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Selective esterification of glycerol with acetic acid to green fuel bio-additive over a lignosulfonate-based renewable solid acid

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  • Li, Ronghe
  • Wei, Zhong
  • Li, Hongli
  • Yin, Zhili
  • Wang, Ziqing

Abstract

Using waste biomass as feedstock to obtain high value-added chemicals has attracted increasingly more attention from the viewpoint of sustainable development. A novel renewable bio-based solid acid (LFuS) was prepared by a two-step sulfonation of the phenol-formaldehyde condensation product of sodium lignosulfonate (LS-Na) and furfural derived from industrial and agricultural organic wastes. LFuS was then firstly employed as a catalyst for the selective esterification of glycerol (GL) with acetic acid (HOAc) to produce a fuel bio-additive, a mixture of glycerol diacetates (DAG) and glycerol triacetate (TAG). Using LFuS achieved a 98.0% conversion of GL with the selectivity to DAG + TAG of 94.1% under milder conditions. Additionally, the obtained LFuS also exhibited an excellent reusability in this reaction, and no loss in glycerol conversion was observed after five cycles, with the corresponding selectivity to DAG + TAG only decreasing from 94.1% to 90.0% after five cycles. The high concentration of acid sites and the polyphenolic structure of LFuS are responsible for its excellent catalytic performance and reusability in selective esterification of glycerol reaction.

Suggested Citation

  • Li, Ronghe & Wei, Zhong & Li, Hongli & Yin, Zhili & Wang, Ziqing, 2022. "Selective esterification of glycerol with acetic acid to green fuel bio-additive over a lignosulfonate-based renewable solid acid," Renewable Energy, Elsevier, vol. 201(P2), pages 125-134.
    • Handle: RePEc:eee:renene:v:201:y:2022:i:p2:p:125-134
    DOI: 10.1016/j.renene.2022.11.040
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    References listed on IDEAS

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    1. Okoye, P.U. & Abdullah, A.Z. & Hameed, B.H., 2017. "A review on recent developments and progress in the kinetics and deactivation of catalytic acetylation of glycerol—A byproduct of biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 387-401.
    2. Banu, Ionut & Bumbac, Gheorghe & Bombos, Dorin & Velea, Sanda & Gălan, Ana-Maria & Bozga, Grigore, 2020. "Glycerol acetylation with acetic acid over Purolite CT-275. Product yields and process kinetics," Renewable Energy, Elsevier, vol. 148(C), pages 548-557.
    3. Dechakhumwat, Suppasate & Hongmanorom, Plaifa & Thunyaratchatanon, Chachchaya & Smith, Siwaporn Meejoo & Boonyuen, Supakorn & Luengnaruemitchai, Apanee, 2020. "Catalytic activity of heterogeneous acid catalysts derived from corncob in the esterification of oleic acid with methanol," Renewable Energy, Elsevier, vol. 148(C), pages 897-906.
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