IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v14y2021i4p870-d495241.html
   My bibliography  Save this article

The Relationship between Thermal Characteristics and Microstructure/Composition of Carbon Dioxide Hydrate in the Presence of Cyclopentane

Author

Listed:
  • Chun-Gang Xu

    (Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
    CAS Key Laboratory of Gas Hydrate, Guangzhou 510640, China
    Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development, Guangzhou 510640, China
    Guangzhou Center for Gas Hydrate Research, Chinese Academy of Sciences, Guangzhou 510640, China)

  • Min Wang

    (Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
    Nano Science and Technology Institute, University of Sciences and Technology of China, Suzhou 215123, China)

  • Gang Xu

    (Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
    School of Engneering Sciences, University of Sciences and Technology of China, Hefei 230023, China)

  • Xiao-Sen Li

    (Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
    CAS Key Laboratory of Gas Hydrate, Guangzhou 510640, China
    Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development, Guangzhou 510640, China
    Guangzhou Center for Gas Hydrate Research, Chinese Academy of Sciences, Guangzhou 510640, China)

  • Wei Zhang

    (Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
    School of Engneering Sciences, University of Sciences and Technology of China, Hefei 230023, China)

  • Jing Cai

    (Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
    CAS Key Laboratory of Gas Hydrate, Guangzhou 510640, China
    Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development, Guangzhou 510640, China
    Guangzhou Center for Gas Hydrate Research, Chinese Academy of Sciences, Guangzhou 510640, China)

  • Zhao-Yang Chen

    (Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
    CAS Key Laboratory of Gas Hydrate, Guangzhou 510640, China
    Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development, Guangzhou 510640, China
    Guangzhou Center for Gas Hydrate Research, Chinese Academy of Sciences, Guangzhou 510640, China)

Abstract

Hydrate-based carbon dioxide (CO 2 ) separation and capture is a new technology for achieving CO 2 emission reduction. However, it is still not commercially applied for the ambiguity of microscopic hydrate formation mechanism. In a constant volume experiment of hydrate formation, there are two or more pressure platforms, indicating that there might be two or more different hydrates formation in succession. In order to reveal the relationship between the microscopic process and the gas consumption in the process of hydrate formation, hydrate composition and formation mechanism of cyclopentane-CO 2 (CP-CO 2 ) system was investigated using a differential scanning calorimeter (DSC) and Raman spectroscopy. The results indicated CO 2 -CP binary hydrate and CO 2 hydrate are formed successively, and they coexist in the final hydrate. CP-CO 2 binary hydrates forms preferentially, and as crystal seeds, inducing the formation of CO 2 hydrates. The two hydrates formation processes cause the two pressure-drops. The results provide a scientific basis for increasing the gas consumption in different stages of gas hydrate formation in the presence of hydrate formation promoter.

Suggested Citation

  • Chun-Gang Xu & Min Wang & Gang Xu & Xiao-Sen Li & Wei Zhang & Jing Cai & Zhao-Yang Chen, 2021. "The Relationship between Thermal Characteristics and Microstructure/Composition of Carbon Dioxide Hydrate in the Presence of Cyclopentane," Energies, MDPI, vol. 14(4), pages 1-17, February.
  • Handle: RePEc:gam:jeners:v:14:y:2021:i:4:p:870-:d:495241
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/14/4/870/pdf
    Download Restriction: no

    File URL: https://www.mdpi.com/1996-1073/14/4/870/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Xia, Zhi-ming & Li, Xiao-sen & Chen, Zhao-yang & Li, Gang & Cai, Jing & Wang, Yi & Yan, Ke-feng & Xu, Chun-gang, 2017. "Hydrate-based acidic gases capture for clean methane with new synergic additives," Applied Energy, Elsevier, vol. 207(C), pages 584-593.
    2. Dijkstra, J.W & Jansen, D, 2004. "Novel concepts for CO2 capture," Energy, Elsevier, vol. 29(9), pages 1249-1257.
    3. Xu, Chun-Gang & Yan, Ran & Fu, Juan & Zhang, Shao-Hong & Yan, Ke-Feng & Chen, Zhao-Yang & Xia, Zhi-Ming & Li, Xiao-Sen, 2019. "Insight into micro-mechanism of hydrate-based methane recovery and carbon dioxide capture from methane-carbon dioxide gas mixtures with thermal characterization," Applied Energy, Elsevier, vol. 239(C), pages 57-69.
    4. Yang, Mingjun & Jing, Wen & Zhao, Jiafei & Ling, Zheng & Song, Yongchen, 2016. "Promotion of hydrate-based CO2 capture from flue gas by additive mixtures (THF (tetrahydrofuran) + TBAB (tetra-n-butyl ammonium bromide))," Energy, Elsevier, vol. 106(C), pages 546-553.
    5. Lee, Yohan & Lee, Dongyoung & Lee, Jong-Won & Seo, Yongwon, 2016. "Enclathration of CO2 as a co-guest of structure H hydrates and its implications for CO2 capture and sequestration," Applied Energy, Elsevier, vol. 163(C), pages 51-59.
    6. Li, Ze-Yu & Xia, Zhi-Ming & Chen, Zhao-Yang & Li, Xiao-Sen & Xu, Chun-Gang & Yan, Ran, 2019. "The plateau effects and crystal transition study in Tetrahydrofuran (THF)/CO2/H2 hydrate formation processes," Applied Energy, Elsevier, vol. 238(C), pages 195-201.
    7. Li, Xiao-Sen & Xu, Chun-Gang & Chen, Zhao-Yang & Wu, Hui-Jie, 2010. "Tetra-n-butyl ammonium bromide semi-clathrate hydrate process for post-combustion capture of carbon dioxide in the presence of dodecyl trimethyl ammonium chloride," Energy, Elsevier, vol. 35(9), pages 3902-3908.
    8. Airong Li & Jie Wang & Buping Bao, 2019. "High‐efficiency CO2 capture and separation based on hydrate technology: A review," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 9(2), pages 175-193, April.
    9. Lee, Yohan & Choi, Wonjung & Seo, Young-ju & Lee, Joo Yong & Lee, Jaehyoung & Seo, Yongwon, 2018. "Structural transition induced by cage-dependent guest exchange in CH4 + C3H8 hydrates with CO2 injection for energy recovery and CO2 sequestration," Applied Energy, Elsevier, vol. 228(C), pages 229-239.
    10. Li, Xiao-Sen & Xu, Chun-Gang & Chen, Zhao-Yang & Wu, Hui-Jie, 2011. "Hydrate-based pre-combustion carbon dioxide capture process in the system with tetra-n-butyl ammonium bromide solution in the presence of cyclopentane," Energy, Elsevier, vol. 36(3), pages 1394-1403.
    11. Biying Yu & Guangpu Zhao & Runying An, 2019. "Framing the picture of energy consumption in China," Natural Hazards: Journal of the International Society for the Prevention and Mitigation of Natural Hazards, Springer;International Society for the Prevention and Mitigation of Natural Hazards, vol. 99(3), pages 1469-1490, December.
    12. Kotowicz, Janusz & Chmielniak, Tadeusz & Janusz-Szymańska, Katarzyna, 2010. "The influence of membrane CO2 separation on the efficiency of a coal-fired power plant," Energy, Elsevier, vol. 35(2), pages 841-850.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Yiwei Wang & Lin Wang & Zhen Hu & Youli Li & Qiang Sun & Aixian Liu & Lanying Yang & Jing Gong & Xuqiang Guo, 2021. "The Thermodynamic and Kinetic Effects of Sodium Lignin Sulfonate on Ethylene Hydrate Formation," Energies, MDPI, vol. 14(11), pages 1-19, June.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Wang, Xiaolin & Zhang, Fengyuan & Lipiński, Wojciech, 2020. "Research progress and challenges in hydrate-based carbon dioxide capture applications," Applied Energy, Elsevier, vol. 269(C).
    2. Yang, Mingjun & Zhou, Hang & Wang, Pengfei & Song, Yongchen, 2018. "Effects of additives on continuous hydrate-based flue gas separation," Applied Energy, Elsevier, vol. 221(C), pages 374-385.
    3. Xu, Chun-Gang & Li, Xiao-Sen & Lv, Qiu-Nan & Chen, Zhao-Yang & Cai, Jing, 2012. "Hydrate-based CO2 (carbon dioxide) capture from IGCC (integrated gasification combined cycle) synthesis gas using bubble method with a set of visual equipment," Energy, Elsevier, vol. 44(1), pages 358-366.
    4. Veluswamy, Hari Prakash & Kumar, Asheesh & Premasinghe, Kulesha & Linga, Praveen, 2017. "Effect of guest gas on the mixed tetrahydrofuran hydrate kinetics in a quiescent system," Applied Energy, Elsevier, vol. 207(C), pages 573-583.
    5. Yuan, Qing & Sun, Chang-Yu & Yang, Xin & Ma, Ping-Chuan & Ma, Zheng-Wei & Liu, Bei & Ma, Qing-Lan & Yang, Lan-Ying & Chen, Guang-Jin, 2012. "Recovery of methane from hydrate reservoir with gaseous carbon dioxide using a three-dimensional middle-size reactor," Energy, Elsevier, vol. 40(1), pages 47-58.
    6. Choi, Wonjung & Lee, Yohan & Mok, Junghoon & Seo, Yongwon, 2020. "Influence of feed gas composition on structural transformation and guest exchange behaviors in sH hydrate – Flue gas replacement for energy recovery and CO2 sequestration," Energy, Elsevier, vol. 207(C).
    7. Chen, Zhaoyang & Fang, Jie & Xu, Chungang & Xia, Zhiming & Yan, Kefeng & Li, Xiaosen, 2020. "Carbon dioxide hydrate separation from Integrated Gasification Combined Cycle (IGCC) syngas by a novel hydrate heat-mass coupling method," Energy, Elsevier, vol. 199(C).
    8. Kim, Soyoung & Choi, Sung-Deuk & Seo, Yongwon, 2017. "CO2 capture from flue gas using clathrate formation in the presence of thermodynamic promoters," Energy, Elsevier, vol. 118(C), pages 950-956.
    9. Nguyen, Ngoc N. & La, Vinh T. & Huynh, Chinh D. & Nguyen, Anh V., 2022. "Technical and economic perspectives of hydrate-based carbon dioxide capture," Applied Energy, Elsevier, vol. 307(C).
    10. Yan, Jin & Lu, Yi-Yu & Zhong, Dong-Liang & Zou, Zhen-Lin & Li, Jian-Bo, 2019. "Enhanced methane recovery from low-concentration coalbed methane by gas hydrate formation in graphite nanofluids," Energy, Elsevier, vol. 180(C), pages 728-736.
    11. Ding, Ya-Long & Xu, Chun-Gang & Yu, Yi-Song & Li, Xiao-Sen, 2017. "Methane recovery from natural gas hydrate with simulated IGCC syngas," Energy, Elsevier, vol. 120(C), pages 192-198.
    12. Park, Joon Ho & Park, Jungjoon & Lee, Jae Won & Kang, Yong Tae, 2023. "Progress in CO2 hydrate formation and feasibility analysis for cold thermal energy harvesting application," Renewable and Sustainable Energy Reviews, Elsevier, vol. 187(C).
    13. Mok, Junghoon & Choi, Wonjung & Seo, Yongwon, 2021. "The dual-functional roles of N2 gas for the exploitation of natural gas hydrates: An inhibitor for dissociation and an external guest for replacement," Energy, Elsevier, vol. 232(C).
    14. Yi, Jie & Zhong, Dong-Liang & Yan, Jin & Lu, Yi-Yu, 2019. "Impacts of the surfactant sulfonated lignin on hydrate based CO2 capture from a CO2/CH4 gas mixture," Energy, Elsevier, vol. 171(C), pages 61-68.
    15. Aminnaji, Morteza & Qureshi, M Fahed & Dashti, Hossein & Hase, Alfred & Mosalanejad, Abdolali & Jahanbakhsh, Amir & Babaei, Masoud & Amiri, Amirpiran & Maroto-Valer, Mercedes, 2024. "CO2 Gas hydrate for carbon capture and storage applications – Part 1," Energy, Elsevier, vol. 300(C).
    16. Babu, Ponnivalavan & Ong, Hong Wen Nelson & Linga, Praveen, 2016. "A systematic kinetic study to evaluate the effect of tetrahydrofuran on the clathrate process for pre-combustion capture of carbon dioxide," Energy, Elsevier, vol. 94(C), pages 431-442.
    17. Li, Ze-Yu & Xia, Zhi-Ming & Chen, Zhao-Yang & Li, Xiao-Sen & Xu, Chun-Gang & Yan, Ran, 2019. "The plateau effects and crystal transition study in Tetrahydrofuran (THF)/CO2/H2 hydrate formation processes," Applied Energy, Elsevier, vol. 238(C), pages 195-201.
    18. Cheng, Zucheng & Li, Shaohua & Liu, Yu & Zhang, Yi & Ling, Zheng & Yang, Mingjun & Jiang, Lanlan & Song, Yongchen, 2022. "Post-combustion CO2 capture and separation in flue gas based on hydrate technology:A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    19. Wang, Fang & Mu, Jinchi & Lin, Wenjing & Cao, Yuehan & Wang, Yuhan & Leng, Shuai & Guo, Lihong & Zhou, Ying, 2024. "Post-combustion CO2 capture via the hydrate formation at the gas-liquid-solid interface induced by the non-surfactant graphene oxide," Energy, Elsevier, vol. 290(C).
    20. Zheng, Junjie & Bhatnagar, Krittika & Khurana, Maninder & Zhang, Peng & Zhang, Bao-Yong & Linga, Praveen, 2018. "Semiclathrate based CO2 capture from fuel gas mixture at ambient temperature: Effect of concentrations of tetra-n-butylammonium fluoride (TBAF) and kinetic additives," Applied Energy, Elsevier, vol. 217(C), pages 377-389.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:14:y:2021:i:4:p:870-:d:495241. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.