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The Thermochemical Conversion of Forestry Residues from Silver Fir ( Abies alba Mill.) by Torrefaction and Pyrolysis

Author

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  • Elena Butnaru

    (“Petru Poni” Institute of Macromolecular Chemistry, 41A Grigore Ghica Vodă Alley, 700487 Iași, Romania)

  • Mihai Brebu

    (“Petru Poni” Institute of Macromolecular Chemistry, 41A Grigore Ghica Vodă Alley, 700487 Iași, Romania)

Abstract

Forestry residue is a renewable energy biomass whose valorization has increased due to the interest in replacing exhaustible and environmentally unfriendly fossil resources. Needles, cones and bark from silver fir were thermally processed by separated and combined torrefaction (250 °C) and pyrolysis (550 °C). The torrefaction removed the humidity and extractives and degraded the hemicelluloses, significantly decreasing the oxygen content to ~11 wt% and increasing the carbon content to ~80 wt%, while enhancing the calorific value of the solids (~32 MJ/kg). The pyrolysis produced solid materials with high amounts of fixed carbon (~60–70 wt%) and high heating values, of ~29 MJ/kg. The combined torrefaction + pyrolysis increased the energy yield of the process and decreased the O/C and H/C atomic ratios to about 0.1 and 0.5, respectively, which is close to those of coals. It also led to condensable products with more homogeneously distributed compounds, regardless of the initial biomass type. More than 110 chemical compounds were confirmed in the condensable products, in amounts that depended on the type of starting material and on the thermal treatment. These included the following: terpenes, from extractives; furans, acids and linear ketones, from hemicelluloses; cyclic ketones and saccharides, from cellulose; and aromatic hydrocarbons and phenol derivatives, from lignin. Clear distinctions between the thermal procedures and the sample origins were evidenced by an exploratory data analysis (PCA), which suggested the presence of different types of lignin in the three starting materials.

Suggested Citation

  • Elena Butnaru & Mihai Brebu, 2022. "The Thermochemical Conversion of Forestry Residues from Silver Fir ( Abies alba Mill.) by Torrefaction and Pyrolysis," Energies, MDPI, vol. 15(10), pages 1-20, May.
  • Handle: RePEc:gam:jeners:v:15:y:2022:i:10:p:3483-:d:812276
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    References listed on IDEAS

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    1. Arkadiusz Dyjakon & Tomasz Noszczyk, 2020. "Alternative Fuels from Forestry Biomass Residue: Torrefaction Process of Horse Chestnuts, Oak Acorns, and Spruce Cones," Energies, MDPI, vol. 13(10), pages 1-19, May.
    2. Motte, Jean-Charles & Sambusiti, Cecilia & Dumas, Claire & Barakat, Abdellatif, 2015. "Combination of dry dark fermentation and mechanical pretreatment for lignocellulosic deconstruction: An innovative strategy for biofuels and volatile fatty acids recovery," Applied Energy, Elsevier, vol. 147(C), pages 67-73.
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    5. Matteo Borella & Alessandro A. Casazza & Gabriella Garbarino & Paola Riani & Guido Busca, 2022. "A Study of the Pyrolysis Products of Kraft Lignin," Energies, MDPI, vol. 15(3), pages 1-15, January.
    6. Arkadiusz Dyjakon & Tomasz Noszczyk & Agata Mostek, 2021. "Mechanical Durability and Grindability of Pellets after Torrefaction Process," Energies, MDPI, vol. 14(20), pages 1-16, October.
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    Cited by:

    1. Gendek, Arkadiusz & Piętka, Jacek & Aniszewska, Monika & Malaťák, Jan & Velebil, Jan & Tamelová, Barbora & Krilek, Jozef & Moskalik, Tadeusz, 2023. "Energy value of silver fir (Abies alba) and Norway spruce (Picea abies) wood depending on the degree of its decomposition by selected fungal species," Renewable Energy, Elsevier, vol. 215(C).
    2. Umut Şen & Bruno Esteves & Helena Pereira, 2023. "Pyrolysis and Extraction of Bark in a Biorefineries Context: A Critical Review," Energies, MDPI, vol. 16(13), pages 1-23, June.
    3. Grzegorz Czerski, 2022. "Pyrolysis and Gasification of Biomass and Waste," Energies, MDPI, vol. 15(19), pages 1-5, October.

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