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Techno economic analysis of a micro Gas-to-Liquid unit for associated natural gas conversion

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  • Pauletto, Gianluca
  • Galli, Federico
  • Gaillardet, Alice
  • Mocellin, Paolo
  • Patience, Gregory S.

Abstract

Flared and vented natural gas in remote regions of the world contribute ¿1% of the total CO2 emissions. High investment costs to build facilities to treat this gas and labor costs to operate the infrastructure are deterrents to addressing this environmental burden. Here we report a techno-economic analysis of a commercial mobile manufacturing plant that processes 2400 m3 d-1 of methane via a tandem short contact time catalytic partial oxidation (CPOX) and a single-pass Fischer–Tropsch fluidized bed to produce 7 bbl d-1. Starting from methane and air, a thermodynamic analysis identified the optimized operating conditions considering both carbon yield, CO/H2 ratio and adiabatic conditions. We studied the flammability limits of the mixture at operating pressures and temperatures. The economic analysis itemizes costs for all equipment rather than applying scale-up power law or factors. The greatest contributors to direct costs are the compressors and the CPOX reactor. Operating CPOX at 2.0 MPa reduces reactor volumes but to achieve 90% conversion and selectivity requires operating this unit above 900 °C. Avoiding syngas compression and upstream syngas conditioning reduces capital costs. The capital cost (CAPEX) reaches 570 000 USD when the whole process operates at 2.0 MPa. Considering numbering-up, the price of the 100th unit approaches 360 000 USD thus the MRU increases profitability. We demonstrate how thermodynamics constrains methane conversion and syngas selectivity. A large part of achieving low CAPEX is operating a single pass process, building multiple units, and replacing the methane to heat the treater at the oil tank battery with the incondensable gas leaving the three phases separator downstream the Fischer–Tropsch reactor.

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  • Pauletto, Gianluca & Galli, Federico & Gaillardet, Alice & Mocellin, Paolo & Patience, Gregory S., 2021. "Techno economic analysis of a micro Gas-to-Liquid unit for associated natural gas conversion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
    • Handle: RePEc:eee:rensus:v:150:y:2021:i:c:s1364032121007383
    DOI: 10.1016/j.rser.2021.111457
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    References listed on IDEAS

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    1. Mohajerani, Sara & Kumar, Amit & Oni, Abayomi Olufemi, 2018. "A techno-economic assessment of gas-to-liquid and coal-to-liquid plants through the development of scale factors," Energy, Elsevier, vol. 150(C), pages 681-693.
    2. Zdzisław Jaworski & Paulina Pianko-Oprych, 2018. "A Comparative Thermodynamic Study of Equilibrium Conditions for Carbon Deposition from Catalytic C–H–O Reformates," Energies, MDPI, vol. 11(5), pages 1-12, May.
    3. Marvin B. Lieberman, 1989. "The learning curve, technology barriers to entry, and competitive survival in the chemical processing industries," Strategic Management Journal, Wiley Blackwell, vol. 10(5), pages 431-447, September.
    4. Herz, Gregor & Reichelt, Erik & Jahn, Matthias, 2017. "Design and evaluation of a Fischer-Tropsch process for the production of waxes from biogas," Energy, Elsevier, vol. 132(C), pages 370-381.
    5. Ramberg, David J. & Henry Chen, Y.H. & Paltsev, Sergey & Parsons, John E., 2017. "The economic viability of gas-to-liquids technology and the crude oil–natural gas price relationship," Energy Economics, Elsevier, vol. 63(C), pages 13-21.
    6. Blumberg, Timo & Morosuk, Tatiana & Tsatsaronis, George, 2017. "Exergy-based evaluation of methanol production from natural gas with CO2 utilization," Energy, Elsevier, vol. 141(C), pages 2528-2539.
    7. Reyes Valle, C. & Villanueva Perales, A.L. & Vidal-Barrero, F. & Gómez-Barea, A., 2013. "Techno-economic assessment of biomass-to-ethanol by indirect fluidized bed gasification: Impact of reforming technologies and comparison with entrained flow gasification," Applied Energy, Elsevier, vol. 109(C), pages 254-266.
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    1. Rodrigues, A.C.C., 2022. "Decreasing natural gas flaring in Brazilian oil and gas industry," Resources Policy, Elsevier, vol. 77(C).
    2. Do, Thai Ngan & Hur, Young Gul & Chung, Hegwon & Kim, Jiyong, 2023. "Potentials and benefit assessment of green fuels from residue gas via gas-to-liquid," Renewable and Sustainable Energy Reviews, Elsevier, vol. 182(C).

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