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Development and Comparison of Thermodynamic Equilibrium and Kinetic Approaches for Biomass Pyrolysis Modeling

Author

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  • Sahar Safarian

    (Department of Technology Management and Economics, Division of Environmental Systems Analysis, Chalmers University of Technology, 412 96 Gothenburg, Sweden)

  • Magnus Rydén

    (Department of Space, Earth and Environment, Division of Energy Technology, Chalmers University of Technology, 412 96 Gothenburg, Sweden)

  • Matty Janssen

    (Department of Technology Management and Economics, Division of Environmental Systems Analysis, Chalmers University of Technology, 412 96 Gothenburg, Sweden)

Abstract

Biomass pyrolysis is considered as a thermochemical conversion system that is performed under oxygen-depleted conditions. A large body of literature exists in which thermodynamic equilibrium (TE) and kinetic approaches have been applied to predict pyrolysis products. However, the reliability, accuracy and predictive power of both modeling approaches is an area of concern. To address these concerns, in this paper, two new simulation models based on the TE and kinetic approaches are developed using Aspen Plus, to analyze the performance of each approach. Subsequently, the results of two models are compared with modeling and experimental results available in the literature. The comparison shows that, on the one hand, the performance of the TE approach is not satisfactory and cannot be used as an effective way for pyrolysis modeling. On the other hand, the results generated by the new model based on the kinetic approach suggests that this approach is suitable for modeling biomass pyrolysis processes. Calculation of the root mean square error (RMS), to quantify the deviation of the model results from the experiment results, confirms that this kinetic model presents superior agreement with experimental data in comparison with other kinetic models in the literature. The acquired RMS for the developed kinetic method in this paper varies within the span of 1.2 to 3.2 depending on temperature (400–600 °C) and various feedstocks (pine spruce sawdust, bagasse, wood bark, beech wood and paddy straw).

Suggested Citation

  • Sahar Safarian & Magnus Rydén & Matty Janssen, 2022. "Development and Comparison of Thermodynamic Equilibrium and Kinetic Approaches for Biomass Pyrolysis Modeling," Energies, MDPI, vol. 15(11), pages 1-18, May.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:11:p:3999-:d:827063
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    References listed on IDEAS

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    1. Peters, Jens F. & Banks, Scott W. & Bridgwater, Anthony V. & Dufour, Javier, 2017. "A kinetic reaction model for biomass pyrolysis processes in Aspen Plus," Applied Energy, Elsevier, vol. 188(C), pages 595-603.
    2. Sahar Safarian & Runar Unnthorsson & Christiaan Richter, 2020. "Techno-Economic and Environmental Assessment of Power Supply Chain by Using Waste Biomass Gasification in Iceland," Biophysical Economics and Resource Quality, Springer, vol. 5(2), pages 1-13, June.
    3. Safarian, Sahar & Unnthorsson, Runar & Richter, Christiaan, 2020. "The equivalence of stoichiometric and non-stoichiometric methods for modeling gasification and other reaction equilibria," Renewable and Sustainable Energy Reviews, Elsevier, vol. 131(C).
    4. Mohammed J. Kabir & Ashfaque Ahmed Chowdhury & Mohammad G. Rasul, 2015. "Pyrolysis of Municipal Green Waste: A Modelling, Simulation and Experimental Analysis," Energies, MDPI, vol. 8(8), pages 1-20, July.
    5. Safarian, Sahar & Unnthorsson, Runar & Richter, Christiaan, 2020. "Performance analysis and environmental assessment of small-scale waste biomass gasification integrated CHP in Iceland," Energy, Elsevier, vol. 197(C).
    6. Khodaei, Hassan & Gonzalez, Luis & Chapela, Sergio & Porteiro, Jacobo & Nikrityuk, Petr & Olson, Chris, 2021. "CFD-based coupled multiphase modeling of biochar production using a large-scale pyrolysis plant," Energy, Elsevier, vol. 217(C).
    7. Kaushal, Priyanka & Tyagi, Rakesh, 2017. "Advanced simulation of biomass gasification in a fluidized bed reactor using ASPEN PLUS," Renewable Energy, Elsevier, vol. 101(C), pages 629-636.
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    1. Janaki Komandur & Abhishek Kumar & Preethi Para & Kaustubha Mohanty, 2022. "Kinetic Parameters Estimation of Thermal and Co-Pyrolysis of Groundnut De-oiled Cake and Polyethylene Terephthalate (PET) Waste," Energies, MDPI, vol. 15(20), pages 1-12, October.
    2. Savelii Kukharets & Gennadii Golub & Marek Wrobel & Olena Sukmaniuk & Krzysztof Mudryk & Taras Hutsol & Algirdas Jasinskas & Marcin Jewiarz & Jonas Cesna & Iryna Horetska, 2022. "A Theoretical Model of the Gasification Rate of Biomass and Its Experimental Confirmation," Energies, MDPI, vol. 15(20), pages 1-15, October.
    3. Grzegorz Czerski, 2022. "Pyrolysis and Gasification of Biomass and Waste," Energies, MDPI, vol. 15(19), pages 1-5, October.
    4. Sahar Safarian, 2023. "Climate Impact Comparison of Biomass Combustion and Pyrolysis with Different Applications for Biochar Based on LCA," Energies, MDPI, vol. 16(14), pages 1-11, July.

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