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The Relationship between Thermal Characteristics and Microstructure/Composition of Carbon Dioxide Hydrate in the Presence of Cyclopentane

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  • Chun-Gang Xu

    (Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
    CAS Key Laboratory of Gas Hydrate, Guangzhou 510640, China
    Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development, Guangzhou 510640, China
    Guangzhou Center for Gas Hydrate Research, Chinese Academy of Sciences, Guangzhou 510640, China)

  • Min Wang

    (Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
    Nano Science and Technology Institute, University of Sciences and Technology of China, Suzhou 215123, China)

  • Gang Xu

    (Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
    School of Engneering Sciences, University of Sciences and Technology of China, Hefei 230023, China)

  • Xiao-Sen Li

    (Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
    CAS Key Laboratory of Gas Hydrate, Guangzhou 510640, China
    Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development, Guangzhou 510640, China
    Guangzhou Center for Gas Hydrate Research, Chinese Academy of Sciences, Guangzhou 510640, China)

  • Wei Zhang

    (Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
    School of Engneering Sciences, University of Sciences and Technology of China, Hefei 230023, China)

  • Jing Cai

    (Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
    CAS Key Laboratory of Gas Hydrate, Guangzhou 510640, China
    Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development, Guangzhou 510640, China
    Guangzhou Center for Gas Hydrate Research, Chinese Academy of Sciences, Guangzhou 510640, China)

  • Zhao-Yang Chen

    (Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
    CAS Key Laboratory of Gas Hydrate, Guangzhou 510640, China
    Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development, Guangzhou 510640, China
    Guangzhou Center for Gas Hydrate Research, Chinese Academy of Sciences, Guangzhou 510640, China)

Abstract

Hydrate-based carbon dioxide (CO 2 ) separation and capture is a new technology for achieving CO 2 emission reduction. However, it is still not commercially applied for the ambiguity of microscopic hydrate formation mechanism. In a constant volume experiment of hydrate formation, there are two or more pressure platforms, indicating that there might be two or more different hydrates formation in succession. In order to reveal the relationship between the microscopic process and the gas consumption in the process of hydrate formation, hydrate composition and formation mechanism of cyclopentane-CO 2 (CP-CO 2 ) system was investigated using a differential scanning calorimeter (DSC) and Raman spectroscopy. The results indicated CO 2 -CP binary hydrate and CO 2 hydrate are formed successively, and they coexist in the final hydrate. CP-CO 2 binary hydrates forms preferentially, and as crystal seeds, inducing the formation of CO 2 hydrates. The two hydrates formation processes cause the two pressure-drops. The results provide a scientific basis for increasing the gas consumption in different stages of gas hydrate formation in the presence of hydrate formation promoter.

Suggested Citation

  • Chun-Gang Xu & Min Wang & Gang Xu & Xiao-Sen Li & Wei Zhang & Jing Cai & Zhao-Yang Chen, 2021. "The Relationship between Thermal Characteristics and Microstructure/Composition of Carbon Dioxide Hydrate in the Presence of Cyclopentane," Energies, MDPI, vol. 14(4), pages 1-17, February.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:4:p:870-:d:495241
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    References listed on IDEAS

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