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Sustainable hydrogen and syngas production from waste valorization of biodiesel synthesis by-product: Green chemistry approach

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  • Khademi, Mohammad Hasan
  • Alipour-Dehkordi, Afshar
  • Nalchifard, Fereshteh

Abstract

Currently, global concerns about greenhouse gas emissions, climate changes, and over-consumption of fossil fuels have drawn human attention to the use of environmentally friendly biofuels and renewable energy sources such as biodiesel. Though biodiesel can serve as an alternative source to fossil diesel fuel, it is quite comparatively expensive to produce. This challenge can be nullified by converting glycerol, a main by-product during biodiesel synthesis, into valuable products such as hydrogen. Catalytic steam reforming of bio-glycerol is one of the potential technologies to address this requirement, which is the main subject of this research. However, this process suffers from energy supply and environmental issues due to CO2 emissions. In an attempt to resolve this problem, an energy self-sufficient approach has been developed to provide the required energy in an eco-friendly way through the combustion of a part of the produced hydrogen. Among the impacts of this novel procedure on environmental and energy resources management, the following can be mentioned: eliminating dependence on hydrocarbon energy resources; non-greenhouse gas emissions; hydrogen production as renewable energy; and syngas production suitable for methanol and GTL synthesis processes. After sensitivity analysis and optimization of thermal efficiency, the highest hydrogen recovery (≅70%) and H2:CO≅2 can be achieved at acceptable glycerol conversion (≅81%) and the lowest level of hydrogen consumption (which is 1/5 of the total produced hydrogen). Furthermore, comparing this process with other conventional hydrogen production technologies showed that it was competitive with other ones in terms of thermal efficiency (≅50%), making it highly promising for commercialization.

Suggested Citation

  • Khademi, Mohammad Hasan & Alipour-Dehkordi, Afshar & Nalchifard, Fereshteh, 2023. "Sustainable hydrogen and syngas production from waste valorization of biodiesel synthesis by-product: Green chemistry approach," Renewable and Sustainable Energy Reviews, Elsevier, vol. 175(C).
  • Handle: RePEc:eee:rensus:v:175:y:2023:i:c:s1364032123000473
    DOI: 10.1016/j.rser.2023.113191
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    References listed on IDEAS

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    1. Okoye, P.U. & Abdullah, A.Z. & Hameed, B.H., 2017. "A review on recent developments and progress in the kinetics and deactivation of catalytic acetylation of glycerol—A byproduct of biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 387-401.
    2. Dou, Binlin & Song, Yongchen & Wang, Chao & Chen, Haisheng & Xu, Yujie, 2014. "Hydrogen production from catalytic steam reforming of biodiesel byproduct glycerol: Issues and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 30(C), pages 950-960.
    3. Charisiou, N.D. & Italiano, C. & Pino, L. & Sebastian, V. & Vita, A. & Goula, M.A., 2020. "Hydrogen production via steam reforming of glycerol over Rh/γ-Al2O3 catalysts modified with CeO2, MgO or La2O3," Renewable Energy, Elsevier, vol. 162(C), pages 908-925.
    4. Kothari, Richa & Buddhi, D. & Sawhney, R.L., 2008. "Comparison of environmental and economic aspects of various hydrogen production methods," Renewable and Sustainable Energy Reviews, Elsevier, vol. 12(2), pages 553-563, February.
    5. Parthasarathy, Prakash & Narayanan, K. Sheeba, 2014. "Hydrogen production from steam gasification of biomass: Influence of process parameters on hydrogen yield – A review," Renewable Energy, Elsevier, vol. 66(C), pages 570-579.
    6. Masum, B.M. & Masjuki, H.H. & Kalam, M.A. & Rizwanul Fattah, I.M. & Palash, S.M. & Abedin, M.J., 2013. "Effect of ethanol–gasoline blend on NOx emission in SI engine," Renewable and Sustainable Energy Reviews, Elsevier, vol. 24(C), pages 209-222.
    7. He, Li & Fan, Yilin & Bellettre, Jérôme & Yue, Jun & Luo, Lingai, 2020. "A review on catalytic methane combustion at low temperatures: Catalysts, mechanisms, reaction conditions and reactor designs," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    8. Abdin, Zainul & Zafaranloo, Ali & Rafiee, Ahmad & Mérida, Walter & Lipiński, Wojciech & Khalilpour, Kaveh R., 2020. "Hydrogen as an energy vector," Renewable and Sustainable Energy Reviews, Elsevier, vol. 120(C).
    9. Macedo, M. Salomé & Soria, M.A. & Madeira, Luis M., 2021. "Process intensification for hydrogen production through glycerol steam reforming," Renewable and Sustainable Energy Reviews, Elsevier, vol. 146(C).
    10. Nikolaidis, Pavlos & Poullikkas, Andreas, 2017. "A comparative overview of hydrogen production processes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 597-611.
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