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Insight into micro-mechanism of hydrate-based methane recovery and carbon dioxide capture from methane-carbon dioxide gas mixtures with thermal characterization

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Listed:
  • Xu, Chun-Gang
  • Yan, Ran
  • Fu, Juan
  • Zhang, Shao-Hong
  • Yan, Ke-Feng
  • Chen, Zhao-Yang
  • Xia, Zhi-Ming
  • Li, Xiao-Sen

Abstract

Energy shortage and carbon emission reduction are the two big problems in the development of human society. The technologies involving CH4-CO2 binary hydrate is considered to be promising for CH4 recovery and carbon emission reduction. The DSC, Raman, FTIR, Cryo-SEM and PXRD are employed to investigate the thermal process, the micro structure and compositions of the CH4-CO2 hydrate formation and decomposition. The investigations reveal that there are not one kind of hydrate but rather multi-kinds of hydrates coexistence during the hydrate formation. The mechanism of gas hydrate formation could be considered as, under a certain condition, the component with lower enthalpy prior to entrap the cavities to stabilize the hydrate cages in the process of constructing hydrate cages by water molecules, and once the relevant cages are stabilized, the hydrates thereby exist. To fully disperse the oil additive (e.g. CP) into water can effectively improve the gas consumption and enhance CO2 separation efficiency in the process of CH4-CO2 binary hydrate formation. The methods presented here can also be employed for other fields such as hydrate-based sea-water desalination, CO2 separation and H2 purification from IGCC syngas, gas transportation, and other fields.

Suggested Citation

  • Xu, Chun-Gang & Yan, Ran & Fu, Juan & Zhang, Shao-Hong & Yan, Ke-Feng & Chen, Zhao-Yang & Xia, Zhi-Ming & Li, Xiao-Sen, 2019. "Insight into micro-mechanism of hydrate-based methane recovery and carbon dioxide capture from methane-carbon dioxide gas mixtures with thermal characterization," Applied Energy, Elsevier, vol. 239(C), pages 57-69.
    • Handle: RePEc:eee:appene:v:239:y:2019:i:c:p:57-69
    DOI: 10.1016/j.apenergy.2019.01.087
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    References listed on IDEAS

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    1. Xu, Chun-Gang & Cai, Jing & Yu, Yi-Song & Yan, Ke-Feng & Li, Xiao-Sen, 2018. "Effect of pressure on methane recovery from natural gas hydrates by methane-carbon dioxide replacement," Applied Energy, Elsevier, vol. 217(C), pages 527-536.
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    3. Yu, Yi-Song & Zhang, Qing-Zong & Li, Xiao-Sen & Chen, Chang & Zhou, Shi-Dong, 2020. "Kinetics, compositions and structures of carbon dioxide/hydrogen hydrate formation in the presence of cyclopentane," Applied Energy, Elsevier, vol. 265(C).
    4. Elke Kossel & Nikolaus K. Bigalke & Christian Deusner & Matthias Haeckel, 2021. "Microscale Processes and Dynamics during CH 4 –CO 2 Guest-Molecule Exchange in Gas Hydrates," Energies, MDPI, vol. 14(6), pages 1-31, March.
    5. Chun-Gang Xu & Min Wang & Gang Xu & Xiao-Sen Li & Wei Zhang & Jing Cai & Zhao-Yang Chen, 2021. "The Relationship between Thermal Characteristics and Microstructure/Composition of Carbon Dioxide Hydrate in the Presence of Cyclopentane," Energies, MDPI, vol. 14(4), pages 1-17, February.
    6. Cui, Gan & Wang, Shun & Dong, Zengrui & Xing, Xiao & Shan, Tianxiang & Li, Zili, 2020. "Effects of the diameter and the initial center temperature on the combustion characteristics of methane hydrate spheres," Applied Energy, Elsevier, vol. 257(C).

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