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Design and Performance Comparison of Methanol Production Processes with Carbon Dioxide Utilization

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  • Yih-Hang Chen

    (Department of Chemical and Materials Engineering, Tamkang University, New Taipei City 25137, Taiwan)

  • David Shan-Hill Wong

    (Department of Chemical Engineering, National Tsing Hua University, Hsinchu 30013, Taiwan)

  • Ya-Chien Chen

    (Department of Chemical and Materials Engineering, Tamkang University, New Taipei City 25137, Taiwan)

  • Chao-Min Chang

    (Department of Chemical and Materials Engineering, Tamkang University, New Taipei City 25137, Taiwan)

  • Hsuan Chang

    (Department of Chemical and Materials Engineering, Tamkang University, New Taipei City 25137, Taiwan)

Abstract

Carbon dioxide recycling is one of the possible contributions to CO 2 mitigation and provides an opportunity to use a low-cost carbon source. Methanol is a commodity chemical that serves as an important basic chemical and energy feedstock with growing demand. For each of the four types of industrial methanol production processes from natural gas (methane), i.e., steam reforming (SR), autothermal reforming (ATR), combined reforming (CR), and two-step reforming (TSR), CO 2 utilization cases of (A) no utilization, (B) as reforming step feedstock, and (C) as methanol synthesis step feedstock were designed based on common industrial operation conditions and analyzed for energy consumption, exergy loss (EX loss ), net CO 2 reduction (NCR) and internal rate of return (IRR). The utilization of CO 2 can reduce energy consumption. The processes with the lowest and the highest EX loss are SR and ATR, respectively. All SR processes give negative NCR. All the B-type processes are positive in NCR except B-SR. The highest NCR is obtained from the B-ATR process with a value of 0.23 kg CO 2 /kg methanol. All the processes are profitable with positive IRR results and the highest IRR of 41% can be obtained from B-ATR. The utilization of CO 2 in the industrial methanol process can realize substantial carbon reduction and is beneficial to process economics.

Suggested Citation

  • Yih-Hang Chen & David Shan-Hill Wong & Ya-Chien Chen & Chao-Min Chang & Hsuan Chang, 2019. "Design and Performance Comparison of Methanol Production Processes with Carbon Dioxide Utilization," Energies, MDPI, vol. 12(22), pages 1-18, November.
    • Handle: RePEc:gam:jeners:v:12:y:2019:i:22:p:4322-:d:286402
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    References listed on IDEAS

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    1. Usman, Muhammad & Wan Daud, W.M.A. & Abbas, Hazzim F., 2015. "Dry reforming of methane: Influence of process parameters—A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 45(C), pages 710-744.
    2. Pérez-Fortes, Mar & Schöneberger, Jan C. & Boulamanti, Aikaterini & Tzimas, Evangelos, 2016. "Methanol synthesis using captured CO2 as raw material: Techno-economic and environmental assessment," Applied Energy, Elsevier, vol. 161(C), pages 718-732.
    3. Blumberg, Timo & Morosuk, Tatiana & Tsatsaronis, George, 2017. "Exergy-based evaluation of methanol production from natural gas with CO2 utilization," Energy, Elsevier, vol. 141(C), pages 2528-2539.
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