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Preparation and Properties of Capric–Myristic Acid/Expanded Graphite Composite Phase Change Materials for Latent Heat Thermal Energy Storage

Author

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  • Dongyi Zhou

    (School of Energy Science and Engineering, Central South University, Changsha 410083, China
    School of Mechanical and Energy Engineering, Shaoyang University, Shaoyang 422000, China
    Key Laboratory of Hunan Province for Efficient Power System and Intelligent Manufacturing, Shaoyang University, Shaoyang 422000, China)

  • Jiawei Yuan

    (School of Mechanical and Energy Engineering, Shaoyang University, Shaoyang 422000, China)

  • Yuhong Zhou

    (School of Mechanical and Energy Engineering, Shaoyang University, Shaoyang 422000, China)

  • Yicai Liu

    (School of Energy Science and Engineering, Central South University, Changsha 410083, China)

Abstract

A novel composite phase change material (CPCM), capric–myristic acid/expanded graphite (CA–MA/EG) CPCM, was prepared by absorbing liquid CA–MA (as the phase change material (PCM)) into EG (as the substrate material) for heat storage in the backfill materials of soil-source heat pump systems. The thermal characteristics and microstructure of the novel CPCM were analyzed using differential scanning calorimetry (DSC) and scanning electronic microscopy (SEM). The thermal conductivities of CA–MA/EG CPCM were surveyed. The thermal stability of the CA–MA/EG was analyzed using thermogravimetric analysis (TGA) and thermal cycle tests. The results showed that the optimal mass content of CA–MA in CPCM was approximately 92.4% and the CA–MA was uniformly distributed in the vesicular structure of EG; the CA–MA/EG CPCM had an appropriate phase change temperature ( T m : 19.78 °C, T f : 18.85 °C), high latent heat ( H m : 137.3 J/g, H f : 139.9 J/g), and excellent thermostability and thermal reliability. The thermal conductivity of the CPCM was remarkably enhanced after adding EG. Therefore, the CPCMs demonstrated outstanding thermal performance and can be utilized in low-temperature latent heat thermal energy storage (LHTES) systems, such as soil-source heat pump systems.

Suggested Citation

  • Dongyi Zhou & Jiawei Yuan & Yuhong Zhou & Yicai Liu, 2020. "Preparation and Properties of Capric–Myristic Acid/Expanded Graphite Composite Phase Change Materials for Latent Heat Thermal Energy Storage," Energies, MDPI, vol. 13(10), pages 1-12, May.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:10:p:2462-:d:357771
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    1. Zhang, P. & Xiao, X. & Ma, Z.W., 2016. "A review of the composite phase change materials: Fabrication, characterization, mathematical modeling and application to performance enhancement," Applied Energy, Elsevier, vol. 165(C), pages 472-510.
    2. Mohamed, Shamseldin A. & Al-Sulaiman, Fahad A. & Ibrahim, Nasiru I. & Zahir, Md. Hasan & Al-Ahmed, Amir & Saidur, R. & Yılbaş, B.S. & Sahin, A.Z., 2017. "A review on current status and challenges of inorganic phase change materials for thermal energy storage systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 1072-1089.
    3. Pereira da Cunha, Jose & Eames, Philip, 2016. "Thermal energy storage for low and medium temperature applications using phase change materials – A review," Applied Energy, Elsevier, vol. 177(C), pages 227-238.
    4. Wei, Haiting & Xie, Xiuzhen & Li, Xiangqi & Lin, Xingshui, 2016. "Preparation and characterization of capric-myristic-stearic acid eutectic mixture/modified expanded vermiculite composite as a form-stable phase change material," Applied Energy, Elsevier, vol. 178(C), pages 616-623.
    5. Wang, Tingyu & Wang, Shuangfeng & Luo, Ruilian & Zhu, Chunyu & Akiyama, Tomohiro & Zhang, Zhengguo, 2016. "Microencapsulation of phase change materials with binary cores and calcium carbonate shell for thermal energy storage," Applied Energy, Elsevier, vol. 171(C), pages 113-119.
    6. Lin, Yaxue & Jia, Yuting & Alva, Guruprasad & Fang, Guiyin, 2018. "Review on thermal conductivity enhancement, thermal properties and applications of phase change materials in thermal energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2730-2742.
    7. Li, Wei & Zhang, Rong & Jiang, Nan & Tang, Xiao-fen & Shi, Hai-feng & Zhang, Xing-xiang & Zhang, Yuankai & Dong, Lin & Zhang, Ningxin, 2013. "Composite macrocapsule of phase change materials/expanded graphite for thermal energy storage," Energy, Elsevier, vol. 57(C), pages 607-614.
    8. Ramakrishnan, Sayanthan & Sanjayan, Jay & Wang, Xiaoming & Alam, Morshed & Wilson, John, 2015. "A novel paraffin/expanded perlite composite phase change material for prevention of PCM leakage in cementitious composites," Applied Energy, Elsevier, vol. 157(C), pages 85-94.
    9. Akeiber, Hussein & Nejat, Payam & Majid, Muhd Zaimi Abd. & Wahid, Mazlan A. & Jomehzadeh, Fatemeh & Zeynali Famileh, Iman & Calautit, John Kaiser & Hughes, Ben Richard & Zaki, Sheikh Ahmad, 2016. "A review on phase change material (PCM) for sustainable passive cooling in building envelopes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 60(C), pages 1470-1497.
    10. Gunasekara, Saman Nimali & Martin, Viktoria & Chiu, Justin Ningwei, 2017. "Phase equilibrium in the design of phase change materials for thermal energy storage: State-of-the-art," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 558-581.
    11. Fan, Liwu & Khodadadi, J.M., 2011. "Thermal conductivity enhancement of phase change materials for thermal energy storage: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 24-46, January.
    12. Bose, Prabhu & Amirtham, Valan Arasu, 2016. "A review on thermal conductivity enhancement of paraffinwax as latent heat energy storage material," Renewable and Sustainable Energy Reviews, Elsevier, vol. 65(C), pages 81-100.
    13. He, Hongtao & Zhao, Pin & Yue, Qinyan & Gao, Baoyu & Yue, Dongting & Li, Qian, 2015. "A novel polynary fatty acid/sludge ceramsite composite phase change materials and its applications in building energy conservation," Renewable Energy, Elsevier, vol. 76(C), pages 45-52.
    14. Karaipekli, Ali & Sarı, Ahmet & Kaygusuz, Kamil, 2007. "Thermal conductivity improvement of stearic acid using expanded graphite and carbon fiber for energy storage applications," Renewable Energy, Elsevier, vol. 32(13), pages 2201-2210.
    15. M. Mofijur & Teuku Meurah Indra Mahlia & Arridina Susan Silitonga & Hwai Chyuan Ong & Mahyar Silakhori & Muhammad Heikal Hasan & Nandy Putra & S.M. Ashrafur Rahman, 2019. "Phase Change Materials (PCM) for Solar Energy Usages and Storage: An Overview," Energies, MDPI, vol. 12(16), pages 1-20, August.
    16. Yuan, Yanping & Zhang, Nan & Tao, Wenquan & Cao, Xiaoling & He, Yaling, 2014. "Fatty acids as phase change materials: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 482-498.
    17. Zhao, Pin & Yue, Qinyan & He, Hongtao & Gao, Baoyu & Wang, Yan & Li, Qian, 2014. "Study on phase diagram of fatty acids mixtures to determine eutectic temperatures and the corresponding mixing proportions," Applied Energy, Elsevier, vol. 115(C), pages 483-490.
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