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Composite macrocapsule of phase change materials/expanded graphite for thermal energy storage

Author

Listed:
  • Li, Wei
  • Zhang, Rong
  • Jiang, Nan
  • Tang, Xiao-fen
  • Shi, Hai-feng
  • Zhang, Xing-xiang
  • Zhang, Yuankai
  • Dong, Lin
  • Zhang, Ningxin

Abstract

Three kinds of macro-encapsulated phase change materials (MacroPCMs) were fabricated, i.e., MacroPCMs with a single core–shell structure, MacroPCMs containing microencapsulated phase change materials (MicroPCMs), and composite macrocapsules of MicroPCMs/expanded graphite prepared by suspension-like polymerization followed by a piercing–solidifying incuber process. The morphology, microstructure, phase change property, as well as seal tightness were systematically characterized by field emission scanning electron microscope (FESEM), differential scanning calorimetry (DSC), and energy dispersive X-ray spectrometer (EDS). The core–shell structured macrocapsules exhibit a homogeneous thickness shell. The interface combination between MicroPCMs and polymer substrate was studied through the cross section micrograph of MacroPCMs containing MicroPCMs. The morphology and seal tightness of MacroPCMs fabricated with expanded graphite absorbing both PCMs and shell-forming monomers, enhanced significantly compared with that of PCMs alone. In addition, the effects of polymer substrate proportion between styrene-maleic anhydride copolymer and sodium alginate on the microstructure and performance of MacroPCMs were discussed as well.

Suggested Citation

  • Li, Wei & Zhang, Rong & Jiang, Nan & Tang, Xiao-fen & Shi, Hai-feng & Zhang, Xing-xiang & Zhang, Yuankai & Dong, Lin & Zhang, Ningxin, 2013. "Composite macrocapsule of phase change materials/expanded graphite for thermal energy storage," Energy, Elsevier, vol. 57(C), pages 607-614.
    • Handle: RePEc:eee:energy:v:57:y:2013:i:c:p:607-614
    DOI: 10.1016/j.energy.2013.05.007
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    1. Rezaei, M. & Anisur, M.R. & Mahfuz, M.H. & Kibria, M.A. & Saidur, R. & Metselaar, I.H.S.C., 2013. "Performance and cost analysis of phase change materials with different melting temperatures in heating systems," Energy, Elsevier, vol. 53(C), pages 173-178.
    2. Li, Wei & Song, Guolin & Tang, Guoyi & Chu, Xiaodong & Ma, Sude & Liu, Caifeng, 2011. "Morphology, structure and thermal stability of microencapsulated phase change material with copolymer shell," Energy, Elsevier, vol. 36(2), pages 785-791.
    3. Rao, Zhonghao & Wang, Shuangfeng & Peng, Feifei & Zhang, Wei & Zhang, Yanlai, 2012. "Dissipative particle dynamics investigation of microencapsulated thermal energy storage phase change materials," Energy, Elsevier, vol. 44(1), pages 805-812.
    4. Kenisarin, Murat M. & Kenisarina, Kamola M., 2012. "Form-stable phase change materials for thermal energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(4), pages 1999-2040.
    5. Colella, Francesco & Sciacovelli, Adriano & Verda, Vittorio, 2012. "Numerical analysis of a medium scale latent energy storage unit for district heating systems," Energy, Elsevier, vol. 45(1), pages 397-406.
    6. Wang, Jian-Ping & Zhang, Xing-Xiang & Wang, Xue-Chen, 2011. "Preparation, characterization and permeation kinetics description of calcium alginate macro-capsules containing shape-stabilize phase change materials," Renewable Energy, Elsevier, vol. 36(11), pages 2984-2991.
    7. Li, Gang & Hwang, Yunho & Radermacher, Reinhard & Chun, Ho-Hwan, 2013. "Review of cold storage materials for subzero applications," Energy, Elsevier, vol. 51(C), pages 1-17.
    8. Zhang, Zhengguo & Zhang, Ni & Peng, Jing & Fang, Xiaoming & Gao, Xuenong & Fang, Yutang, 2012. "Preparation and thermal energy storage properties of paraffin/expanded graphite composite phase change material," Applied Energy, Elsevier, vol. 91(1), pages 426-431.
    9. Li, Wei & Zhang, Xing-xiang & Wang, Xue-chen & Tang, Guo-yi & Shi, Hai-feng, 2012. "Fabrication and morphological characterization of microencapsulated phase change materials (MicroPCMs) and macrocapsules containing MicroPCMs for thermal energy storage," Energy, Elsevier, vol. 38(1), pages 249-254.
    10. Zhang, Lei & Zhu, Jiaoqun & Zhou, Weibing & Wang, Jun & Wang, Yan, 2012. "Thermal and electrical conductivity enhancement of graphite nanoplatelets on form-stable polyethylene glycol/polymethyl methacrylate composite phase change materials," Energy, Elsevier, vol. 39(1), pages 294-302.
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