IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v153y2020icp1479-1487.html
   My bibliography  Save this article

The effect of using different acids to catalyze the prehydrolysis stage on the organosolv delignification of beech wood in two-stage process

Author

Listed:
  • Ibrahim, Qusay
  • Arauzo, Pablo J.
  • Kruse, Andrea

Abstract

In this study, beech wood was fractionated in lab scale rector by one-stage and two-stage processes. The two-stage processes of the prehydrolysis with no catalyst (only water) and catalyst (sulfuric, phosphoric, oxalic acids), and the subsequent effect on the organosolv process were studied. A one-stage organosolv delignification of beech wood (control experiment) was conducted at 155 °C for 160 min in 1:1 ethanol/water mixture with 100 mM sulfuric acid, while the two-stage processes were conducted starting from the uncatalyzed and catalyzed (20–200 mM) prehydrolysis of beech wood at 175 °C for 60 min. The results indicate that sulfuric acid enhanced the removal of xylan from beech wood during the prehydrolysis stage. Moreover, the effectiveness of the delignification of beech wood using a one-stage process is more than the two-stage, as well as the enzymatic digestibility of the pulp, which was better than those of the two-stage processes. However, the enzymatic digestibility results of the pulp obtained after sulfuric acid catalyzed prehydrolysis followed by organosolv delignification shown better results than the other two-stage processes. Additionally, high klason content, low sugar content, low Mw, and high phenolic hydroxyl groups of lignin was recovered by a one-stage organosolv delignification.

Suggested Citation

  • Ibrahim, Qusay & Arauzo, Pablo J. & Kruse, Andrea, 2020. "The effect of using different acids to catalyze the prehydrolysis stage on the organosolv delignification of beech wood in two-stage process," Renewable Energy, Elsevier, vol. 153(C), pages 1479-1487.
    • Handle: RePEc:eee:renene:v:153:y:2020:i:c:p:1479-1487
    DOI: 10.1016/j.renene.2020.02.111
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148120303062
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2020.02.111?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Kirtika Kohli & Ravindra Prajapati & Brajendra K. Sharma, 2019. "Bio-Based Chemicals from Renewable Biomass for Integrated Biorefineries," Energies, MDPI, vol. 12(2), pages 1-40, January.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Wang, Peng & Su, Yan & Tang, Wei & Huang, Caoxing & Lai, Chenhuan & Ling, Zhe & Yong, Qiang, 2022. "Revealing enzymatic digestibility of kraft pretreated larch based on a comprehensive analysis of substrate-related factors," Renewable Energy, Elsevier, vol. 199(C), pages 1461-1468.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zhou, Man & Fakayode, Olugbenga Abiola & Ahmed Yagoub, Abu ElGasim & Ji, Qinghua & Zhou, Cunshan, 2022. "Lignin fractionation from lignocellulosic biomass using deep eutectic solvents and its valorization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 156(C).
    2. Diana Constantinescu-Aruxandei & Florin Oancea, 2023. "Closing the Nutrient Loop—The New Approaches to Recovering Biomass Minerals during the Biorefinery Processes," IJERPH, MDPI, vol. 20(3), pages 1-52, January.
    3. Bogusława Waliszewska & Mieczysław Grzelak & Eliza Gaweł & Agnieszka Spek-Dźwigała & Agnieszka Sieradzka & Wojciech Czekała, 2021. "Chemical Characteristics of Selected Grass Species from Polish Meadows and Their Potential Utilization for Energy Generation Purposes," Energies, MDPI, vol. 14(6), pages 1-14, March.
    4. Li Ji & Pengfei Li & Fuhou Lei & Xianliang Song & Jianxin Jiang & Kun Wang, 2020. "Coproduction of Furfural, Phenolated Lignin and Fermentable Sugars from Bamboo with One-Pot Fractionation Using Phenol-Acidic 1,4-Dioxane," Energies, MDPI, vol. 13(20), pages 1-17, October.
    5. Cai, Xin & Wang, Zhichao & Ye, Yueyuan & Wang, Duo & Zhang, Zhaoxia & Zheng, Zhifeng & Liu, Yunquan & Li, Shuirong, 2021. "Conversion of chitin biomass into 5-hydroxymethylfurfural: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
    6. Pomeroy, Brett & Grilc, Miha & Likozar, Blaž, 2022. "Artificial neural networks for bio-based chemical production or biorefining: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 153(C).
    7. Aristide Giuliano, 2023. "The Transition of Scientific Research from Biomass-to-Energy/Biofuels to Biomass-to-Biochemicals in a Biorefinery Systems Framework," Energies, MDPI, vol. 16(5), pages 1-4, February.
    8. Zhou, Qiaoqiao & Liu, Zhenyu & Wu, Ta Yeong & Zhang, Lian, 2023. "Furfural from pyrolysis of agroforestry waste: Critical factors for utilisation of C5 and C6 sugars," Renewable and Sustainable Energy Reviews, Elsevier, vol. 176(C).
    9. Akinola David Olugbemide & Ana Oberlintner & Uroš Novak & Blaž Likozar, 2021. "Lignocellulosic Corn Stover Biomass Pre-Treatment by Deep Eutectic Solvents (DES) for Biomethane Production Process by Bioresource Anaerobic Digestion," Sustainability, MDPI, vol. 13(19), pages 1-13, September.
    10. Parvez, Ashak Mahmud & Lewis, Jonathan David & Afzal, Muhammad T., 2021. "Potential of industrial hemp (Cannabis sativa L.) for bioenergy production in Canada: Status, challenges and outlook," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).
    11. Nneka B. Ekwe & Maksim V. Tyufekchiev & Ali A. Salifu & Klaus Schmidt-Rohr & Zhaoxi Zheng & Alex R. Maag & Geoffrey A. Tompsett & Charles M. Cai & Emmanuel O. Onche & Ayten Ates & Winston O. Soboyejo , 2022. "Bamboo as a Cost-Effective Source of Renewable Carbon for Sustainable Economic Development in Low- and Middle-Income Economies," Energies, MDPI, vol. 16(1), pages 1-17, December.
    12. Guzelciftci, Begum & Park, Ki-Bum & Kim, Joo-Sik, 2020. "Production of phenol-rich bio-oil via a two-stage pyrolysis of wood," Energy, Elsevier, vol. 200(C).
    13. Bartolucci, L. & Cordiner, S. & Di Carlo, A. & Gallifuoco, A. & Mele, P. & Mulone, V., 2024. "Platform chemicals recovery from spent coffee grounds aqueous-phase pyrolysis oil," Renewable Energy, Elsevier, vol. 220(C).
    14. Martyna Przydacz & Marcin Jędrzejczyk & Jacek Rogowski & Małgorzata Szynkowska-Jóźwik & Agnieszka M. Ruppert, 2020. "Highly Efficient Production of DMF from Biomass-Derived HMF on Recyclable Ni-Fe/TiO 2 Catalysts," Energies, MDPI, vol. 13(18), pages 1-14, September.
    15. Sigrid Kusch-Brandt & Mohammad A. T. Alsheyab, 2021. "Wastewater Refinery: Producing Multiple Valuable Outputs from Wastewater," J, MDPI, vol. 4(1), pages 1-11, February.
    16. Thombal, Priyanka Raju & Thombal, Raju S. & Han, Sung Soo, 2021. "Comprehensive study on the catalytic methods for furyl alkane synthesis: A promising biodiesel precursor," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:153:y:2020:i:c:p:1479-1487. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.