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Influence of feed gas composition on structural transformation and guest exchange behaviors in sH hydrate – Flue gas replacement for energy recovery and CO2 sequestration

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  • Choi, Wonjung
  • Lee, Yohan
  • Mok, Junghoon
  • Seo, Yongwon

Abstract

This study investigated the influence of feed gas composition on structural transformation and guest exchange behaviors in the replacement of sH (CH4 + methylcyclopentane) hydrate with CO2 + N2 for energy recovery and CO2 sequestration. CO2 + N2 mixtures with three different CO2 concentrations (20, 40, and 60%) were used as replacement gases, and their exchange behaviors were observed with gas chromatography, nuclear magnetic resonance, and powder X-ray diffraction. The experimental results demonstrated that an increase in the CO2 concentration of replacement gases increased the structural transformation of sH to sI, which resulted in the enhancement of both the extent of replacement and the guest exchange rate. However, the highest extent of replacement was observed in the CO2 (40%) and N2 (60%) mixture due to the asymmetrical change in the CO2 and N2 compositions in the replaced hydrates, which was caused by the higher degree of structural transformation in feed gas with a higher CO2 concentration and the larger N2 inclusion in replaced hydrates at the lower CO2 concentration. The experimental results obtained in this study are helpful for accurately understanding the replacement mechanism and guest exchange behaviors in sH hydrate–flue gas replacement.

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  • Choi, Wonjung & Lee, Yohan & Mok, Junghoon & Seo, Yongwon, 2020. "Influence of feed gas composition on structural transformation and guest exchange behaviors in sH hydrate – Flue gas replacement for energy recovery and CO2 sequestration," Energy, Elsevier, vol. 207(C).
    • Handle: RePEc:eee:energy:v:207:y:2020:i:c:s0360544220314067
    DOI: 10.1016/j.energy.2020.118299
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    1. Judith M. Schicks & Erik Spangenberg & Ronny Giese & Bernd Steinhauer & Jens Klump & Manja Luzi, 2011. "New Approaches for the Production of Hydrocarbons from Hydrate Bearing Sediments," Energies, MDPI, vol. 4(1), pages 1-22, January.
    2. Xu, Chun-Gang & Cai, Jing & Lin, Fu-hua & Chen, Zhao-Yang & Li, Xiao-Sen, 2015. "Raman analysis on methane production from natural gas hydrate by carbon dioxide–methane replacement," Energy, Elsevier, vol. 79(C), pages 111-116.
    3. Lee, Yohan & Choi, Wonjung & Seo, Young-ju & Lee, Joo Yong & Lee, Jaehyoung & Seo, Yongwon, 2018. "Structural transition induced by cage-dependent guest exchange in CH4 + C3H8 hydrates with CO2 injection for energy recovery and CO2 sequestration," Applied Energy, Elsevier, vol. 228(C), pages 229-239.
    4. Bhade, Piyush & Phirani, Jyoti, 2015. "Gas production from layered methane hydrate reservoirs," Energy, Elsevier, vol. 82(C), pages 686-696.
    5. Tupsakhare, Swanand S. & Castaldi, Marco J., 2019. "Efficiency enhancements in methane recovery from natural gas hydrates using injection of CO2/N2 gas mixture simulating in-situ combustion," Applied Energy, Elsevier, vol. 236(C), pages 825-836.
    6. E. Dendy Sloan, 2003. "Fundamental principles and applications of natural gas hydrates," Nature, Nature, vol. 426(6964), pages 353-359, November.
    7. Lee, Yohan & Kim, Yunju & Lee, Jaehyoung & Lee, Huen & Seo, Yongwon, 2015. "CH4 recovery and CO2 sequestration using flue gas in natural gas hydrates as revealed by a micro-differential scanning calorimeter," Applied Energy, Elsevier, vol. 150(C), pages 120-127.
    8. Jiang, Xingxing & Li, Shuxia & Zhang, Lina, 2012. "Sensitivity analysis of gas production from Class I hydrate reservoir by depressurization," Energy, Elsevier, vol. 39(1), pages 281-285.
    9. Zhao, Jiafei & Yu, Tao & Song, Yongchen & Liu, Di & Liu, Weiguo & Liu, Yu & Yang, Mingjun & Ruan, Xuke & Li, Yanghui, 2013. "Numerical simulation of gas production from hydrate deposits using a single vertical well by depressurization in the Qilian Mountain permafrost, Qinghai-Tibet Plateau, China," Energy, Elsevier, vol. 52(C), pages 308-319.
    10. Lee, Yohan & Lee, Dongyoung & Lee, Jong-Won & Seo, Yongwon, 2016. "Enclathration of CO2 as a co-guest of structure H hydrates and its implications for CO2 capture and sequestration," Applied Energy, Elsevier, vol. 163(C), pages 51-59.
    11. Li, Xiao-Sen & Li, Bo & Li, Gang & Yang, Bo, 2012. "Numerical simulation of gas production potential from permafrost hydrate deposits by huff and puff method in a single horizontal well in Qilian Mountain, Qinghai province," Energy, Elsevier, vol. 40(1), pages 59-75.
    12. Seo, Young-ju & Park, Seongmin & Kang, Hyery & Ahn, Yun-Ho & Lim, Dongwook & Kim, Se-Joon & Lee, Jaehyoung & Lee, Joo Yong & Ahn, Taewoong & Seo, Yongwon & Lee, Huen, 2016. "Isostructural and cage-specific replacement occurring in sII hydrate with external CO2/N2 gas and its implications for natural gas production and CO2 storage," Applied Energy, Elsevier, vol. 178(C), pages 579-586.
    13. Hou, Jian & Xia, Zhizeng & Li, Shuxia & Zhou, Kang & Lu, Nu, 2016. "Operation parameter optimization of a gas hydrate reservoir developed by cyclic hot water stimulation with a separated-zone horizontal well based on particle swarm algorithm," Energy, Elsevier, vol. 96(C), pages 581-591.
    14. Zhong, Dong-Liang & Wang, Wen-Chun & Zou, Zhen-Lin & Lu, Yi-Yu & Yan, Jin & Ding, Kun, 2018. "Investigation on methane recovery from low-concentration coal mine gas by tetra-n-butyl ammonium chloride semiclathrate hydrate formation," Applied Energy, Elsevier, vol. 227(C), pages 686-693.
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    1. Choi, Wonjung & Mok, Junghoon & Lee, Yohan & Lee, Jaehyoung & Seo, Yongwon, 2021. "Optimal driving force for the dissociation of CH4 hydrates in hydrate-bearing sediments using depressurization," Energy, Elsevier, vol. 223(C).
    2. Aminnaji, Morteza & Qureshi, M Fahed & Dashti, Hossein & Hase, Alfred & Mosalanejad, Abdolali & Jahanbakhsh, Amir & Babaei, Masoud & Amiri, Amirpiran & Maroto-Valer, Mercedes, 2024. "CO2 Gas hydrate for carbon capture and storage applications – Part 1," Energy, Elsevier, vol. 300(C).
    3. Mok, Junghoon & Choi, Wonjung & Seo, Yongwon, 2021. "The dual-functional roles of N2 gas for the exploitation of natural gas hydrates: An inhibitor for dissociation and an external guest for replacement," Energy, Elsevier, vol. 232(C).
    4. Go, Woojin & Yun, Soyeong & Lee, Dongyoung & Seo, Yongwon, 2022. "Experimental and computational investigation of hydrophilic monomeric substances as novel CO2 hydrate inhibitors and potential synergists," Energy, Elsevier, vol. 244(PB).

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