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Highly Efficient Production of DMF from Biomass-Derived HMF on Recyclable Ni-Fe/TiO 2 Catalysts

Author

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  • Martyna Przydacz

    (Institute of General and Ecological Chemistry, Faculty of Chemistry, Lodz University of Technology, ul. Zeromskiego 116, 90-924 Lodz, Poland)

  • Marcin Jędrzejczyk

    (Institute of General and Ecological Chemistry, Faculty of Chemistry, Lodz University of Technology, ul. Zeromskiego 116, 90-924 Lodz, Poland)

  • Jacek Rogowski

    (Institute of General and Ecological Chemistry, Faculty of Chemistry, Lodz University of Technology, ul. Zeromskiego 116, 90-924 Lodz, Poland)

  • Małgorzata Szynkowska-Jóźwik

    (Institute of General and Ecological Chemistry, Faculty of Chemistry, Lodz University of Technology, ul. Zeromskiego 116, 90-924 Lodz, Poland)

  • Agnieszka M. Ruppert

    (Institute of General and Ecological Chemistry, Faculty of Chemistry, Lodz University of Technology, ul. Zeromskiego 116, 90-924 Lodz, Poland)

Abstract

5-Hydroxymethylfurfural, which can be derived from lignocellulosic biomass, can be transformed via the hydrodeoxygenation process to potential biofuels, such as 2,5 dimethylfuran or other chemicals of industrial importance. Non-noble metal catalysts constitute a robust and cheap solution for this process. In this work, the modification of the Ni/TiO 2 catalyst by the addition of iron and support modification was evaluated. It was shown that bimetallic Ni-Fe catalysts are more selective and stable than their monometallic counterparts. This improvement in properties depends on the Ni:Fe ratio, but the support plays an equally important role—namely the high surface area anatase titania support improves the metal dispersion, resulting in a higher catalytic activity, and the formation of NiFe alloy facilitates the C=O bond cleavage. Such catalysts are active and stable and can be easily separated from the reaction mixture thanks to their magnetic properties.

Suggested Citation

  • Martyna Przydacz & Marcin Jędrzejczyk & Jacek Rogowski & Małgorzata Szynkowska-Jóźwik & Agnieszka M. Ruppert, 2020. "Highly Efficient Production of DMF from Biomass-Derived HMF on Recyclable Ni-Fe/TiO 2 Catalysts," Energies, MDPI, vol. 13(18), pages 1-14, September.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:18:p:4660-:d:410262
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    References listed on IDEAS

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    1. Ye, Run-Ping & Gong, Weibo & Sun, Zhao & Sheng, Qingtao & Shi, Xiufeng & Wang, Tongtong & Yao, Yi & Razink, Joshua J. & Lin, Ling & Zhou, Zhangfeng & Adidharma, Hertanto & Tang, Jinke & Fan, Maohong &, 2019. "Enhanced stability of Ni/SiO2 catalyst for CO2 methanation: Derived from nickel phyllosilicate with strong metal-support interactions," Energy, Elsevier, vol. 188(C).
    2. Kirtika Kohli & Ravindra Prajapati & Brajendra K. Sharma, 2019. "Bio-Based Chemicals from Renewable Biomass for Integrated Biorefineries," Energies, MDPI, vol. 12(2), pages 1-40, January.
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