IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v12y2019i3p480-d202962.html
   My bibliography  Save this article

A Simple Method of Finding New Dry and Isentropic Working Fluids for Organic Rankine Cycle

Author

Listed:
  • Gábor Györke

    (Budapest University of Technology and Economics, Department of Energy Engineering, Muegyetem rkp. 3, H-1111 Budapest, Hungary)

  • Axel Groniewsky

    (Budapest University of Technology and Economics, Department of Energy Engineering, Muegyetem rkp. 3, H-1111 Budapest, Hungary)

  • Attila R. Imre

    (Budapest University of Technology and Economics, Department of Energy Engineering, Muegyetem rkp. 3, H-1111 Budapest, Hungary
    MTA Centre for Energy Research, Department of Thermohydraulics, POB. 49, H-1525 Budapest, Hungary)

Abstract

One of the most crucial challenges of sustainable development is the use of low-temperature heat sources (60–200 °C), such as thermal solar, geothermal, biomass, or waste heat, for electricity production. Since conventional water-based thermodynamic cycles are not suitable in this temperature range or at least operate with very low efficiency, other working fluids need to be applied. Organic Rankine Cycle (ORC) uses organic working fluids, which results in higher thermal efficiency for low-temperature heat sources. Traditionally, new working fluids are found using a trial-and-error procedure through experience among chemically similar materials. This approach, however, carries a high risk of excluding the ideal working fluid. Therefore, a new method and a simple rule of thumb—based on a correlation related to molar isochoric specific heat capacity of saturated vapor states—were developed. With the application of this thumb rule, novel isentropic and dry working fluids can be found applicable for given low-temperature heat sources. Additionally, the importance of molar quantities—usually ignored by energy engineers—was demonstrated.

Suggested Citation

  • Gábor Györke & Axel Groniewsky & Attila R. Imre, 2019. "A Simple Method of Finding New Dry and Isentropic Working Fluids for Organic Rankine Cycle," Energies, MDPI, vol. 12(3), pages 1-11, February.
  • Handle: RePEc:gam:jeners:v:12:y:2019:i:3:p:480-:d:202962
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/12/3/480/pdf
    Download Restriction: no

    File URL: https://www.mdpi.com/1996-1073/12/3/480/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Zare, V. & Mahmoudi, S.M.S., 2015. "A thermodynamic comparison between organic Rankine and Kalina cycles for waste heat recovery from the Gas Turbine-Modular Helium Reactor," Energy, Elsevier, vol. 79(C), pages 398-406.
    2. Albornoz, Jorge & Mejía, Andrés & Quinteros-Lama, Héctor & Garrido, José Matías, 2018. "A rigorous and accurate approach for predicting the wet-to-dry transition for working mixtures in organic Rankine cycles," Energy, Elsevier, vol. 156(C), pages 509-519.
    3. Garrido, José Matías & Quinteros-Lama, Héctor & Mejía, Andrés & Wisniak, Jaime & Segura, Hugo, 2012. "A rigorous approach for predicting the slope and curvature of the temperature–entropy saturation boundary of pure fluids," Energy, Elsevier, vol. 45(1), pages 888-899.
    4. Chao Zhang & Jinglun Fu & Pengfei Yuan & Jianjun Liu, 2018. "Guidelines for Optimal Selection of Subcritical Low-Temperature Geothermal Organic Rankine Cycle Configuration Considering Reinjection Temperature Limits," Energies, MDPI, vol. 11(11), pages 1-18, October.
    5. Ziviani, Davide & James, Nelson A. & Accorsi, Felipe A. & Braun, James E. & Groll, Eckhard A., 2018. "Experimental and numerical analyses of a 5 kWe oil-free open-drive scroll expander for small-scale organic Rankine cycle (ORC) applications," Applied Energy, Elsevier, vol. 230(C), pages 1140-1156.
    6. White, J.A. & Velasco, S., 2018. "Characterizing wet and dry fluids in temperature-entropy diagrams," Energy, Elsevier, vol. 154(C), pages 269-276.
    7. Fuhaid Alshammari & Apostolos Karvountzis-Kontakiotis & Apostolos Pesyridis & Muhammad Usman, 2018. "Expander Technologies for Automotive Engine Organic Rankine Cycle Applications," Energies, MDPI, vol. 11(7), pages 1-36, July.
    8. Györke, Gábor & Deiters, Ulrich K. & Groniewsky, Axel & Lassu, Imre & Imre, Attila R., 2018. "Novel classification of pure working fluids for Organic Rankine Cycle," Energy, Elsevier, vol. 145(C), pages 288-300.
    9. Bao, Junjiang & Zhao, Li, 2013. "A review of working fluid and expander selections for organic Rankine cycle," Renewable and Sustainable Energy Reviews, Elsevier, vol. 24(C), pages 325-342.
    10. Wang, E.H. & Zhang, H.G. & Fan, B.Y. & Ouyang, M.G. & Zhao, Y. & Mu, Q.H., 2011. "Study of working fluid selection of organic Rankine cycle (ORC) for engine waste heat recovery," Energy, Elsevier, vol. 36(5), pages 3406-3418.
    11. Wang, Z.Q. & Zhou, N.J. & Guo, J. & Wang, X.Y., 2012. "Fluid selection and parametric optimization of organic Rankine cycle using low temperature waste heat," Energy, Elsevier, vol. 40(1), pages 107-115.
    12. Quoilin, Sylvain & Broek, Martijn Van Den & Declaye, Sébastien & Dewallef, Pierre & Lemort, Vincent, 2013. "Techno-economic survey of Organic Rankine Cycle (ORC) systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 22(C), pages 168-186.
    13. He, Chao & Liu, Chao & Gao, Hong & Xie, Hui & Li, Yourong & Wu, Shuangying & Xu, Jinliang, 2012. "The optimal evaporation temperature and working fluids for subcritical organic Rankine cycle," Energy, Elsevier, vol. 38(1), pages 136-143.
    14. Liu, Bo-Tau & Chien, Kuo-Hsiang & Wang, Chi-Chuan, 2004. "Effect of working fluids on organic Rankine cycle for waste heat recovery," Energy, Elsevier, vol. 29(8), pages 1207-1217.
    15. Varga, Zoltán & Palotai, Balázs, 2017. "Comparison of low temperature waste heat recovery methods," Energy, Elsevier, vol. 137(C), pages 1286-1292.
    16. Chen, Huijuan & Goswami, D. Yogi & Stefanakos, Elias K., 2010. "A review of thermodynamic cycles and working fluids for the conversion of low-grade heat," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(9), pages 3059-3067, December.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Gábor Pörzse & Zoltán Csedő & Máté Zavarkó, 2021. "Disruption Potential Assessment of the Power-to-Methane Technology," Energies, MDPI, vol. 14(8), pages 1-21, April.
    2. Attila R. Imre & Réka Kustán & Axel Groniewsky, 2019. "Thermodynamic Selection of the Optimal Working Fluid for Organic Rankine Cycles," Energies, MDPI, vol. 12(10), pages 1-15, May.
    3. Zoltán Csedő & Botond Sinóros-Szabó & Máté Zavarkó, 2020. "Seasonal Energy Storage Potential Assessment of WWTPs with Power-to-Methane Technology," Energies, MDPI, vol. 13(18), pages 1-21, September.
    4. Juan A. White & Santiago Velasco, 2019. "Approximating the Temperature–Entropy Saturation Curve of ORC Working Fluids From the Ideal Gas Isobaric Heat Capacity," Energies, MDPI, vol. 12(17), pages 1-14, August.
    5. Ana Fernández-Guillamón & Ángel Molina-García & Francisco Vera-García & José A. Almendros-Ibáñez, 2021. "Organic Rankine Cycle Optimization Performance Analysis Based on Super-Heater Pressure: Comparison of Working Fluids," Energies, MDPI, vol. 14(9), pages 1-16, April.
    6. Andrea Arbula Blecich & Paolo Blecich, 2023. "Thermoeconomic Analysis of Subcritical and Supercritical Isobutane Cycles for Geothermal Power Generation," Sustainability, MDPI, vol. 15(11), pages 1-25, May.
    7. Attila R. Imre & Réka Kustán & Axel Groniewsky, 2020. "Mapping of the Temperature–Entropy Diagrams of van der Waals Fluids," Energies, MDPI, vol. 13(6), pages 1-15, March.
    8. Daniarta, Sindu & Nemś, Magdalena & Kolasiński, Piotr, 2023. "A review on thermal energy storage applicable for low- and medium-temperature organic Rankine cycle," Energy, Elsevier, vol. 278(PA).
    9. Xinxin Zhang & Yin Zhang & Min Cao & Jingfu Wang & Yuting Wu & Chongfang Ma, 2019. "Working Fluid Selection for Organic Rankine Cycle Using Single-Screw Expander," Energies, MDPI, vol. 12(16), pages 1-23, August.
    10. Yang, Minbo & Li, Ting & Feng, Xiao & Wang, Yufei, 2020. "A simulation-based targeting method for heat pump placements in heat exchanger networks," Energy, Elsevier, vol. 203(C).
    11. Zoltán Csedő & Máté Zavarkó & Balázs Vaszkun & Sára Koczkás, 2021. "Hydrogen Economy Development Opportunities by Inter-Organizational Digital Knowledge Networks," Sustainability, MDPI, vol. 13(16), pages 1-26, August.
    12. González, Johan & Llovell, Fèlix & Garrido, José Matías & Quinteros-Lama, Héctor, 2022. "A rigorous approach for characterising the limiting optimal efficiency of working fluids in organic Rankine cycles," Energy, Elsevier, vol. 254(PA).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Juan A. White & Santiago Velasco, 2019. "Approximating the Temperature–Entropy Saturation Curve of ORC Working Fluids From the Ideal Gas Isobaric Heat Capacity," Energies, MDPI, vol. 12(17), pages 1-14, August.
    2. Oko, C.O.C. & Njoku, I.H., 2017. "Performance analysis of an integrated gas-, steam- and organic fluid-cycle thermal power plant," Energy, Elsevier, vol. 122(C), pages 431-443.
    3. Lecompte, S. & Huisseune, H. & van den Broek, M. & De Paepe, M., 2015. "Methodical thermodynamic analysis and regression models of organic Rankine cycle architectures for waste heat recovery," Energy, Elsevier, vol. 87(C), pages 60-76.
    4. Attila R. Imre & Réka Kustán & Axel Groniewsky, 2019. "Thermodynamic Selection of the Optimal Working Fluid for Organic Rankine Cycles," Energies, MDPI, vol. 12(10), pages 1-15, May.
    5. Bao, Junjiang & Zhao, Li, 2013. "A review of working fluid and expander selections for organic Rankine cycle," Renewable and Sustainable Energy Reviews, Elsevier, vol. 24(C), pages 325-342.
    6. Xu, Heng & Gao, Naiping & Zhu, Tong, 2016. "Investigation on the fluid selection and evaporation parametric optimization for sub- and supercritical organic Rankine cycle," Energy, Elsevier, vol. 96(C), pages 59-68.
    7. Attila R. Imre & Réka Kustán & Axel Groniewsky, 2020. "Mapping of the Temperature–Entropy Diagrams of van der Waals Fluids," Energies, MDPI, vol. 13(6), pages 1-15, March.
    8. He, Chao & Liu, Chao & Zhou, Mengtong & Xie, Hui & Xu, Xiaoxiao & Wu, Shuangying & Li, Yourong, 2014. "A new selection principle of working fluids for subcritical organic Rankine cycle coupling with different heat sources," Energy, Elsevier, vol. 68(C), pages 283-291.
    9. Braimakis, Konstantinos & Karellas, Sotirios, 2017. "Integrated thermoeconomic optimization of standard and regenerative ORC for different heat source types and capacities," Energy, Elsevier, vol. 121(C), pages 570-598.
    10. Ayachi, Fadhel & Ksayer, Elias Boulawz & Neveu, Pierre & Zoughaib, Assaad, 2016. "Experimental investigation and modeling of a hermetic scroll expander," Applied Energy, Elsevier, vol. 181(C), pages 256-267.
    11. Liu, Chao & He, Chao & Gao, Hong & Xie, Hui & Li, Yourong & Wu, Shuangying & Xu, Jinliang, 2013. "The environmental impact of organic Rankine cycle for waste heat recovery through life-cycle assessment," Energy, Elsevier, vol. 56(C), pages 144-154.
    12. Kajurek, Jakub & Rusowicz, Artur & Grzebielec, Andrzej & Bujalski, Wojciech & Futyma, Kamil & Rudowicz, Zbigniew, 2019. "Selection of refrigerants for a modified organic Rankine cycle," Energy, Elsevier, vol. 168(C), pages 1-8.
    13. Xu, Jinliang & Yu, Chao, 2014. "Critical temperature criterion for selection of working fluids for subcritical pressure Organic Rankine cycles," Energy, Elsevier, vol. 74(C), pages 719-733.
    14. Xinxin Zhang & Yin Zhang & Min Cao & Jingfu Wang & Yuting Wu & Chongfang Ma, 2019. "Working Fluid Selection for Organic Rankine Cycle Using Single-Screw Expander," Energies, MDPI, vol. 12(16), pages 1-23, August.
    15. Györke, Gábor & Deiters, Ulrich K. & Groniewsky, Axel & Lassu, Imre & Imre, Attila R., 2018. "Novel classification of pure working fluids for Organic Rankine Cycle," Energy, Elsevier, vol. 145(C), pages 288-300.
    16. Aram Mohammed Ahmed & László Kondor & Attila R. Imre, 2021. "Thermodynamic Efficiency Maximum of Simple Organic Rankine Cycles," Energies, MDPI, vol. 14(2), pages 1-17, January.
    17. Fuhaid Alshammari & Apostolos Karvountzis-Kontakiotis & Apostolos Pesyridis & Muhammad Usman, 2018. "Expander Technologies for Automotive Engine Organic Rankine Cycle Applications," Energies, MDPI, vol. 11(7), pages 1-36, July.
    18. Li, Tailu & Zhu, Jialing & Hu, Kaiyong & Kang, Zhenhua & Zhang, Wei, 2014. "Implementation of PDORC (parallel double-evaporator organic Rankine cycle) to enhance power output in oilfield," Energy, Elsevier, vol. 68(C), pages 680-687.
    19. Nian, Yong-Le & Cheng, Wen-Long, 2018. "Insights into geothermal utilization of abandoned oil and gas wells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 87(C), pages 44-60.
    20. Cavazzini, G. & Bari, S. & Pavesi, G. & Ardizzon, G., 2017. "A multi-fluid PSO-based algorithm for the search of the best performance of sub-critical Organic Rankine Cycles," Energy, Elsevier, vol. 129(C), pages 42-58.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:12:y:2019:i:3:p:480-:d:202962. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.