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Chromium-based MIL-101 metal organic framework as a fully regenerable D4 adsorbent for biogas purification

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  • Gargiulo, Nicola
  • Peluso, Antonio
  • Aprea, Paolo
  • Marino, Ottavio
  • Cioffi, Raffaele
  • Jannelli, Elio
  • Cimino, Stefano
  • Lisi, Luciana
  • Caputo, Domenico

Abstract

In this work, the chromium-based MIL-101 metal organic framework has been synthesized and investigated as a fully regenerable, high capacity sorbent for siloxanes, which are common contaminants in raw biogas from anaerobic digestion. Adsorption isotherms of D4, the most common siloxane in waste treatment plants, have been collected at different temperatures and modelled by means of the Langmuir theoretical isotherm. The selected metal organic framework shows a remarkable affinity for siloxane adsorption and an outstanding saturation capacity weakly dependent on temperature. Moreover, repeated adsorption isotherms, collected after a reactivation treatment of the same adsorbent sample, clearly indicate full regeneration capabilities. Considering that chromium-based MIL-101 is also a noticeable H2S adsorbent, the results reported in this work pave the way to its potential application for the simultaneous removal of the two main poisoning compounds contained in biogas.

Suggested Citation

  • Gargiulo, Nicola & Peluso, Antonio & Aprea, Paolo & Marino, Ottavio & Cioffi, Raffaele & Jannelli, Elio & Cimino, Stefano & Lisi, Luciana & Caputo, Domenico, 2019. "Chromium-based MIL-101 metal organic framework as a fully regenerable D4 adsorbent for biogas purification," Renewable Energy, Elsevier, vol. 138(C), pages 230-235.
    • Handle: RePEc:eee:renene:v:138:y:2019:i:c:p:230-235
    DOI: 10.1016/j.renene.2019.01.096
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    1. Carolinne Secco & Maria Eduarda Kounaris Fuziki & Angelo Marcelo Tusset & Giane Gonçalves Lenzi, 2023. "Reactive Processes for H 2 S Removal," Energies, MDPI, vol. 16(4), pages 1-14, February.
    2. Zheng, Yanhui & Hou, Xifeng & Liu, Yuheng & Ma, Zichuan, 2021. "Hexamethyldisiloxane removal from biogas using reduced graphene-oxide aerogels as adsorbents," Renewable Energy, Elsevier, vol. 178(C), pages 153-161.

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