. "Dynamic Evaluation of Desiccant Dehumidification Evaporative Cooling Options for Greenhouse Air-Conditioning Application in Multan (Pakistan)," Energies, MDPI, vol. 14(4), pages 1-21, February.
    11. Muhammad Aleem & Ghulam Hussain & Muhammad Sultan & Takahiko Miyazaki & Muhammad H. Mahmood & Muhammad I. Sabir & Abdul Nasir & Faizan Shabir & Zahid M. Khan, 2020. "Experimental Investigation of Desiccant Dehumidification Cooling System for Climatic Conditions of Multan (Pakistan)," Energies, MDPI, vol. 13(21), pages 1-23, October.
    12. Yang, Yifan & Cui, Gary & Lan, Christopher Q., 2019. "Developments in evaporative cooling and enhanced evaporative cooling - A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 113(C), pages 1-1.
    13. Amit Kumar & Avadhesh Yadav, 2017. "Experimental investigation of solar-powered desiccant cooling system by using composite desiccant “CaCl2/jute”," Environment, Development and Sustainability: A Multidisciplinary Approach to the Theory and Practice of Sustainable Development, Springer, vol. 19(4), pages 1279-1292, August.
    14. Shazia Noor & Hadeed Ashraf & Muhammad Sultan & Zahid Mahmood Khan, 2020. "Evaporative Cooling Options for Building Air-Conditioning: A Comprehensive Study for Climatic Conditions of Multan (Pakistan)," Energies, MDPI, vol. 13(12), pages 1-23, June.
    15. Husham Abdulmalek, Shaymaa & Khalaji Assadi, Morteza & Al-Kayiem, Hussain H. & Gitan, Ali Ahmed, 2018. "A comparative analysis on the uniformity enhancement methods of solar thermal drying," Energy, Elsevier, vol. 148(C), pages 1103-1115.
    16. Ghulam Hussain & Muhammad Aleem & Muhammad Sultan & Uzair Sajjad & Sobhy M. Ibrahim & Redmond R. Shamshiri & Muhammad Farooq & Muhammad Usman Khan & Muhammad Bilal, 2022. "Evaluating Evaporative Cooling Assisted Solid Desiccant Dehumidification System for Agricultural Storage Application," Sustainability, MDPI, vol. 14(3), pages 1-25, January.
    17. Tokarev, Mikhail M. & Gordeeva, Larisa G. & Grekova, Alexandra D. & Aristov, Yuri I., 2018. "Adsorption cycle “heat from cold” for upgrading the ambient heat: The testing a lab-scale prototype with the composite sorbent CaClBr/silica," Applied Energy, Elsevier, vol. 211(C), pages 136-145.
    18. Abou-Ziyan, H. & Abd El-Raheim, D. & Mahmoud, O. & Fatouh, M., 2017. "Performance characteristics of thin-multilayer activated alumina bed," Applied Energy, Elsevier, vol. 190(C), pages 29-42.
    19. Sultan, Muhammad & Miyazaki, Takahiko & Saha, Bidyut Baran & Koyama, Shigeru, 2016. "Steady-state investigation of water vapor adsorption for thermally driven adsorption based greenhouse air-conditioning system," Renewable Energy, Elsevier, vol. 86(C), pages 785-795.
    20. Wu, X.N. & Ge, T.S. & Dai, Y.J. & Wang, R.Z., 2018. "Review on substrate of solid desiccant dehumidification system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3236-3249.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:15:y:2022:i:23:p:8908-:d:983944. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.