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Ultrasound-assisted dispersion of bifunctional CaO-ZrO2 nanocatalyst over acidified kaolin for production of biodiesel from waste cooking oil

Author

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  • Ghasemi, Iman
  • Haghighi, Mohammad
  • Bekhradinassab, Ensie
  • Ebrahimi, Alireza

Abstract

The work aimed to produce biodiesel from waste cooking oil (WCO) using a novel catalyst from acid-modified kaolin with ZrO2 and CaO. The catalyst was created by acid-treatment of kaolin and then impregnating kaolin with ZrO2 as an acid-active-component and CaO as a base-enhancer. Ultrasound was applied to disperse promoters on kaolin(T) and improve specific-surface-area and pore-volume. XRD, FESEM, FTIR, 3D-surface, EDX-dot mapping, TEM, BET-BJH, TPD-NH3, and TPD-CO2 analyses were used for characterization. A one-pot experiment has been performed to generate biodiesel from WCO by esterification and transesterification under the reaction-conditions of 10 wt% catalyst-loading, 110 °C, 3 h, and m.r = 20. The selected-nanocatalyst, Zr-Ca/Kaolin(T)-U(300), was found to have a high-activity for producing biodiesel from WCO with total-conversion, FFA-conversion, and TG-conversion rates of 93.4%, 99.0%, and 73.4%, respectively. This outstanding performance is attributed to the high acid and base strength of the catalyst (total-acid-density = 0.453 mmol NH3/g and total-base-density = 0.324 mmol CO2/g), its well-dispersed enhancer, and its high specific-surface-area (22.49 m2/g) and pore-volume (0.09 cm3/g). The selected-nanocatalyst also demonstrated great stability against five-successive-cycles (activity-reduction = 2.1%) and NaCl as an impurity of WCO (activity-reduction = 1.6%). Overall, this work presents a promising-approach for producing biodiesel from WCO using a highly efficient and stable bi-functional nanocatalyst.

Suggested Citation

  • Ghasemi, Iman & Haghighi, Mohammad & Bekhradinassab, Ensie & Ebrahimi, Alireza, 2024. "Ultrasound-assisted dispersion of bifunctional CaO-ZrO2 nanocatalyst over acidified kaolin for production of biodiesel from waste cooking oil," Renewable Energy, Elsevier, vol. 225(C).
    • Handle: RePEc:eee:renene:v:225:y:2024:i:c:s0960148124003525
    DOI: 10.1016/j.renene.2024.120287
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    1. Sun, Hao & Ma, Mingzhe & Fan, Mengmeng & Sun, Kang & Xu, Wei & Wang, Kui & Li, Baojun & Jiang, Jianchun, 2022. "Controllable preparation of biomass derived mesoporous activated carbon supported nano-CaO catalysts for biodiesel production," Energy, Elsevier, vol. 261(PB).
    2. Kodgire, Pravin & Sharma, Anvita & Kachhwaha, Surendra Singh, 2023. "Optimization and kinetics of biodiesel production of Ricinus communis oil and used cottonseed cooking oil employing synchronised ‘ultrasound + microwave’ and heterogeneous CaO catalyst," Renewable Energy, Elsevier, vol. 212(C), pages 320-332.
    3. Muhammad Nobi Hossain & Md Sufi Ullah Siddik Bhuyan & Abul Hasnat Md Ashraful Alam & Yong Chan Seo, 2018. "Biodiesel from Hydrolyzed Waste Cooking Oil Using a S-ZrO 2 /SBA-15 Super Acid Catalyst under Sub-Critical Conditions," Energies, MDPI, vol. 11(2), pages 1-13, January.
    4. Li, Ying & Niu, Shengli & Hao, Yanan & Zhou, Wenbo & Wang, Jun & Liu, Jiangwei, 2022. "Role of oxygen vacancy on activity of Fe-doped SrTiO3 perovskite bifunctional catalysts for biodiesel production," Renewable Energy, Elsevier, vol. 199(C), pages 1258-1271.
    5. da Silva, Paula Maria Melo & Gonçalves, Matheus Arrais & da Luz Corrêa, Ana Paula & da Luz, Patrícia Teresa Souza & Zamian, José Roberto & da Rocha Filho, Geraldo Narciso & da Conceição, Leyvison Rafa, 2023. "Preparation and characterization of a novel efficient catalyst based on molybdenum oxide supported over graphene oxide for biodiesel synthesis," Renewable Energy, Elsevier, vol. 211(C), pages 126-139.
    6. de Brito, Vitor Lima & Gonçalves, Matheus Arrais & dos Santos, Hiarla Cristina Lima & da Rocha Filho, Geraldo Narciso & da Conceição, Leyvison Rafael Vieira, 2023. "Biodiesel production from waste frying oil using molybdenum over niobia as heterogeneous acid catalyst: Process optimization and kinetics study," Renewable Energy, Elsevier, vol. 215(C).
    7. Das, Arpita & Li, Hui & Kataki, Rupam & Agrawal, Pratibha S. & Moyon, N.S. & Gurunathan, Baskar & Rokhum, Samuel Lalthazuala, 2023. "Terminalia arjuna bark – A highly efficient renewable heterogeneous base catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 212(C), pages 185-196.
    8. Xia, Shaige & Li, Jian & Chen, Guanyi & Tao, Junyu & Li, Wanqing & Zhu, Guangbin, 2022. "Magnetic reusable acid-base bifunctional Co doped Fe2O3–CaO nanocatalysts for biodiesel production from soybean oil and waste frying oil," Renewable Energy, Elsevier, vol. 189(C), pages 421-434.
    9. Al-Hamamre, Zayed & Sandouqa, Arwa & Al-Saida, Basel & Shawabkeh, Reyad A. & Alnaief, Mohammad, 2023. "Biodiesel production from waste cooking oil using heterogeneous KNO3/Oil shale ash catalyst," Renewable Energy, Elsevier, vol. 211(C), pages 470-483.
    10. Li, Ronghe & Wei, Zhong & Li, Hongli & Yin, Zhili & Wang, Ziqing, 2022. "Selective esterification of glycerol with acetic acid to green fuel bio-additive over a lignosulfonate-based renewable solid acid," Renewable Energy, Elsevier, vol. 201(P2), pages 125-134.
    11. Singh, Himmat & Ali, Amjad, 2023. "Esterification as well as transesterification of waste oil using potassium imbued tungstophosphoric acid supported graphene oxide as heterogeneous catalyst: Optimization and kinetic modeling," Renewable Energy, Elsevier, vol. 207(C), pages 422-435.
    12. Sangsiri, Pimpajee & Laosiripojana, Navadol & Daorattanachai, Pornlada, 2022. "Synthesis of sulfonated carbon-based catalysts from organosolv lignin and methanesulfonic acid: Its activity toward esterification of stearic acid," Renewable Energy, Elsevier, vol. 193(C), pages 113-127.
    13. Ebadinezhad, Behzad & Haghighi, Mohammad & Zeinalzadeh, Hossein, 2021. "Influence of carbon casting loading and ultrasound irradiation on catalytic design of Al–Si–P zeotype nanostructure for biofuel production," Renewable Energy, Elsevier, vol. 177(C), pages 290-307.
    14. Dehghani, Sahar & Haghighi, Mohammad, 2020. "Sono-enhanced dispersion of CaO over Zr-Doped MCM-41 bifunctional nanocatalyst with various Si/Zr ratios for conversion of waste cooking oil to biodiesel," Renewable Energy, Elsevier, vol. 153(C), pages 801-812.
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